Aggregated thread structure, production method thereof, and electric wire using the same

Patent metadata

Field	Value
Publication number	US-9424960-B2
Application number	US-201414454714-A
Country	US
Kind code	B2
Filing date	Aug 7, 2014
Priority date	Nov 22, 2010
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

A method for producing an aggregated thread structure includes (a) a process of dispersing carbon nanotube to a first solvent, which is water or a mixed solvent containing organic solvent and water, with a surfactant, to create a dispersion and (b) a process of injecting the dispersion, in which carbon nanotube is dispersed, to a condensing liquid, which is a second solvent that differs from the first solvent, to thereby aggregate and spin carbon nanotube. The aggregated thread structure containing carbon nanotube has: a bulk density of 0.5 g/cm 3 or more; a weight reduction rate up to 450° C. of 50% or less; a G/D ratio for resonance Raman scattering measurement of 10 or more; and an electric conductivity of 50 S/cm or more.

First claim

The invention claimed is:

1. A method for producing an aggregated thread structure, the method comprising:
(a) dispersing carbon nanotubes to a first solvent, which is water or a mixed solvent containing organic solvent and water, with a surfactant, to create a dispersion; and
(b) injecting said dispersion of carbon nanotubes into a condensing liquid, which is a second solvent differing from the first solvent, to thereby aggregate and spin the carbon nanotubes;
wherein said condensing liquid is a solution consisting essentially of one of N-methyl pyrrolidone, N,N-dimethyl acetamide, propylene carbonate, formamide, N-methyl formamide, methanol, ethanol, or propanol, and said condensing liquid and said first solvent differ in their affinity to said surfactant, and
the pH of said condensing liquid is 3 to 11.

2. The method for producing an aggregated thread structure according to claim 1 , wherein said surfactant is a surfactant selected from one or more type(s) selected from the following groups (1) to (3):
(1) a non-ionic surfactant with an HLB, calculated by the Griffin method, of 8 or more;
(2) an anionic surfactant: alkyl benzene sulfonate, alkyl alcohol sulfate salt, sodium alkyl diphenyl ether disulphonate, sodium polyoxyethylene alkyl ether sulfate, sodium diakyl sulfosuccinate, sodium alkyl aryl sulfosuccinate, n-lauroyl sarcosine sodium salt, sodium polyoxyethylene alkyl phenyl ether sulfate, sodium (meta)acryloyl polyoxyalkylene sulfate, alkyl alcohol phosphate;
(3) a cationic surfactant: tetra alkyl ammonium halide.

3. The method for producing an aggregated thread structure according to claim 2 , wherein said surfactant is a combination of one or more surfactants selected from each of said group (1) and said group (2), or each of said group (1) and said group (3).

4. The method for producing an aggregated thread structure according to claim 2 , wherein said surfactant comprises a plurality of surfactants with different lengths of main chain.

5. The method for producing an aggregated thread structure according to claim 2 , wherein said surfactant comprises sodium dodecyl sulfate.

6. The method for producing an aggregated thread structure according to claim 1 , which further comprises:
a process of extracting said aggregated thread structure from said condensing liquid and immersing in a solvent;
a process of drying said aggregated thread structure; and
a process of stretching said aggregated thread structure;
following said process (b).

7. The method for producing an aggregated thread structure according to claim 6 , which further comprises a process of twisting said aggregated thread structure.

8. The method for producing an aggregated thread structure according to claim 1 , wherein said carbon nanotubes are treated for catalyst removal.

Assignees

• Furukawa Electric Co Ltd
• Nat Inst Advanced Ind Science & Tech

Inventors

• Rikihisa Hiroaki
• Tachibana Masato
• Shimada Michihiro
• Asaka Kinji
• Mukai Ken
• Sugino Takushi

Classifications

• C01B31/0253

  Chemistry & Metallurgy · mapped topic

• Y10S977/842

  for carbon nanotubes or fullerenes · CPC title

• H01B1/04

  mainly consisting of carbon-silicon compounds, carbon or silicon · CPC title

• Y10T428/2918

  including free carbon or carbide or therewith [not as steel] · CPC title

• Y10S977/742

  Carbon nanotubes, CNTs · CPC title