Treatment of aromatic hydrocarbon stream

Patent metadata

Field	Value
Publication number	US-9422208-B2
Application number	US-201414221764-A
Country	US
Kind code	B2
Filing date	Mar 21, 2014
Priority date	May 7, 2013
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

The invention is directed to a process of contacting at least one zeolite, selected from the MWW family of zeolites, with an aromatic hydrocarbon stream in a system comprising at least one reactor containing the at least one zeolite, wherein the conditions in the reactor are adjusted in response to at least one measurement of the system so as to preferentially increase oxygenate removal or to preferentially increase olefin removal.

First claim

What is claimed is:

1. A process comprising contacting an aromatic hydrocarbon stream comprising xylenes, olefins, and oxygenates, in at least two reactors containing at least one zeolite independently selected from the MWW family of zeolites, to produce a product stream from said reactor,
wherein at least one condition of contacting in each reactor is individually adjusted in response to at least one measurement of a system comprising said zeolite, said aromatic hydrocarbon stream, said reactor, and said product stream, so as to preferentially increase oxygenate removal or to preferentially increase olefin removal from said aromatic hydrocarbon stream in each individual reactor,
wherein said at least one condition of contacting is selected from the temperature and/or space velocity of said aromatic hydrocarbon stream, the temperature of said zeolite, and combinations thereof.

2. The process of claim 1 , wherein said measurement is correlated with the concentration of at least one oxygenate or olefin at one or more than one location in said system.

3. The process of claim 1 , wherein hydrogen gas is present in said at least two reactors.

4. The process of claim 1 , wherein hydrogen gas is not present in said at least two reactors.

5. The process of claim 3 , wherein hydrogen gas is intermittently supplied to said at least two reactors.

6. The process of claim 1 , wherein the aromatic hydrocarbon stream is selected from at least one of (a) imported aromatic hydrocarbon streams that are subject to exposure to an oxygen-containing environment at some point in processing; (b) product steams from xylene production involving transalkylation, isomerization, alkylation, extraction, reforming, disproportionation, and mixtures thereof.

7. The process of claim 1 , wherein downstream of said reactors there is at least one process selected from: (i) a process comprising the isolation of at least one of the isomers of xylene, preferably crystallization or adsorptive separation; (ii) a manufacturing process comprising the production of polyester or a precursor thereof, starting from paraxylene; and/or (iii) the isomerization of a non-equilibrium xylenes mixture to equilibrium, such as by vapor-phase or liquid-phase isomerization.

8. The process of claim 1 , wherein the aromatic hydrocarbon stream that contacts the at least one zeolite selected from the MWW family of zeolites is derived from an alkylation reaction comprising contact of an alkylating agent including methanol and/or dimethylether (DME) with benzene and/or toluene in the presence of an acid active molecular sieve catalyst in an alkylation reactor wherein said catalyst and alkylation reactor conditions are effective to produce an alkylation reactor product comprising paraxylene in greater than equilibrium amounts, co-produce oxygenates such as phenol, optionally C9+ aromatic hydrocarbons, non-aromatic hydrocarbons including styrene and optionally light gases, and optionally unreacted components including the alkylation agent (methanol and/or DME), water, benzene and/or toluene.

9. The process of claim 8 , wherein the product of the alkylation reactor is separated into one or more constituent parts, and at least one of said constituent parts comprises said paraxylene.

10. The process of claim 8 , comprising:
(a) optionally separating said alkylation reactor product into separate streams, at least a portion of at least one of which is recycled to said alkylation reactor, said separate streams selected from (i) one or more streams comprising unreacted components, (ii) one or more streams comprising oxygenates; (iii) one or more streams comprising olefins; (iv) at least one stream comprising paraxylene; (v) at least one stream comprising C9+ aromatics, if present; (vi) at least one stream comprising light gases, if present;
(b) measuring the concentration of at least one oxygenate and/or at least one olefin in the paraxylene product and/or one or more of said separate streams;
(c) measuring the concentration of said at least one oxygenate and/or at least one olefin in said the feed to said alkylation reaction, optionally wherein said feed includes said recycle;
(d) contacting at least one of (i) said product, (ii) at least one of said separate streams, (iii) at least one recycle, where present; (iv) at least one or more streams comprising olefins; (v) at least one or more streams comprising oxygenates, where present; with at least one zeolite independently selected from the MWW family of zeolites in at least two reactors under conditions effective to reduce the level of oxygenates and/or olefins, if present; and
(e) adjusting at least one of the temperature and/or space velocity of said aromatic hydrocarbon stream, the temperature of said zeolite, or combinations thereof in at least one of said at least two reactors so as to increase the amount of olefin removed and/or increase the amount of oxygenate removed in step (d).

11. The process of claim 1 , wherein the at least one zeolite from the MWW family of molecular sieves is selected from MCM-22, MCM-36, MCM-49, MCM-56, and EMM-10.

12. The process of claim 1 , wherein the at least one zeolite is used mixed with or in series with a clay.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Bender Timothy P
• Wang Chong Jhoo
• Heeter Glenn A
• Pilliod Dana L

Classifications

• C07C7/13

  by molecular-sieve technique · CPC title

• C07C2/865

  the non-hydrocarbon is an ether · CPC title

• C07C2/864 Primary

  the non-hydrocarbon is an alcohol · CPC title

• C07C7/14

  by crystallisation; Purification or separation of the crystals · CPC title

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title