Aqueous autoxidisable coating composition

Patent metadata

Field	Value
Publication number	US-9416295-B2
Application number	US-201313936025-A
Country	US
Kind code	B2
Filing date	Jul 5, 2013
Priority date	Mar 31, 2008
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

An aqueous coating composition comprising an autoxidizable polyester resin having ≧30 wt % of fatty acid residues; a Tg in the range of from −60° C. to +35° C.; an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; a Mw in the range of from 2,500 to 100,000 g/mol; the composition having a co-solvent content less that 15 wt % by weight of total composition; a solids content >30 wt %; and when in the form of a film, the composition has a telegraphing value of less than 20 gloss units.

First claim

The invention claimed is:

1. An aqueous coating composition comprising an autoxidisable urethanised polyesteramide resin which comprises <5 wt % of trimellitic acid and/or trimellitic anhydride, wherein the autoxidisable urethanised polyesteramide resin is obtained from components comprising:
i) 10 to 45 wt % of a cyclic anhydride;
iii) 33 to 65 wt % of fatty acid residues having an iodine number between 80 and 155 g I 2 /100 g fatty acid, wherein the fatty acid residues contain less than 10 wt % of fatty acid residues that contain 3 or more double bonds;
iv) 10 to 35 wt % of a hydroxyl functional amine; and
v) 0.5 to 7 wt % of a polyisocyanate; wherein
i)+iii)+iv)+v)=100%; and wherein
the autoxidisable urethanised polyesteramide resin has:
(I) a ND×AV value which is in a range of from 22 to 65 mg KOH/g, where ND is a neutralization degree of the acid groups and AV is an acid value of the autoxidisable urethanised polyesteramide resin;
(II) a Tg in the range of from −60° C. to +35° C.;
(III) an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; and
(IV) a Mw in the range of from 2,500 to 100,000 g/mol; wherein
said composition has:
a) a co-solvent content ≦15 wt % based on the total weight of the composition;
b) a solids content >30 wt %; and wherein
said composition when in the form of a film has a telegraphing value of less than 20 gloss units;
where the telegraphing value is the difference between an initial smooth gloss value minus an initial rough gloss value of the film, where the initial smooth gloss value is the gloss when the film is cast on smooth PVC (Rz=1 μm [±0.25 μm]);
the initial rough gloss value is the gloss when the film is cast on rough PVC (Rz=25 μm [±5 μm]); and wherein
each film has a dry film thickness of 52 μm [±6 μm]; and
each initial gloss value is measured at a 20° angle, one day (24 h) after the film has been cast.

2. An aqueous coating composition according to claim 1 , wherein the ND×AV value of the autoxidisable urethanised polyesteramide resin is 27 to 57 mg KOH/g.

3. An aqueous coating composition according to claim 1 , wherein the composition comprises <13 wt % N-methylpyrrolidone based on the total weight of resin solids in the composition.

4. An aqueous coating composition according to claim 1 , wherein the autoxidisable urethanised polyesteramide resin comprises at least 5 wt % of ring structures.

5. An aqueous coating composition according to claim 1 , wherein the autoxidisable urethanised polyesteramide resin comprises <15 wt % of phthalic acid, phthalic anhydride and/or benzoic acid.

6. An aqueous coating composition according to claim 1 , wherein the fatty acid residues have an iodine number between 100 and 150 g I 2 /100 g fatty acid.

7. An aqueous coating composition according to claim 1 , wherein the autoxidisable urethanised polyesteramide resin comprises 1 to 7 wt % of isocyanates based on the total weight of resin solids in the composition.

8. An aqueous coating composition according to claim 1 , wherein the autoxidisable urethanised polyesteramide resin has an amide group content of at least 15 mmoles/100 g solid resin.

9. An aqueous coating composition according to claim 1 comprising:
i) 35 to 65 wt % of the autoxidisable urethanised polyesteramide resin;
ii) 0 to 20 wt % of the co-solvent; and
iii) 35 to 65 wt % of water; wherein
i)+ii)+iii)=100%.

10. An aqueous coating composition according to claim 1 , comprising:
i) 10 to 40 wt % of pigment;
ii) 10 to 40 wt % of the autoxidisable urethanised polyesteramide resin;
iii) 20 to 70 wt % of water; and
iv) 0 to 15 wt % of the co-solvent;
v) 0 to 2.5 wt % of thickener based on the weight of the solids; and
vi) 0 to 5 wt % of dispersing agent based on the weight of the solids, wherein i)+ii)+iii)+iv)=100%.

11. An aqueous coating composition according to claim 1 , comprising resin solids in the composition comprising at least 50 wt % of the autoxidisable urethanised polyesteramide resin based on the total weight of resin solids.

12. An aqueous coating composition according to claim 1 , wherein the initial rough gloss value minus the rough gloss value measured at 4 days after film formation is less than 10 gloss units.

13. A substrate coated with the aqueous coating composition according to claim 1 .

14. A method for coating a substrate comprising applying the aqueous coating composition according to claim 1 to the substrate and then drying the aqueous composition to form a coated substrate.

15. A paint comprising the aqueous coating composition according to claim 1 .

Assignees

• Dsm Ip Assets Bv

Inventors

• Tennebroek Ronald
• Overbeek Gerardus Cornelis
• Bergman Franciscus Adrianus Cornelis
• Aabich Mourad
• Coogan Richard George
• Swaans Roel Johannes Marinus

Classifications

• C08F220/325

  containing glycidyl radical, e.g. glycidyl (meth)acrylate · CPC title

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title

• C08G18/4233

  derived from polymerised higher fatty acids or alcohols · CPC title

• Y10T428/31511

  Of epoxy ether · CPC title

• C09D133/14 Primary

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title