Method of fabricating electrodes of high power-density flow cell

Patent metadata

Field	Value
Publication number	US-9425463-B2
Application number	US-201414266945-A
Country	US
Kind code	B2
Filing date	May 1, 2014
Priority date	Oct 28, 2013
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

A method is provided for producing electrodes of flow cell having high power density. A plurality of seeds are distributed on a surface of a conductive carbon material. The seeds are etched into nanoparticles to form carbon nanotube (CNT) electrodes. The present invention can be applied to vanadium redox flow cell with advantages of the CNT electrodes, such as conductivity, corrosion resistance, mechanical strength and specific and electrochemical surface area. Electrons are directly passed to the material through CNTs and then to an external electronic load for improving power density of flow cell, making a cell pack more compact and reducing energy consumption on charging and discharging without using noble metal material.

First claim

What is claimed is:

1. A method of fabricating electrodes of high power-density flow cell, comprising steps of:
(a) pre-treatment: processing a first high-temperature treatment at a first elevated temperature to a conductive carbon material, then cooling the conductive carbon material to room temperature, then exposing the conductive carbon material to a second high-temperature treatment at a second, more elevated temperature;
(b) seed settlement: distributing a plurality of seeds on a surface of said conductive carbon material;
(c) etching: etching each of said seeds on said surface of said conductive carbon material into a plurality of nanoparticles; and
(d) microwave molding: forming a plurality of carbon nanotube (CNT) electrodes on said surface of said conductive carbon material by introducing CH 4 , H 2 and N 2 and directly microwaving said nanoparticles,
wherein, in step (a), said first high-temperature treatment comprises exposing the carbon-based conductive material to a temperature of 140 Celsius degrees (° C.)±20% for at least 10 hours in a furnace with oxygen introduced.

2. The method according claim 1 , wherein, in step (a), said conductive carbon material is selected from a group consisting of a carbon felt and a graphite felt.

3. The method according claim 1 , wherein the second high-temperature treatment comprises exposing the conductive carbon material to 500° C.±20% and so as to process a functionalization treatment.

4. The method according claim 1 , further comprising removing impurities in said conductive carbon material with 8 molar (M) nitric acid and 2M sulfuric acid under a reflux condition.

5. The method according claim 1 , wherein, in step (b), said seeds are iron and said seeds are distributed on said surface of said conductive carbon material through a sol-gel or an iron-bearing leaching method.

6. The method according claim 1 , wherein, in step (c), each of said seeds on said surface of said conductive carbon material is directly etched into said nanoparticle through a hydrogen-plasma treatment.

7. The method according claim 1 , wherein, in step (d), a chemical vapor deposition device assisted with microwave plasma is used to directly form multi-walled CNT electrodes on said surface of said conductive carbon material directly with the nanoparticles.

8. The method according claim 7 , wherein, when microwave power of said device reaches 2500 watts (W), CH 4 , H 2 and N 2 are introduced at flow rates of 20 standard cubic centimeters per minute (sccm), 80 sccm and 80 sccm, respectively, for 10 minutes to grow said CNT electrodes; and wherein, during growing said CNT electrodes, said device is maintained at a pressure of 40 torrs±20% and a reaction temperature of 900° C.±20%.

9. The method according claim 1 , wherein, in step (d), each of said CNT electrodes has a diameter less than 50 nanometers (nm)±20% and a length of 1 micrometer (μm)±20%.

10. A method of fabricating electrodes of high power-density flow cell, comprising steps of:
(a) pre-treatment: processing a first high-temperature treatment at a first elevated temperature to a conductive carbon material, then cooling the conductive carbon material to room temperature, then exposing the conductive carbon material to a second high-temperature treatment at a second, more elevated temperature;
(b) seed settlement: distributing a plurality of seeds on a surface of said conductive carbon material;
(c) etching: etching each of said seeds on said surface of said conductive carbon material into a plurality of nanoparticles; and
(d) microwave molding: forming a plurality of carbon nanotube (CNT) electrodes on said surface of said conductive carbon material by introducing CH 4 , H 2 and N 2 and directly microwaving said nanoparticles,
wherein, in step (d), a chemical vapor deposition device assisted with microwave plasma is used to directly form multi-walled CNT electrodes on said surface of said conductive carbon material directly with the nanoparticles,
wherein, when microwave power of said device reaches 2500 watts (W), CH 4 , H 2 and N 2 are introduced at flow rates of 20 standard cubic centimeters per minute (sccm), 80 sccm and 80 sccm, respectively, for 10 minutes to grow said CNT electrodes; and wherein, during growing said CNT electrodes, said device is maintained at a pressure of 40 torrs±20% and a reaction temperature of 900° C.±20%.

Assignees

• Inst Nuclear Energy Res Atomic Energy Council Executive Yuan Roc

Inventors

• Hsu Ning-Yih
• Chang Yuan-Ming
• Chen Kuan-Hsiang
• Wei Hwa-Jou
• Wang chen-hao
• Huang Wan-Min

Classifications

• H01M4/8817 Primary

  Treatment of supports before application of the catalytic active composition (coated porous composites H01M8/0245) · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/8875

  Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title