Electrolyte membrane for solid polymer fuel cells, membrane electrode assembly having said electrolyte membrane, and solid polymer fuel cell

Patent metadata

Field	Value
Publication number	US-9419301-B2
Application number	US-201113994907-A
Country	US
Kind code	B2
Filing date	Nov 14, 2011
Priority date	Jan 7, 2011
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

An electrolyte membrane for solid polymer fuel cell includes a reinforce membrane made of nonwoven fibers and an electrolyte provided in a space among the nonwoven fibers. The nonwoven fibers have a non-uniform mass distribution in a plane of the electrolyte membrane. A mass of the nonwoven fibers per unit area in a region corresponding to at least part of a peripheral portion of a fuel cell-use gasket frame is greater than a mass of the nonwoven fibers per unit area in a region corresponding to a center portion of the gasket frame. The electrolyte membrane for solid polymer fuel cell is attached to the fuel cell-use gasket frame.

First claim

The invention claimed is:

1. An electrolyte membrane for a solid polymer fuel cell, comprising:
a reinforce membrane made of nonwoven fibers; and
an electrolyte provided in a space among the nonwoven fibers,
characterized in that the electrolyte membrane has a power generating region and a gasket frame region, the gasket frame region provided on an outer circumference of the power generating region, the nonwoven fibers having a mass per unit area continuously varying as a whole from the power generating region to the gasket frame region,
in that the nonwoven fibers have a non-uniform mass distribution in a plane of the electrolyte membrane, the mass of the nonwoven fibers per unity area ranging from 0.1mg/cm 2 to 1.5mg/cm 2 , and
in that the nonwoven fibers have a mass per unit area in a region corresponding to the gasket frame region and a region corresponding to at least part of a peripheral portion of the region corresponding to the gasket frame region which is greater than a mass per unit area in a region corresponding to a center portion of the power generating region,
wherein a mass per unit area of the nonwoven fibers of the power generating region increases from the region corresponding to the center portion of the power generating region to the outer circumference of the power generating region, and
wherein the nonwoven fibers have a mass per unit area in a region having a width corresponding to 10% of a length of a side of the power generating region from the gasket frame region which is greater than the mass per unit area in the region corresponding to the center portion of the power generating region.

2. An electrolyte membrane for a solid polymer fuel cell, comprising:
a reinforce membrane made of nonwoven fibers; and
an electrolyte provided in a space among the nonwoven fibers,
characterized in that the electrolyte membrane has a power generating region and a gasket frame region, the gasket frame region provided on an outer circumference of the power generating region, the nonwoven fibers having a mass per unit area continuously varying as a whole from the power generating region to the gasket frame region,
in that the nonwoven fibers have a non-uniform mass distribution in a plane of the electrolyte membrane, the mass of the nonwoven fibers per unity area ranging from 0.1mg/cm 2 to 1.5mg/cm 2 , and
in that the nonwoven fibers have a mass per unit area in a region corresponding to the gasket frame region and a region corresponding to at least part of a peripheral portion of the region corresponding to the gasket frame region which is greater than a mass per unit area in a region corresponding to a center portion of the power generating region,
wherein the nonwoven fibers have a mass per unit area in a region corresponding to a fuel gas inlet of the solid polymer fuel cell to which the electrolyte membrane is adaptable, the mass per unit area in the region corresponding to the fuel gas inlet of the solid polymer fuel cell being greater than the mass per unit area in the region corresponding to the center portion of the power generating region, and
wherein the nonwoven fibers have a mass per unit area in a region having a width corresponding to 30% of a length of a side of the power generating region provided with the fuel gas inlet of the solid polymer fuel cell to which the electrolyte membrane is adaptable, the mass per unit area in the region having the width corresponding to 30% of the length of the side of the power generating region being greater than the mass per unit area in the region corresponding to the center portion of the power generating region.

3. An electrolyte membrane for a solid polymer fuel cell, comprising:
a reinforce membrane made of nonwoven fibers; and
an electrolyte provided in a space among the nonwoven fibers,
characterized in that the electrolyte membrane has a power generating region and a gasket frame region, the gasket frame region provided on an outer circumference of the power generating region, the nonwoven fibers having a mass per unit area continuously varying as a whole from the power generating region to the gasket frame region,
in that the nonwoven fibers have a non-uniform mass distribution in a plane of the electrolyte membrane, the mass of the nonwoven fibers per unity area ranging from 0.1mg/cm 2 to 1.5mg/cm 2 , and
in that the nonwoven fibers have a mass per unit area in a region corresponding to the gasket frame region and a region corresponding to at least part of a peripheral portion of the region corresponding to the gasket frame region which is greater than a mass per unit area in a region corresponding to a center portion of the power generating region,
wherein the nonwoven fibers have a mass per unit area in a region corresponding to a fuel gas outlet of the solid polymer fuel cell to which the electrolyte membrane is adaptable, the mass per unit area in the region corresponding to the fuel gas outlet of the solid polymer fuel cell being greater than the mass per unit area in the region corresponding to the center portion of the power generating region, and
wherein the nonwoven fibers have a mass per unit area in a region having a width corresponding to 30% of a length of a side of the power generating region provided with the fuel gas outlet of the solid polymer fuel cell to which the electrolyte membrane is adaptable, the mass per unit in the region having the width corresponding to 30% of the length of the side of the power generating region area being greater than the mass per unit area in the region corresponding to the center portion of the power generating region.

4. The electrolyte membrane for the solid polymer fuel cell according to claim 1 ,
wherein the mass per unit area in the region corresponding to the gasket frame region and the region corresponding to the at least part of the peripheral portion of the region corresponding to the gasket frame region is greater than and smaller than 15 times as great as the mass per unit area in the region corresponding to the center portion of the power generating region.

5. The electrolyte membrane for the solid polymer fuel cell according to claim 1 ,
wherein the reinforce membrane has a thickness in the region corresponding to the gasket frame region and the region corresponding to the at least part of the peripheral portion of the region corresponding to the gasket frame region which is greater than and 15 times or less of a thickness in the region corresponding to the center portion of the power generating region.

6. The electrolyte membrane for the solid polymer fuel cell according to claim 1 ,
wherein the nonwoven fibers have a fiber diameter in the region corresponding to the gasket frame region and the region corresponding to the at least part of the peripheral portion of the region corresponding to the gasket frame region which is greater than and 15 times or less of a fiber diameter in the region corresponding to the center portion of the power generating region.

7. The electrolyte membrane for the solid polymer fuel cell according to claim 1 ,
wherein the nonwoven fibers are prepared through electrospinning.

8. The electrolyte membrane for the solid polymer fuel cell according to claim 1 ,
wherein the electrolyte membrane is a proton conductive ion exchange membrane.

9. The electrolyte membrane for the solid polymer fuel cell according to claim 2 ,
wherein the mass per unit area in the region corresponding to the gasket frame region and the region corresponding to the at least part of the peripheral portion of the region corresponding to the gasket frame region is greater than and smaller than 15 times as great as the mass per unit area in the region corresponding to the center porti

Assignees

• Mori Masahiro
• Kikuzumi Shinya
• Kawashima Tsutomu
• Ueyama Yasuhiro
• Kubota Kazunori
• Panasonic Ip Man Co Ltd

Inventors

• Mori Masahiro
• Kikuzumi Shinya
• Kawashima Tsutomu
• Ueyama Yasuhiro
• Kubota Kazunori

Classifications

• H01M8/1062

  characterised by the physical properties of the porous support, e.g. its porosity or thickness · CPC title

• H01M8/1039 Primary

  halogenated, e.g. sulfonated polyvinylidene fluorides · CPC title

• Y02E60/521

  Cross-Sectional Technologies · mapped topic

• H01B1/122 Primary

  Ionic conductors · CPC title

• H01M8/106

  characterised by the chemical composition of the porous support · CPC title