Conductive full vulcanized thermoplastic elastomer and its preparation method

Patent metadata

Field	Value
Publication number	US-9424959-B2
Application number	US-201214001948-A
Country	US
Kind code	B2
Filing date	Mar 2, 2012
Priority date	Mar 4, 2011
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

The invention provides a conductive full vulcanized thermoplastic elastomer and its preparation method, and relates to the technical field of full vulcanized thermoplastic elastomer. The full vulcanized thermoplastic elastomer is obtained by melt-blending components including rubber particles having crosslinking structure with mean particle diameter of 0.02 to 1 μm, carbon nanotubes as conductive fillers and thermoplastic plastics once, wherein the weight ratio of the rubber particles and the thermoplastic plastics is from 30:70 to 75:25 and the content of conductive fillers is from 0.3 to 10 weight parts based on the total weight of rubber particles and thermoplastic plastics of 100 weight parts. The resulting conductive full vulcanized thermoplastic elastomers have low content of conductive fillers and excellent combination performances. It can be prepared by conventional rubber processing methods and can be used to produce electronic production equipment, means, electronic instrument, instrument housing and decorative materials of clean production workshop having static resistance, electro magnetic interference resistance and clean requirement.

First claim

The invention claimed is:

1. A conductive full vulcanized thermoplastic elastomer comprising the following components in the form of mixture:
(a) thermoplastic plastics; (b) rubber particles having crosslinking structure; (c) conductive fillers;
wherein the rubber particles of component (b) have mean particle diameter of 0.02 to 1 μm, gel content of 60 wt % or greater, and homogenous structure; and the conductive fillers of component (c) include carbon nanotubes;
the microscopic phase state of the conductive full vulcanized thermoplastic elastomer is that the thermoplastic plastics of component (a) are continuous phase, the rubber particles of component (b) are dispersed phase, and the carbon nanotubes of component (c) are dispersed in the continuous phase and distributed between the rubber particles and are not dispersed or embedded in the rubber phase;
wherein the weight ratio of the rubber particles of component (b) to the thermoplastic plastics of component (a) is from 30:70 to 75:25, and the content of the conductive fillers of component (c) is from 0.3 to 10 weight percentage of the total weight of the rubber particles of component (b) and the thermoplastic plastics of component (a).

2. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the thermoplastic plastics of component (a) are at least one selected from the group consisting of polypropylene, polyethylene, polyamide, polyvinylchloride, polyurethane, polyester, polycarbonate, polyformaldehyde, polystyrene, polyphenylene sulfide, polyimide, polysulfone or grafting modified substances of such thermoplastic plastics above.

3. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the rubber particles having crosslinking structure of component (b) have gel content of 75 wt % or greater.

4. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the rubber particles having crosslinking structure of component (b) have mean particle diameter of 0.05 to 0.5 μm.

5. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the carbon nanotubes are at least one selected from the group consisting of single walled carbon nanotubes, double wall carbon nanotubes and multi-walled carbon nanotubes.

6. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the carbon nanotubes are multi-walled carbon nanotubes.

7. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the carbon nanotubes have mean diameter of 0.4 to 500 nm, mean length of 0.1 to 1000 μm, and aspect ratio of 0.25 to 2.5×10 6 .

8. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the carbon nanotubes have mean diameter of 1 to 50 nm, mean length of 1 to 50 μm, and aspect ratio of 20 to 1×10 4 .

9. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the weight ratio of rubber particles of component (b) to thermoplastic plastics of component (a) is from 50:50 to 75:25.

10. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the content of conductive fillers of component (c) is from 0.5 to 10 weight parts based on the total weight of rubber particles of component (b) and thermoplastic plastics of component (a) of 100 weight parts.

11. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the content of conductive fillers of component (c) is from 0.5 to 7 weight parts based on the total weight of rubber particles of component (b) and thermoplastic plastics of component (a) of 100 weight parts.

12. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the thermoplastic plastics of component (a) comprises polyethylene, and wherein the polyethylene comprises at least one selected from the group consisting of low density polyethylene, linear low density polyethylene, high density polyethylene and grafted polyethylene.

13. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the thermoplastic plastics of component (a) comprises polypropylene, and wherein the polypropylene comprises at least one selected from the group consisting of polypropylene homopolymer, polypropylene copolymer and grafted polypropylene.

14. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the rubber particles having crosslinking structure of component (b) are full vulcanized powdered rubber or crosslinked type powdered rubber.

15. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the rubber particles having crosslinking structure of component (b) are full vulcanized powdered rubber comprising at least one selected from the group consisting of full vulcanized powdered natural rubber, full vulcanized powdered styrene butadiene rubber, full vulcanized powdered carboxylic styrene butadiene rubber, full vulcanized powdered nitrile rubber, full vulcanized powdered carboxylic nitrile rubber, full vulcanized powdered polybutadiene rubber, full vulcanized powdered chloroprene rubber, full vulcanized powdered silicone rubber, full vulcanized powdered acrylate rubber, full vulcanized powdered butadiene-styrene-vinylpyridine rubber, full vulcanized powdered isoprene rubber, full vulcanized powdered butyl rubber, full vulcanized powdered polysulfide rubber, full vulcanized powdered acrylate-butadiene rubber, full vulcanized powdered polyurethane rubber and full vulcanized powdered fluorubber.

16. The conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein the rubber particles having crosslinking structure of component (b) are crosslinked type powdered rubber which comprise crosslinked type powdered styrene butadiene rubber or crosslinked type powdered polybutadiene rubber.

17. A method for preparing the conductive full vulcanized thermoplastic elastomer according to claim 1 , wherein components including the thermoplastic plastics of component (a), the rubber particles having crosslinking structure of component (b) and the conductive fillers of component (c) are subjected to pass through plastics blending equipment and melt-blended once to obtain the conductive full vulcanized thermoplastic elastomer.

Assignees

• Zhang Xiaohong
• Qiao Jinliang
• Qi Guicun
• Song Zhihai
• Cai Chuanlun
• Wang Ya
• Gao Jianming
• Zhang Hongbin
• Lai Jinmei
• Li Binghai
• Wang Haosheng
• Zhu Yilei
• China Petroleum & Chem Corp
• Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp

Inventors

• Zhang Xiaohong
• Qiao Jinliang
• Qi Guicun
• Song Zhihai
• Cai Chuanlun
• Wang Ya
• Gao Jianming
• Zhang Hongbin
• Lai Jinmei
• Li Binghai
• Wang Haosheng
• Zhu Yilei

Classifications

• C08K3/04

  Carbon · CPC title

• C08L23/12

  Polypropene · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• H01B1/24 Primary

  the conductive material comprising carbon-silicon compounds, carbon or silicon · CPC title

• C08J2325/10

  with conjugated dienes · CPC title