Method for synthesis of lactic acid and its derivatives and catalyst for preparing same

Patent metadata

Field	Value
Publication number	US-9422216-B2
Application number	US-201314424760-A
Country	US
Kind code	B2
Filing date	Aug 27, 2013
Priority date	Aug 27, 2012
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

The present disclosure provides a catalyst for preparing lactic acid and derivatives thereof, comprising at least one of metallic compounds MX n , wherein M is selected from Na, K, Mg, Ca, Sr, Ba, Al, Ga, In, Sn, Sb, Bi, Cr, Mn, Fe, Co, Ni and Zn, and n is an integer of 1 to 6. The present disclosure further provides a method for synthesis of lactic acid and derivatives thereof, wherein at least one raw material including carbohydrates, at least one alcohol, at least one of the aforesaid catalysts and at least one solvent are heated to react to prepare lactic acid and derivatives thereof.

First claim

What is claimed is:

1. A catalyst for preparing lactic acid and derivatives thereof, comprising at least one of metallic compounds MX n , wherein M is selected from Li, Na, K, Mg, Ca, Sr, Ba, Al, Ga, In, Sn, Sb, Bi, Cr, Mn, Fe, Co, Ni and Zn, n is an integer of 1 to 6; the anion X of the metallic compound MX n is selected from F − , Cl − , Br − , I − , SO 4 2− , HSO 4 − , CH 3 SO 3 − , C 6 H 5 SO 3 − , H 2 PO 4 − , HPO 4 2− , PO 4 3− , PF 6 − , BO 2 − , BF 4 − , SiF 6 2− and CH 3 CO 2 − ; the catalyst comprise at least two of the metallic compounds MX n , at least one of which is a metal halide.

2. The catalyst for preparing lactic acid and derivatives thereof of claim 1 , wherein the metal ion in the metallic compound MX n is selected from Li + , Na + , K + , Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ , Al 3+ , Ga 3+ , In 3+ , Sn 2+ , Sn 4+ , Sb 3+ , Bi 3+ , Cr 3+ , Cr 6+ , Mn 2+ , Fe 2+ , Fe 3+ , Co 2+ , Ni 2+ and Zn 2+ .

3. The catalyst for preparing lactic acid and derivatives thereof of claim 1 , wherein the anion of the metallic compound MX n is selected from F − , Cl − , Br − , I − , SO 4 2− , HSO 4 − , CH 3 SO 3 − , C 6 H 5 SO 3 − and CH 3 CO 2 − .

4. The catalyst for preparing lactic acid and derivatives thereof of claim 1 , wherein the metal halide is a metal chloride.

5. The catalyst for preparing lactic acid and derivatives thereof of claim 4 , wherein the metal chloride is SnCl 2 , SnCl 4 or SbCl 3 .

6. The catalyst for preparing lactic acid and derivatives thereof of claim 5 , wherein the catalyst is selected from any one of combinations of SnCl 2 and MgCl 2 , combinations of SnCl 2 and NaCl, combinations of SnCl 2 and CaCl 2 , combinations of SnCl 2 and AlCl 3 , combinations of SnCl 2 and FeCl 3 , combinations of SnCl 2 and SbCl 3 , combinations of SnCl 2 and ZnCl 2 , and combinations of SnCl 2 and ZnBr 2 .

7. The catalyst for preparing lactic acid and derivatives thereof of claim 5 , wherein the catalyst is selected from any one of combinations of SbCl 3 and CrCl 3 , combinations of SbCl 3 and NaCl, combinations of SbCl 3 and CaCl 2 , combinations of SbCl 3 and AlCl 3 , combinations of SbCl 3 and FeCl 3 , combinations of SbCl 3 and ZnCl 2 , and combinations of SbCl 3 and ZnBr 2 .

8. A method for synthesis of lactic acid and derivatives thereof, comprising heating combinations of at least one raw material comprising carbohydrates, at least one alcohol, at least one catalyst and at least one solvent to make the combinations react, wherein the at least one catalyst is the catalyst of claim 1 .

9. The method for synthesis of lactic acid and derivatives thereof of claim 8 , wherein the raw material comprising carbohydrates is selected from at least one of monosaccharides and polysaccharides.

10. The method for synthesis of lactic acid and derivatives thereof of claim 9 , wherein the raw material comprising carbohydrates is selected from at least one of starch, glucan, sucrose, fructose and glucose.

11. The method for synthesis of lactic acid and derivatives thereof of claim 8 , wherein the raw material comprising carbohydrates is selected from at least one of lignocelluloses.

12. The method for synthesis of lactic acid and derivatives thereof of claim 11 , wherein the raw material comprising carbohydrates is selected from at least one of cotton, bagasse, corn cob, cottonseed shell, wheat straw, rice straw, and microcrystalline cellulose.

13. The method for synthesis of lactic acid and derivatives thereof of claim 8 , wherein the alcohol is selected from at least one of monohydric alcohols, dihydric alcohols and polyhydric alcohols.

14. The method for synthesis of lactic acid and derivatives thereof of claim 13 , wherein the monohydric alcohol is selected from at least one of methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and tert-butanol.

15. The method for synthesis of lactic acid and derivatives thereof of claim 13 , wherein the dihydric alcohol is selected from at least one of ethylene glycol, 1,2-propylene glycol, and 1,3-propylene glycol.

16. The method for synthesis of lactic acid and derivatives thereof of claim 13 , wherein the polyhydric alcohol is glycerol.

17. The method for synthesis of lactic acid and derivatives thereof of claim 8 , wherein the solvent is a polar solvent which is selected from at least one of water, alcohols, and fatty acid methyl esters of C8-C22.

18. The method for synthesis of lactic acid and derivatives thereof of claim 17 , wherein the solvent is selected from at least one of methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, tert-butanol, ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, and glycerol.

19. The method for synthesis of lactic acid and derivatives thereof of claim 8 , wherein a heating temperature is 80° C.-130° C.

20. The method for synthesis of lactic acid and derivatives thereof of claim 19 , wherein the heating temperature is 120° C.-130° C.

21. The catalyst for preparing lactic acid and derivatives thereof of claim 1 , wherein a heating temperature is 80° C.-130° C.

22. The catalyst for preparing lactic acid and derivatives thereof of claim 21 , wherein the heating temperature is 120° C.-130° C.

Assignees

• Microvast Power Systems Co Ltd
• Microvast Power Systems Co Ltd

Inventors

• Zhou Xiaoping

Classifications

• C07C67/08

  by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

• C07C67/00

  Preparation of carboxylic acid esters · CPC title

• C07C51/00 Primary

  Preparation of carboxylic acids or their salts, halides or anhydrides (of acids by hydrolysis of oils, fats or waxes C11C) · CPC title

• C01G51/085

  Chlorides; Oxychlorides · CPC title

• C01G37/04

  Chromium halides · CPC title