Relative valuation method for naphtha streams

Patent metadata

Field	Value
Publication number	US-9423391-B2
Application number	US-201514589257-A
Country	US
Kind code	B2
Filing date	Jan 5, 2015
Priority date	Oct 18, 2010
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

A system and a method for determining the relative value of a naphtha product includes reforming the naphtha into fractions at a predetermined constant research octane number (RON), conducting PIONA analysis on the reformate, after which modules or steps are performed to assign the feed quality, assign the total liquid yields, assign raw product yields, normalize the assigned raw product yields, assign a value to one or more fractions, and calculate a total value of the naphtha stream. The method is repeated on samples of different crude oils in order to provide relative values at the predetermined RON for comparison purposes.

First claim

I claim:

1. A system for assigning a value to a naphtha sample based upon naphthene and aromatic content of a reformate fraction of the naphtha sample at a target research octane number, the system comprising:
a non-volatile memory device that stores calculation modules and data, the data including naphthene and aromatic content of the reformate fraction;
a processor coupled to the memory;
a first calculation module that calculates and assigns a total products yield as a function of the naphthene content, the aromatic content and the target research octane number;
a second calculation module that calculates and assigns raw product yield to each of methane, ethane, propane, butane and gasoline as a function of the assigned total liquid products yield;
a third calculation module that calculates and assigns a raw product yield of hydrogen as a function of the assigned total liquid product yield and the target research octane number; and
a fourth calculation module that calculates and assigns values to each of hydrogen, methane, ethane, propane, butane and gasoline as a function of the raw product yields of each of hydrogen, methane, ethane, propane, butane and gasoline and a unit value of each product.

2. The system as in claim 1 , further comprising a gas chromatograph that outputs data indicative of the naphthene and aromatic content of a reformate fraction of the naphtha sample at a target research octane number;
wherein the data stored by the non-volatile memory device that stores calculation modules and data includes the outputted naphthene and aromatic content of the reformate fraction of the naphtha sample at the target research octane number.

3. A method for operating a computer to assign a value to a naphtha sample based upon naphthene and aromatic content of a reformate fraction of the naphtha sample at a target research octane number, the method comprising:
entering into the computer data indicative of naphthene and aromatic content of the reformate fraction;
calculating and assigning a total products yield as a function of the naphthene content, the aromatic content and the target research octane number;
calculating and assigning a raw product yield to each of methane, ethane, propane, butane and gasoline as a function of the assigned total liquid products yield;
calculating and assigning a raw product yield of hydrogen as a function of the assigned total liquid product yield and the target research octane number; and
calculating and assigning a value to each of hydrogen, methane, ethane, propane, butane and gasoline as a function of the raw product yields of each of hydrogen, methane, ethane, propane, butane and gasoline and a unit value of each product.

4. The method as in claim 3 , further comprising operating a gas chromatograph to obtain the data indicative of the naphthene and aromatic content of a reformate fraction of the naphtha sample at a target research octane number.

5. A system for determining the relative value of a stream of treated naphtha based upon a separately provided PIONA analysis of the fractions of the naphtha after processing in a reformer that is operated at a severity that yields a gasoline product having a predetermined constant research octane number, the system comprising:
a memory that stores calculation modules and data, the data indicative of the content naphthenes and aromatics derived from the separately provided PIONA analysis of the fractions of the naphtha;
a processor coupled to the memory;
a calculation module that calculates and assigns the total liquid products yield as a function of the naphthene content, the aromatic content and the constant research octane number;
a calculation module that calculates and assigns raw product yield to each of methane, ethane, propane, butane and gasoline as a function of the assigned total liquid products yield;
a calculation module that calculates and assigns raw product yield of hydrogen as a function of the total liquid products yield and the constant research octane number (RON);
a calculation module that calculates and assigns values to each of hydrogen, methane, ethane, propane, butane and gasoline as a function of the raw product yields of each of hydrogen, methane, ethane, propane, butane and gasoline, and a unit value of each product.

6. The system of claim 5 in which the treated naphtha stream contains less than 0.5 ppmw of sulfur and less than 0.5 ppmw nitrogen.

7. The system of claim 5 in which the RON is selected from the range of from 95 to 100.

8. The system of claim 7 in which the RON is selected from the range of from 95 to 98.

9. A method for operating a computer to determine the relative value of a treated naphtha stream derived from a crude oil sample obtained from a particular source, the method comprising:
entering into the computer data indicative of the content naphthenes and aromatics derived from a separately provided PIONA analysis of the fractions of the naphtha stream that is processed in a reformer operated under conditions that produce a gasoline product having a predetermined constant research octane number;
calculating and assigning the total liquid products yield as a function of the naphthene content, the aromatic content and the constant research octane number;
calculating and assigning raw product yield to each of methane, ethane, propane, butane and gasoline as a function of the total liquid products yield;
calculating and assigning raw product yield for hydrogen as a function of the total liquid products yield and the constant research octane number;
calculating and assigning a to each of hydrogen, methane, ethane, propane, butane and gasoline as a function of the raw product yield to each of hydrogen, methane, ethane, propane, butane and gasoline, and a predetermined unit value for each product.

10. The method of claim 9 in which the treated naphtha stream contains less than 0.5 ppmw of sulfur and less than 0.5 ppmw of nitrogen.

11. The method of claim 9 in which the RON is selected from the range of from 95 to 100.

12. The method of claim 9 which includes the further steps of entering PIONA analyses from a plurality of samples derived from different crude oils and compiling the calculated estimated values for each of the treated naphthas to provide a listing of comparative values based upon a constant RON.

Assignees

• Saudi Arabian Oil Co
• Saudi Arabain Oil Company

Inventors

• Koseoglu Omer Refa

Classifications

• G01N2030/025

  Gas chromatography · CPC title

• G01N30/02

  Column chromatography · CPC title

• G01N33/2829 Primary

  Mixtures of fuels · CPC title

• G16C20/30

  Prediction of properties of chemical compounds, compositions or mixtures · CPC title

• C10G2400/02

  Gasoline · CPC title