Polyethylene with high melt strength for use in films

Patent metadata

Field	Value
Publication number	US-9422425-B2
Application number	US-201113515832-A
Country	US
Kind code	B2
Filing date	Jan 11, 2011
Priority date	Jan 11, 2010
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

The present invention is a method for producing a film particularly well suited for shrink film applications, said method comprising the steps of selecting a target polyethylene resin and then increasing the melt strength of the polyethylene resin by reacting the polyethylene resin with an alkoxy amine derivative, and then forming a film from the reacted target polyethylene.

First claim

What is claimed is:

1. A method for producing film, said method comprising the steps of:
a) blending an alkoxy amine derivative with a low density polyethylene to form a masterbatch;
b) selecting a target polyethylene resin having a density as determined according to ASTM D792, in the range of from 0.92 g/cm 3 to 0.94 g/cm 3 , and a melt index, as determined according to ASTM D1238 (2.16 kg, 190° C.), in the range of from 0.01 g/10 min to 10 g/10 min; where the target polyethylene is a linear low density polyethylene;
c) blending the masterbatch with the target polyethylene in an amount and under conditions sufficient to increase the melt strength of the polyethylene resin; where the amount of the alkoxy amine derivative is less than 900 parts per million based on a weight of total polyethylene resin; and
d) blending a composition of c) with 10 to 90 percent by weight of a low density polyethylene composition to form a blend d) that contains the alkoxy amine derivative in an amount of 1 to 400 ppm;
e) forming a film from the blend d).

2. The method of claim 1 wherein the alkoxy amine derivative corresponds to the formula:
(R 1 )(R 2 )N—O—R 3

where R 1 and R 2 are each independently of one another, hydrogen, C 4 -C 42 alkyl or C 4 -C 42 aryl or substituted hydrocarbon groups comprising O and/or N, and where R 1 and R 2 may form a ring structure together; and R 3 is hydrogen, a hydrocarbon or a substituted hydrocarbon group comprising O and/or N.

3. The method of claim 1 wherein the alkoxy amine derivative is a hydroxylamine ester.

4. The method of claim 3 wherein the hydroxyl amine ester is hydroxyl amine ester being 9-(acetyloxy)-3,8,10-triethyl-7,8,10-trimethyl-1,5-dioxa-9-azaspiro[5.5]undec-3-yl]methyl octadecanoate.

5. The method of claim 1 wherein the resulting film is a shrink film.

6. A film comprising:
a) from 10 to 90 percent by weight of a polyethylene polymer made by the process of:
i) selecting a target polyethylene resin having a density, as determined according to ASTM D792, in the range of from 0.92 g/cm 3 to 0.94 g/cm 3 , and a melt index, as determined according to ASTM D1238 (2.16 kg, 190° C.), in the range of from 0.01 g/10 min to 10 g/10 min;

where the target polyethylene is a linear low density polyethylene;
ii) blending an alkoxy amine derivative with a low density polyethylene to form a masterbatch;
iii) blending the masterbatch with the target polyethylene in an amount and under conditions sufficient to increase the melt strength of the polyethylene resin, where the amount of the alkoxy amine derivative is less than 900 parts per million based on a weight of total polyethylene resin; and
b) adding from 10 to 90 percent by weight of a low density polyethylene composition to a blend obtained in iii) to form a composition that contains the alkoxy amine derivative in an amount of 1 to 400 ppm.

7. The film of claim 6 wherein said target polyethylene has a density in the range of from 0.920 to 0.935 g/cm 3 .

8. The film of claim 6 , wherein said target polyethylene has a melt index in the range of 0.01 to 3 g/10 minutes.

9. The film of claim 6 , wherein said target polyethylene has a molecular weight distribution, M w /M n , of less than about 5.

10. The film of claim 6 , wherein said film has a MD shrink tension of greater than 20 cN and a haze of less than 15%.

11. The film of claim 6 , wherein said film has MD tear greater than 100 g and a CD tear greater than 700 g.

12. The film of claim 6 , wherein the melt flow ratio of I 10 /I 2 of the target polyethylene is greater than 9.

13. The film of claim 6 , wherein [Viscosity at 0.1 rad/s]/[Viscosity at 100 rad/s] of the target polyethylene measured at 190° C. is greater than 8.

14. The film of claim 6 , wherein tan delta at 0.1 rad/s of the target polyethylene measured at 190° C. is less than 4.

15. The film of claim 6 , wherein melt strength of the target polyethylene measured as the plateau force (cN) at 190° C. is greater than 5.

16. The film of claim 6 , wherein the gpcBR of the target polyethylene is greater than 0.03.

Assignees

• Karjala Teresa P
• Mazzola Nicolas Cardoso
• Demirors Mehmet
• Gomes Jorge Caminero
• Terrasa Michael A
• Dow Global Technologies Llc
• Dow Brasil Sa

Inventors

• Karjala Teresa P
• Mazzola Nicolas Cardoso
• Demirors Mehmet
• Gomes Jorge Caminero
• Terrasa Michael A

Classifications

• B29D7/01

  Films or sheets · CPC title

• C08L23/0815 Primary

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/26

  modified by chemical after-treatment (saponified copolymers C08L23/0861; unsaturated acid salts C08L23/0876) · CPC title

• C08K5/3435

  Piperidines · CPC title

• C08L23/02

  not modified by chemical after-treatment · CPC title