Liquid crystal composition and liquid crystal display comprising the same

Patent metadata

Field	Value
Publication number	US-9416316-B2
Application number	US-201414511322-A
Country	US
Kind code	B2
Filing date	Oct 10, 2014
Priority date	Mar 18, 2014
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

A liquid crystal composition including a first class including a polar liquid crystal compound having at least one fluorine atom and a second class compound including a neutral liquid crystal compound, in which the first class compound includes a first subclass compound having a dielectric anisotropy (Δ∈) of 15 to 21 and a second subclass compound having a dielectric anisotropy (Δ∈) of 5 to 15, and the first sub-class compound includes a liquid crystal compound expressed by the following Chemical Formula 1,

in which R is an alkyl group or an alkenyl group.

First claim

What is claimed is:

1. A liquid crystal composition comprising:
a first class polar liquid crystal compound comprising a first subclass compound having a dielectric anisotropy of 15 to 21 and a second subclass compound having a dielectric anisotropy of 5 to 15; and
a second class neutral liquid crystal compound comprising at least one compound expressed by following Chemical Formula 3-1 to Chemical Formula 3-4,
wherein the first subclass compound is at least one compound expressed by following Chemical Formula 1, and the second subclass compound is at least one compound expressed by following Chemical Formula 2-1 to Chemical Formula 2-5,

wherein R and R′ are the same or different and R and R′ are an alkyl group or an alkenyl group having two to five carbon atoms.

2. The liquid crystal composition of claim 1 , wherein:
the first subclass compound is present in an amount of about 15 wt % to about 20 wt % based on the total weight of the liquid crystal composition.

3. The liquid crystal composition of claim 1 , wherein:
the first subclass compound is at least one compound expressed by following Chemical Formula 1-1 and Chemical Formula 1-2

4. The liquid crystal composition of claim 3 ,
comprising the second subclass compounds expressed by Chemical Formula 2-1, Chemical Formula 2-2, Chemical Formula 2-3 and Chemical Formula 2-5,

5. The liquid crystal composition of claim 4 , wherein: the second subclass compounds are present in an amount of about 20 wt % to about 40 wt % based on the total weight of the liquid crystal composition.

6. The liquid crystal composition of claim 5 , comprising the second class neutral liquid crystal compounds expressed by Chemical Formula 3-1 to Chemical Formula 3-4

7. The liquid crystal composition of claim 6 , wherein: the second class neutral liquid crystal compounds are present in an amount of about 45 wt % to about 65 wt % based on the total weight of the liquid crystal composition.

8. The liquid crystal composition of claim 7 , wherein: the second class neutral liquid crystal compounds of Chemical Formula 3-1 and Chemical Formula 3-2 are present in an amount of about 30 wt % to about 55 wt % based on the total weight of the liquid crystal composition.

9. The liquid crystal composition of claim 8 , wherein: based on the total weight of the liquid crystal composition,
the first subclass compound expressed by Chemical Formula 1 is present in an amount of about 15 wt % to about 20 wt %,
the second subclass compound expressed by Chemical Formula 2-1 is present in an amount of about 5 wt %,
the second subclass compound expressed by Chemical Formula 2-2 is present in an amount of about 5 wt %,
the second subclass compound expressed by Chemical Formula 2-3 is present in an amount of about 5 wt % to about 10 wt %,
the second subclass compound expressed by Chemical Formula 2-4 is present in an amount of about 0 to about 10 wt %,
the second subclass compound expressed by Chemical Formula 2-5 is present in an amount of about 5 wt % to about 10 wt,
the second class neutral liquid crystal compound expressed by Chemical Formula 3-1 is present in an amount of about 30 wt % to about 40 wt %,
the second class neutral liquid crystal compound expressed by Chemical Formula 3-2 is present in an amount of about 10 wt % to about 15 wt %, and
the second class neutral liquid crystal compound expressed by Chemical Formula 3-3 is present in an amount of about 5 wt % to about 10 wt %.

10. The liquid crystal composition of claim 1 , wherein: the liquid crystal composition has dielectric anisotropy of about 5 to about 8, a rotational viscosity of about 50 mPa·s to about 80 mPa·s, and a phase transition temperature of about 75° C. to about 80° C.

11. A liquid crystal display comprising:
a first substrate;
a second substrate facing the first substrate;
a pair of field generating electrodes formed on at least one of the first substrate and the second substrate; and
a liquid crystal layer disposed between the first substrate and the second substrate,
wherein the liquid crystal layer comprises:
a first class polar liquid crystal compound comprising a first subclass compound having a dielectric anisotropy of 15 to 21 and a second subclass compound having a dielectric anisotropy of 5 to 15, and
a second class neutral liquid crystal compound comprising at least one compound expressed by following Chemical Formula 3-1 to Chemical Formula 3-4,

wherein the first subclass compound is at least one compound expressed by following Chemical Formula 1, and the second subclass compound is at least one compound expressed by following Chemical Formula 2-1 to Chemical Formula 2-5,

wherein R and R′ are the same or different and R and R′ are an alkyl group or an alkenyl group having two or five carbon atoms.

12. The liquid crystal display of claim 11 , wherein: the first subclass compound is at least one compound expressed by following Chemical Formula 1-1 and Chemical Formula 1-2

13. The liquid crystal display of claim 12 , wherein:
the liquid crystal layer comprises the second subclass compounds expressed by Chemical Formula 2-1, Chemical Formula 2-2, Chemical Formula 2-3, and Chemical Formula 2-5

14. The liquid crystal display of claim 13 , wherein: the liquid crystal layer comprises the second class neutral liquid crystal compounds expressed by Chemical Formula 3-1 to Chemical Formula 3-4

15. The liquid crystal display of claim 14 , wherein:
the first subclass compound is present in an amount of about 15 wt % to about 20 wt % based on the total weight of the liquid crystal composition,
the second subclass compound is present in an amount of about 20 wt % to about 40 wt % based on the entire weight of the liquid crystal composition, and
the second class neutral liquid crystal compound is present in an amount of about 45 wt % to about 65 wt % based on the entire weight of the liquid crystal composition.

16. The liquid crystal display of claim 15 , wherein: second class neutral liquid crystal compounds expressed by Chemical Formula 3-1 and Chemical Formula 3-2 are present in an amount of about 30 wt % to about 55 wt % based on the total weight of the liquid crystal composition.

17. The liquid crystal display of claim 16 , wherein: based on the total weight of the liquid crystal composition,
the first subclass compound expressed by Chemical Formula 1 is present in an amount of about 15 wt % to about 20 wt %,
the second subclass compound expressed by the Chemical Formula 2-1 is present in an amount of about 15 wt % to about 20 wt %,
the second subclass compound expressed by Chemical Formula 2-2 is present in an amount of about 5 wt %,
the second subclass compound expressed by Chemical Formula 2-3 is present in an amount of abo

Assignees

• Samsung Display Co Ltd

Inventors

• Kim Si Heun
• Kim Eun A

Classifications

• C09K2019/301

  Cy-Cy-Ph · CPC title

• C09K2019/123

  Ph-Ph-Ph · CPC title

• C09K19/3003 Primary

  Compounds containing at least two rings in which the different rings are directly linked (covalent bond) · CPC title

• C09K2019/3016

  Cy-Ph-Ph · CPC title

• C09K2019/3019

  Cy-Cy-Ph-Ph · CPC title