Electrolyte for rechargeable lithium battery and rechargeable lithium battery including same

Patent metadata

Field	Value
Publication number	US-9419305-B2
Application number	US-201313872945-A
Country	US
Kind code	B2
Filing date	Apr 29, 2013
Priority date	Apr 30, 2012
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

An electrolyte for rechargeable lithium battery includes a lithium salt, a non-aqueous organic solvent, a first additive represented by the following Chemical Formula 1, and a second additive represented by the following Chemical Formula 2.

A rechargeable lithium battery includes the electrolyte.

First claim

What is claimed is:

1. An electrolyte for a rechargeable lithium battery, the electrolyte comprising:
a lithium salt,
a non-aqueous organic solvent,
a first additive represented by the following Chemical Formula 1, and
a second additive represented by the following Chemical Formula 2:

wherein, in Chemical Formula 1, A is phosphorus (P), X is a halogen, n is an integer ranging from 0 to 2, m is an integer ranging from 1 to 3, and n+m=3,

wherein in Chemical Formula 2, R 1 to R 9 are each independently selected from the group consisting of hydrogen, a substituted C1 to C10 alkyl group, and an unsubstituted C1 to C10 alkyl group.

2. The electrolyte for a rechargeable lithium battery of claim 1 , wherein the first additive comprises a compound selected from the group consisting of compounds represented by the following Chemical Formulae 1c to 1e and combinations thereof:

3. The electrolyte for a rechargeable lithium battery of claim 1 , wherein the first additive is included at about 0.1 wt % to about 5 wt % based on the total weight of the electrolyte and the second additive is included at about 0.1 wt % to about 5 wt % based on the total weight of the electrolyte.

4. The electrolyte for rechargeable lithium battery of claim 1 , wherein the first additive is included at about 0.5 wt % to about 1.5 wt % based on the total weight of the electrolyte.

5. The electrolyte for rechargeable lithium battery of claim 1 , wherein the second additive is included at about 0.1 wt % to about 1 wt % based on the total weight of the electrolyte.

6. An electrolyte for a rechargeable lithium battery, the electrolyte comprising:
a lithium salt,
a non-aqueous organic solvent,
a first additive, and
a second additive,
wherein the first additive comprises a compound represented by the following Chemical Formula 1 d, and the second additive comprises a compound represented by the following Chemical Formula 2a:

7. The electrolyte for rechargeable lithium battery of claim 1 , wherein the non-aqueous organic solvent comprises ethylene carbonate (EC), ethylmethyl carbonate (EMC), and dimethyl carbonate (DMC), and the ethylene carbonate (EC) is included at greater than or equal to about 30 wt % based on the total weight of the non-aqueous organic solvent.

8. A rechargeable lithium battery, comprising:
a positive electrode including a positive active material layer,
a negative electrode including a negative active material layer, and
the electrolyte according to claim 1 .

9. A rechargeable lithium battery, comprising:
a positive electrode including a positive active material layer,
a negative electrode including a negative active material layer, and
an electrolyte,
wherein the positive active material layer comprises lithium metal oxide and activated carbon, and
wherein the electrolyte comprises:
a lithium salt,
a non-aqueous organic solvent,
a first additive represented by the following Chemical Formula 1, and
a second additive represented by the following Chemical Formula 2:

wherein, in Chemical Formula 1, A is boron (B) or phosphorus (P), X is a halogen, n is an integer ranging from 0 to 2, m is an integer ranging from 1 to 3, and when A is boron (B), n+m=2, and when A is phosphorus (P), n+m=3,

wherein in Chemical Formula 2, R 1 to R 9 are each independently selected from the group consisting of hydrogen, a substituted C1 to C10 alkyl group, and an unsubstituted C1 to C10 alkyl group.

10. The rechargeable lithium battery of claim 9 , wherein the activated carbon is included at about 0.01 wt % to about 20 wt % based on the total weight of the lithium metal oxide and activated carbon.

11. The rechargeable lithium battery of claim 8 , wherein the negative active material layer comprises soft carbon.

12. The rechargeable lithium battery of claim 8 , wherein the first additive is present on at least one of the positive electrode or the negative electrode, the second additive is present on at least one of the positive electrode or the negative electrode, the first additive is in the electrolyte at about 0.005 M to about 2 M, and the second additive is in the electrolyte at about 0.005 M to about 2 M.

13. The rechargeable lithium battery of claim 8 , wherein the rechargeable lithium battery further comprises a SEI (solid electrolyte interface) film on the surface of the negative electrode.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Choi Yeon-Joo
• Kim Young-Kee
• Ishida Sumihito

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/48

  of inorganic oxides or hydroxides · CPC title

• H01M4/36

  Selection of substances as active materials, active masses, active liquids · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title