Process for producing 2,3,3,3-tetrafluoropropene

Patent metadata

Field	Value
Publication number	US-9422211-B2
Application number	US-201314408339-A
Country	US
Kind code	B2
Filing date	Aug 7, 2013
Priority date	Aug 8, 2012
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

The present invention provides a process for producing 2,3,3,3-tetrafluoropropene, comprising the steps of producing 2-chloro-3,3,3-trifluoropropene by reacting anhydrous hydrogen fluoride with a specific chlorine-containing compound in a gas phase in the presence of a fluorination catalyst while heating; and producing 2,3,3,3-tetrafluoropropene by reacting 2-chloro-3,3,3-trifluoropropene with anhydrous hydrogen fluoride in a gas phase in the presence of a fluorination catalyst while heating, the step of producing 2-chloro-3,3,3-trifluoropropene being performed after the step of producing 2,3,3,3-tetrafluoropropene. According to the process, 2,3,3,3-tetrafluoropropene can be produced with reduced energy and equipment costs in an economically advantageous manner.

First claim

The invention claimed is:

1. A process for producing 2,3,3,3-tetrafluoropropene, comprising the steps of:
producing 2-chloro-3,3,3-trifluoropropene by reacting anhydrous hydrogen fluoride with at least one chlorine-containing compound selected from the group consisting of 1,1,1,2,3-pentachloropropane, 2,3-dichloro-1,1,1-trifluoropropane, and 1,1,2,3-tetrachloropropene in a gas phase in the presence of a fluorination catalyst while heating to produce products comprising 2-chloro-3,3,3-trifluoropropene; and
producing 2,3,3,3-tetrafluoropropene by reacting 2-chloro-3,3,3-trifluoropropene with anhydrous hydrogen fluoride in a gas phase in the presence of a fluorination catalyst while heating to produce products comprising 2,3,3,3-tetrafluoropropene,
the step of producing 2,3,3,3-tetrafluoropropene is performed upstream of the step of producing 2-chloro-3,3,3-trifluoropropene, and
wherein 2,3,3,3-tetrafluoropropene can be continuously produced by circulating 2-chloro-3,3,3-trifluoropropene obtained in the trifluoropropene-producing step to the step of producing 2,3,3,3-tetrafluoropropene.

2. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 , wherein the reaction temperature in the step of producing 2,3,3,3-tetrafluoropropene is higher than the reaction temperature in the step of producing 2-chloro-3,3,3-trifluoropropene.

3. The process for producing 2,3,3,3-tetrafluoropropene according to claim 2 , wherein the reaction temperature in the step of producing 2,3,3,3-tetrafluoropropene is 300 to 450° C., and the reaction temperature in the step of producing 2-chloro-3,3,3-trifluoropropene is 200 to 380° C.

4. The process for producing 2,3,3,3-tetrafluoropropene according to claim 2 , further comprising the step of reheating the products of the step of producing 2-chloro-3,3,3-trifluoropropene.

5. The process for producing 2,3,3,3-tetrafluoropropene according to claim 4 , wherein the step of reheating the products of the step of producing 2-chloro-3,3,3-trifluoropropene comprises elevating the temperature of a portion of the outlet side of a reactor used in the step of producing 2-chloro-3,3,3-trifluoropropene to a temperature higher than that of the other portions of the reactor.

6. The process according to claim 4 , wherein the step of reheating the products of the step of producing 2-chloro-3,3,3-trifluoropropene comprises heating the products using a reactor for reheating disposed downstream of the reactor used in the step of producing 2-chloro-3,3,3-trifluoropropene.

7. The process according to claim 1 , wherein the fluorination catalyst used in the step of producing 2,3,3,3-tetrafluoropropene comprises at least one member selected from the group consisting of chromium oxides, fluorinated chromium oxides, aluminum oxides, and fluorinated aluminum oxides.

8. The process according to claim 1 , wherein each of the fluorination catalyst used in the step of producing 2-chloro-3,3,3-trifluoropropene and the fluorination catalyst used in the step of producing 2,3,3,3-tetrafluoropropene is a chromium oxide represented by the composition formula: CrOm (1.5<m<3) or a fluorinated chromium oxide obtained by fluorinating the chromium oxide.

9. The process according to claim 4 , further comprising the steps of:
separating 2,3,3,3-tetrafluoropropene from the products of the step of producing 2-chloro-3,3,3-trifluoropropene or from the products of the step of reheating the products of the step of producing 2-chloro-3,3,3-trifluoropropene; and
circulating a fraction containing 2-chloro-3,3,3-trifluoropropene to the step of producing 2,3,3,3-tetrafluoropropene as a starting material.

10. The process according to claim 9 , wherein the separation of 2,3,3,3-tetrafluoropropene from the products of the step of producing 2-chloro-3,3,3-trifluoropropene or from the products of the step of reheating the products of the step of producing 2-chloro-3,3,3-trifluoropropene is performed by distillation.

Assignees

• Daikin Ind Ltd

Inventors

• Takahashi Kazuhiro
• Motoyama Hitoshi
• Chaki Takehiro
• Karube Daisuke
• Kishimoto Masayuki

Classifications

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• C07C17/25

  by splitting-off hydrogen halides from halogenated hydrocarbons · CPC title

• C07C17/20 Primary

  of halogen atoms by other halogen atoms · CPC title

• C07C17/206 Primary

  the other compound being HX · CPC title

• C07C21/18

  containing fluorine · CPC title