Methods and systems for predicting a need for introducing anti-fouling additives to a hydrocarbon stream to reduce fouling of crude hydrocarbon refinery components

Patent metadata

Field	Value
Publication number	US-9416325-B2
Application number	US-201314132103-A
Country	US
Kind code	B2
Filing date	Dec 18, 2013
Priority date	Mar 14, 2013
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

Method and system for predicting a need for introducing anti-fouling additives to a hydrocarbon stream in a hydrocarbon refinery. The method comprises characterizing whether the hydrocarbon stream is a non-high solvency dispersive power (“HSDP”) crude and performing at least one of determining whether the hydrocarbon stream is subject to filterable solids levels greater than about 100 wppm or classifying whether the hydrocarbon stream has an expected low flow velocity during normal operating conditions within the refinery. The method further comprises indicating, using a processor, that anti-fouling additives are recommended if the hydrocarbon stream is characterized to be a non-HSDP crude and either the hydrocarbon stream is determined to be subject to filterable solids levels greater than about 100 wppm or the hydrocarbon stream is classified as having expected low flow within a heat exchanger of the refinery.

First claim

What is claimed is:

1. A method of predicting a need for introducing anti-fouling additives to a hydrocarbon stream in a hydrocarbon refinery, the method comprising:
sampling the hydrocarbon stream to characterize whether the hydrocarbon stream is a non-HSDP crude;
performing at least one of:
(a) determining whether the hydrocarbon stream is subject to filterable solids levels greater than about 100 wppm; or
(b) sampling the hydrocarbon stream to classify whether the hydrocarbon stream has an expected flow velocity lower than about 3 ft/s during normal operating conditions within a heat exchanger of the refinery; and
indicating, using a processor, that anti-fouling additives are recommended if the hydrocarbon stream is characterized to be a non-HSDP crude and either the hydrocarbon stream is determined to be subject to filterable solids levels greater than about 100 wppm or the hydrocarbon stream is classified as having expected flow lower than about 3 ft/s within a heat exchanger of the refinery;
introducing one or more antifouling additives to the hydrocarbon stream if the processor indicates that anti-fouling additives are recommended; wherein at least one of the one or more anti-fouling additives is a polyalkyl succinic anhydride derivative.

2. The method of claim 1 , wherein characterizing whether the hydrocarbon stream is a non-HSDP crude includes determining whether the hydrocarbon stream has a solubility blending number below 90 and a total acid number below 0.3.

3. The method of claim 1 , wherein determining whether the hydrocarbon stream is subject to filterable solids levels greater than about 100 wppm includes identifying whether a desalter is provided upstream of the heat exchanger to reduce filterable solids levels to less than about 100 wppm.

4. The method of claim 1 , wherein at least one anti-fouling additive is provided at a concentration of about 1 wppm to about 1000 wppm of crude oil.

5. The method of claim 1 , wherein the at least one anti-fouling additive is provided at a concentration of about 10 wppm to about 100 wppm of crude oil.

6. The method of claim 1 , wherein the at least one anti-fouling additive is provided at a concentration of about 18 wppm to about 50 wppm of crude oil.

7. A method of predicting a need for introducing anti-fouling additives to a hydrocarbon stream in a hydrocarbon refinery, the method comprising:
sampling the hydrocarbon stream to characterize whether the hydrocarbon stream is a non-HSDP crude;
determining whether the hydrocarbon stream is subject to filterable solids levels greater than about 100 wppm;
sampling the hydrocarbon stream to classify the hydrocarbon stream as having an expected flow lower than about 3 ft/s within a heat exchanger of the refinery;
indicating, using a processor, that anti-fouling additives are recommended if the hydrocarbon stream is characterized to be a non-HSDP crude and either the hydrocarbon stream is determined to be subject to filterable solids levels greater than about 100 wppm or the hydrocarbon stream is classified as having expected flow lower than about 3 ft/s within a heat exchanger of the refinery.

8. The method of claim 7 , wherein characterizing whether the hydrocarbon stream is a non-HSDP crude includes determining whether the hydrocarbon stream has a solubility blending number below 90 and a total acid number below 0.3.

9. The method of claim 7 , wherein determining whether the hydrocarbon stream is subject to filterable solids levels greater than about 100 wppm includes identifying whether a desalter is provided upstream of the heat exchanger to reduce filterable solids levels to less than about 100 wppm.

10. The method of claim 7 , further comprising introducing one or more antifouling additives to the hydrocarbon stream if the processor indicates that anti-fouling additives are recommended; wherein at least one of the one or more anti-fouling additives is a polyalkyl succinic anhydride derivative.

11. The method of claim 10 , wherein at least one anti-fouling additive is provided at a concentration of about 1 wppm to about 1000 wppm of crude oil.

12. The method of claim 10 , wherein the at least one anti-fouling additive is provided at a concentration of about 10 wppm to about 100 wppm of crude oil.

13. The method of claim 10 , wherein the at least one anti-fouling additive is provided at a concentration of about 18 wppm to about 50 wppm of crude oil.

Assignees

• Brons Glen B
• Exxonmobil Res & Eng Co

Inventors

• Brons Glen B

Classifications

• C10L2290/141

  of additive or catalyst · CPC title

• C10G75/04 Primary

  by addition of antifouling agents · CPC title

• C10L10/04

  for minimising corrosion or incrustation · CPC title

• C10L1/2364

  homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups (C10L1/221 takes precedence) · CPC title

• C10L2290/58

  Control or regulation of the fuel preparation of upgrading process · CPC title