Al—Sc alloy manufacturing method

Patent metadata

Field	Value
Publication number	US-9422611-B2
Application number	US-201314424348-A
Country	US
Kind code	B2
Filing date	Jun 26, 2013
Priority date	Jun 26, 2013
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

Provided is a method of producing an Al—Sc based alloy suitable for production of an Al—Sc based alloy that: eliminates the needs for equipment for heating in an inert gas atmosphere or a vacuum atmosphere, a reducing agent such as metal Ca, and equipment and power for molten salt electrolysis; can be performed adequately by heating up to 1,050° C.; and enables continuous operation. The method of producing an Al—Sc based alloy includes: loading into a reaction vessel metal aluminum (Al), a metal fluoride salt, and a scandium compound; elevating a temperature of a reaction system to from 700 to 1,050° C. to form a molten metal layer including molten metal aluminum serving as a lower layer and a molten salt layer in which the metal fluoride salt and the scandium compound are melted serving as an upper layer; and transferring a scandium ion (Sc 3+ ) generated in the molten salt layer side to the molten metal layer side. The metal fluoride salt has a melting temperature lower than the reaction temperature and has a density in a range of from 70 to 95% of the density of the molten metal aluminum, at the reaction temperature.

First claim

The invention claimed is:

1. A method of producing an Al—Sc based alloy,
the method comprising:
loading into a reaction vessel metal aluminum (Al), one or more metal fluoride salts selected from the group consisting of: an alkali metal fluoride; an alkaline earth metal fluoride; and aluminum fluoride, and a scandium compound comprising an oxide and/or fluoride salt of scandium (Sc);
elevating a temperature of a reaction system in the reaction vessel comprising the metal aluminum (Al), the metal fluoride salt, and the scandium compound to a reaction temperature to form a molten metal layer comprising molten metal aluminum and a molten salt layer in which the metal fluoride salt is melted and the scandium compound is dissolved to generate a scandium ion (Sc 3+ ); and
transferring the scandium ion (Sc 3+ ) generated on a molten salt layer side to a molten metal layer side,
the reaction temperature of the reaction system being set in a range of from 700 to 1,050° C.,
the metal fluoride salt to be used comprising a metal fluoride salt having a melting temperature lower than the reaction temperature and having a density in a range of from 70 to 95% of a density of the molten metal aluminum at the reaction temperature of the reaction system,
the molten salt layer and the molten metal layer serving as an upper layer and a lower layer, respectively, in the reaction system in the reaction vessel, wherein
the alkaline earth metal fluoride is selected from the group consisting of BeF 2 , MgF 2 and CaF 2 .

2. A method of producing an Al—Sc based alloy according to claim 1 ,
the method comprising:
loading into a reaction vessel metal aluminum (Al) and a metal fluoride salt;
elevating a temperature to a reaction temperature to form a molten metal layer and a molten salt layer; and
thereafter, adding a scandium compound into the molten salt layer to generate a scandium ion (Sc 3+ ) in the molten salt layer.

3. A method of producing an Al—Sc based alloy according to claim 1 , wherein the metal fluoride salt comprises a mixture of lithium fluoride and sodium fluoride.

4. A method of producing an Al—Sc based alloy according to claim 1 , wherein the reaction system in the reaction vessel satisfies a relationship of 0.3≦(F Sc −C Sc )/P Sc ≦1.5, where F Sc represents a target Sc concentration in the Al—Sc based alloy in terms of molar percentage (mol %), P Sc represents a Sc 3+ concentration in the molten salt layer in terms of molar percentage, and C Sc represents a Sc concentration in the molten metal layer in terms of molar percentage.

Assignees

• Nippon Light Metal Co

Inventors

• Sugita Kaoru
• YATSUKURA Masato

Classifications

• C22B21/062

  using salt or fluxing agents (C22B21/064, C22B21/066, and C22B21/068 take precedence) · CPC title

• C22C1/026 Primary

  Alloys based on aluminium · CPC title

• C22C21/00

  Alloys based on aluminium · CPC title