Photo conductor overcoat comprising radical polymerizable charge transport molecules and hexa-functional urethane acrylates

Patent metadata

Field	Value
Publication number	US-9417537-B2
Application number	US-201414569929-A
Country	US
Kind code	B2
Filing date	Dec 15, 2014
Priority date	Dec 31, 2012
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

An overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a urethane resin having at least six radical polymerizable functional groups and a charge transport molecule having at least one radical polymerizable functional group. The amount of the urethane resin having at least six radical polymerizable functional groups in the curable composition is about 35 percent to about 65 percent by weight. The amount of the charge transport molecules having at least one radical polymerizable functional group in the curable composition is about 35 percent to about 65 percent by weight. This overcoat layer improves wear resistance of the organic photoconductor drum without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its useful life.

First claim

What is claimed is:

1. A overcoat layer for an organic photoconductor drum, comprising a curable composition including:
about 35 percent to about 65 percent by weight of a urethane acrylate resin having at least six radical polymerizable functional groups,
about 35 percent to about 65 percent by weight of a charge transport molecule having at least one radical polymerizable functional group,
an organic solvent;
and a photoinitiator.

2. The overcoat layer of claim 1 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aromatic urethane acrylate resin.

3. The overcoat layer of claim 1 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aliphatic urethane acrylate resin.

4. The overcoat layer of claim 1 , wherein the charge transport molecule comprises a tryarylamine having at least one radical polymerizable functional group.

5. The overcoat layer of claim 1 , wherein the charge transport molecule comprises a tetraphenylbenzidine having at least one radical polymerizable functional group.

6. The overcoat layer of claim 1 , wherein the curable composition further includes a monomer or oligomer having at most five radical polymerizable functional groups.

7. The overcoat layer of claim 1 , wherein the curable composition further includes a non-radical polymerizable additive at an amount equal to or less than about 10 percent by weight of the curable composition.

8. The overcoat layer of claim 7 , wherein the amount of non-radical polymerizable additive is about 0.1 to about 5 percent by weight of the curable composition.

9. The overcoat layer of claim 1 , wherein a cured curable composition has a thickness of about 0.1 μm to about 10 μm.

Assignees

• Lexmark Int Inc

Inventors

• Bellino Mark Thomas
• Black David Glen
• Luo Weimei
• Reeves Scott Daniel

Classifications

• G03G5/14786

  Macromolecular compounds characterised by specific side-chain substituents or end groups · CPC title

• G03G5/14769

  Other polycondensates comprising nitrogen atoms with or without oxygen atoms in the main chain · CPC title

• G03G5/14734

  Polymers comprising at least one carboxyl radical, e.g. polyacrylic acid, polycrotonic acid, polymaleic acid; Derivatives thereof, e.g. their esters, salts, anhydrides, nitriles, amides · CPC title

• G03G5/0618 Primary

  containing oxygen and nitrogen · CPC title

• G03G5/14791

  Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity · CPC title