Smectic A compositions for use in optical devices
US-8999195-B2 · Apr 7, 2015 · US
US9417470B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9417470-B2 |
| Application number | US-201214344685-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 6, 2012 |
| Priority date | Sep 14, 2011 |
| Publication date | Aug 16, 2016 |
| Grant date | Aug 16, 2016 |
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In a driver for a smectic-A composition liquid crystal panel, the driver forms a resonant circuit operable to oscillate at resonant frequency for ordering the smectic-A liquid crystal composition of the panel.
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The invention claimed is: 1. A driver for a smectic-A composition liquid crystal panel, the driver forming a resonant circuit operable to oscillate at resonant frequency for ordering a smectic-A liquid crystal composition of the liquid crystal panel, wherein the resonant circuit comprises the liquid crystal panel and wherein the liquid crystal panel comprises the liquid crystal composition. 2. A driver according to claim 1 further comprising a node for disordering the smectic-A liquid crystal composition. 3. A driver according to claim 1 further comprising a Q-improving reactance. 4. A driver according to claim 3 , wherein the reactance comprises a capacitor parallel to the panel. 5. A method of driving a panel comprising two substrates sandwiching a liquid crystal composition exhibiting smectic-A properties, each substrate having a respective panel electrode, the method comprising: driving said panel resonantly to cause disordering of the liquid crystal composition. 6. A driver according to claim 1 , wherein the liquid crystal composition is a thermotropic liquid crystal composition exhibiting a smectic type A phase made up of multiple layers, wherein: under the influence of different electric fields applied between the electrodes, the alignment of the layers of the composition can become more ordered or more disordered, the composition has stable states in which the alignment of the layers of the composition are differently ordered including an ordered state, a disordered state and intermediate states, the composition being such that, once switched to a given state by an electric field, it remains substantially in that state when the field is removed. 7. A driver according to claim 1 , wherein the composition comprises an ionic dopant dissolved in a SmA liquid crystal host. 8. A driver according to claim 1 , wherein the composition comprises, in weight %: (a) 25-75% in total of at least one siloxane of the general formula I: wherein: p is 1 to 10, q is 1 to 12, t is 0 or 1, k is 2 or 3, each A is independently a phenyl or cyclohexyl ring and all A are bonded together in para positions, each R is independently a C 1-3 alkyl group, X is a C 1-12 alkyl group, and Z is F, Cl, Br, I, CN, NH 2 , NO 2 , NMe 2 , NCS, CH 3 , OCH 3 , CF 3 , OCF 3 , CH 2 F, or CHF 2 , (b) 0.001-1% in total of at least one quaternary ammonium salt of the general formula II: wherein: T is a methyl group or a silyl or siloxane group, v is 1 to 30, each of R1, R2 and R3 is independently C 1-4 alkyl, and Q − is an oxidatively stable ion, (c) 20-65% in total of at least one polarisable linear molecule having an alkyl chain, the molecule having the general formula III: D-A′ k -Y (III) wherein: D is a C 1-16 straight chained alkyl or alkoxy group optionally containing one or more double bonds, k is 2 or 3, each A′ is independently a phenyl, cyclohexyl, pyrimidine, 1,3-dioxane, or 1,4-bicyclo[2,2,2]octyl ring, and all A are bonded together in para positions, the terminal ring attached to Y optionally being a phenyl, and Y is located in the para position of the terminal ring of the group A′ k and is selected from Z as defined above in connection with Formula I, C 1-16 straight chained alkyl, C 1-16 straight chained alkoxy, OCHF 2 , NMe 2 , CH 3 , OCOCH 3 , and COCH 3 ; and (d) 2-20% in total of at least one side chain liquid crystal polysiloxane of the general formula IV: wherein: a, b and c each independently have a value of 0 to 100 and are such that a+b+c has an average value in the range 3 to 200, and a is such that the chain units of the formula Y—R 2 SiO—[SiR 2 —O] a represents 0 to 25 mole percentage of the compound of the general formula IV, and c is such that the units of the formula chain —[SiHR—O] c —R 2 SiO—Y represents 0 to 15 mole percentage of the compound of the general formula IV, m is 3 to 20, t is 0 or 1, k is 2 or 3, each A is independently a phenyl or cyclohexyl ring and all A are bonded together in para positions, each R is independently a C 1-3 alkyl group, and each Y is independently a C 1-12 alkyl group, a chromophore or a calamitic liquid crystal group, and Z is as defined above in connection with Formula I, and wherein the amounts and the components are selected such that the composition possesses SmA layering, as detected by X-ray diffraction. 9. A driver according to claim 8 , wherein R is methyl. 10. A driver according to claim 8 , wherein v is 13 or 15 and T is methyl. 11. A driver according to claim 8 , wherein Z is CN. 12. A driver according to claim 9 , wherein Z is CN. 13. A driver according to claim 8 , wherein Q − is a ClO 4 − ion. 14. A driver according to claim 8 , wherein a+b+c has an average value in the range 5 to 20.
Circuit arrangements or driving methods for the control of single liquid crystal cells (G02F1/132, G02F1/133382 take precedence) · CPC title
with inductors, other than in the electrode driving circuitry of plasma displays · CPC title
using smectic liquid crystals (G02F1/141 takes precedence) · CPC title
using liquid crystals · CPC title
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