Ultrahard nanotwinned boron nitride bulk materials and synthetic method thereof

Patent metadata

Field	Value
Publication number	US-9422161-B2
Application number	US-201314407017-A
Country	US
Kind code	B2
Filing date	Aug 2, 2013
Priority date	Aug 3, 2012
Publication date	Aug 23, 2016
Grant date	Aug 23, 2016

Abstract

The invention relates to an ultrahard nanotwinned boron nitride bulk material and synthetic method thereof. Particularly, the invention discloses a nanocrystalline cubic boron nitride bulk material containing high density of twins and synthetic method thereof, in which a nanotwinned boron nitride bulk are synthesized from nanospherical boron nitride particles (preferably with a size of 5-70 nm) with onion-like structure as raw materials by using high temperature and high pressure synthesis. As compared with the prior arts, the nanotwinned boron nitride bulk obtained according to the invention has a much higher hardness than that of a normal cubic boron nitride single crystal. The nanotwinned boron nitride bulk has great prospects in applications, such as precision and ultra-precision machining, abrasives, drawing dies, and special optics as well as other fields.

First claim

The invention claimed is:

1. Preparation method for high pressure synthesis of an ultrahard nanotwinned cubic boron nitride bulk material, which has an internal nanocrystalline cubic structure, a grain size of 5-100 nm, a Vickers hardness of 60-120 GPa, and a density of 5-30% twin structure inside the grains, wherein said hardness is determined by varying the load until the measured hardness reaches an asymptotic value independent of the applied loads, comprising the following steps:
(1) Placing nanospherical BN particles with onion-like structure as raw materials into a mold and pressing them into a preform;
(2) Loading the preform into a high pressure synthetic mold, and synthesizing under 4-25 GPa and 1200-2300° C.; and
(3) Decompressing and cooling.

2. Preparation method according to claim 1 , wherein the Vickers hardness of the nanotwinned boron nitride bulk material is 60-120 GPa.

3. Preparation method according to claim 2 , wherein the volume of the ultrahard nanotwinned boron nitride bulk material is 1-2000 mm 3 .

4. Preparation method according to claim 2 , wherein the ultrahard nanotwinned boron nitride bulk material comprises high density of twins inside, and is a nanocrystal with zincblende structure and a grain size of 5-100 nm.

5. Preparation method according to claim 1 , wherein the volume of the ultrahard nanotwinned boron nitride bulk material is 2-2000 mm 3 .

6. Preparation method according to claim 1 , wherein the ultrahard nanotwinned boron nitride bulk material comprises high density of twins inside, and is a nanocrystal with zincblende structure and a grain size of 5-100 nm.

7. Preparation method according to claim 1 , wherein the particle size of the nanospherical BN particles with onion-like structure is 5-70 nm.

8. Preparation method according to claim 1 , wherein the Step ( 2 ) is performed for 1-120 min.

9. Ultrahard nanotwinned cubic boron nitride bulk material, which has an internal nanocrystalline cubic structure, a grain size of 5-100 nm, a Vickers hardness of 60-120 GPa, and a density of 5-30% twin structure inside the grains, wherein said hardness is determined by varying the load until the measured hardness reaches an asymptotic value independent of the applied loads.

10. Ultrahard nanotwinned cubic boron nitride bulk material according to claim 9 , wherein the volume of the boron nitride bulk material is 1-2000 mm 3 .

11. Ultrahard nanotwinned cubic boron nitride bulk material according to claim 10 , wherein the fracture toughness (K IC ) of the ultrahard nanotwinned boron nitride bulk material is 5-15 MPa·M 1/2 .

12. Ultrahard nanotwinned cubic boron nitride bulk material according to claim 9 , wherein the crystal structure of ultrahard nanotwinned boron nitride bulk material is a single phase cubic zincblende structure, with optionally a small amount of hexagonal wurtzite phase structure, and the twin structure inside the grains has a twin thickness of 2-15 nm.

13. Ultrahard nanotwinned cubic boron nitride bulk material according to claim 12 , wherein the fracture toughness (K IC ) of the ultrahard nanotwinned boron nitride bulk material is 5-15 MPa·m 1/2 .

14. Ultrahard nanotwinned cubic boron nitride bulk material according to claim 9 , wherein the fracture toughness (K IC ) of the ultrahard nanotwinned boron nitride bulk material is 5-15 MPa·m 1/2 .

Assignees

• Univ Yanshan

Inventors

• Tian Yongjun
• Yu Dongli
• Xu Bo
• He Julong
• Liu Zhongyuan
• Hu Wentao
• Luo Kun
• Gao Yufei
• Zhao Zhisheng

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C04B2235/723

  Oxygen content · CPC title

• C04B2235/5409

  expressed by specific surface values · CPC title

• C04B2235/5454

  nanometer sized, i.e. below 100 nm · CPC title

• C04B35/645

  Pressure sintering · CPC title