Bi- and tri-layer interfacial layers in perovskite material devices

Patent metadata

Field	Value
Publication number	US-9416279-B2
Application number	US-201514711391-A
Country	US
Kind code	B2
Filing date	May 13, 2015
Priority date	Nov 26, 2013
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

Photovoltaic devices such as solar cells, hybrid solar cell-batteries, and other such devices may include an active layer disposed between two electrodes. The active layer may have perovskite material and other material such as mesoporous material, interfacial layers, thin-coat interfacial layers, and combinations thereof. The perovskite material may be photoactive. The perovskite material may be disposed between two or more other materials in the photovoltaic device. Inclusion of these materials in various arrangements within an active layer of a photovoltaic device may improve device performance. Other materials may be included to further improve device performance, such as, for example: additional perovskites, and additional interfacial layers.

First claim

What is claimed is:

1. A photovoltaic device comprising:
a first electrode;
a second electrode;
an active layer disposed at least partially between the first and second electrodes, the active layer comprising:
photoactive material comprising a perovskite material;
a first interfacial layer disposed adjacent to and in contact with a second interfacial layer; and
a third interfacial layer disposed adjacent to and in contact with the second interfacial layer, wherein the first interfacial layer and the third interfacial layer comprises a different material than the second interfacial layer.

2. The photovoltaic device of claim 1 , wherein the perovskite material has the formula CMX 3 , wherein C comprises one or more cations each selected from the group consisting of Group 1 metals, Group 2 metals, organic cations, and combinations thereof;
wherein M comprises one or more metals each selected from the group consisting of Fe, Co, Ni, Cu, Sn, Pb, Bi, Ge, Ti, Zn, and combinations thereof; and
wherein X comprises one or more anions each selected from the group consisting of halides, pseudohalides, sulfide, selenide, and combinations thereof.

3. The photovoltaic device of claim 1 , wherein the first interfacial layer comprises ZnO.

4. The photovoltaic device of claim 1 , wherein the second interfacial layer comprises Al 2 O 3 .

5. The photovoltaic device of claim 1 , wherein the first interfacial layer comprises ZnO and the second interfacial layer comprises Al 2 O 3 .

6. The photovoltaic device of claim 1 , wherein the first interfacial layer comprises Al 2 O 3 , the second interfacial layer comprises ZnO, and the third interfacial layer comprises Al 2 O 3 .

7. The photovoltaic device of claim 1 , wherein the active layer further comprises a mesoporous material.

8. The photovoltaic device of claim 1 , wherein the active layer further comprises:
a third interfacial layer disposed adjacent to the first interfacial layer or the second interfacial layer; and
a fourth interfacial layer disposed adjacent to the first interfacial layer, the second interfacial layer, or the third interfacial layer.

9. The photovoltaic device of claim 1 , wherein the active layer further comprises:
a third interfacial layer disposed adjacent to the first interfacial layer or the second interfacial layer;
a fourth interfacial layer disposed adjacent to the first interfacial layer, the second interfacial layer, or the third interfacial layer; and
a fifth interfacial layer disposed adjacent to the first interfacial layer, the second interfacial layer, the third interfacial layer, or the fourth interfacial layer.

10. The photovoltaic device of claim 1 , wherein:
the first electrode further comprises an anode;
the second electrode further comprises a cathode; and
the first interfacial layer and the second interfacial layer are disposed between the photoactive layer and the first electrode.

11. The photovoltaic device of claim 1 , wherein the first and second interfacial layers comprise one or more compounds each selected from the group consisting of Al, Bi, Co, Cu, Fe, In, Mn, Mo, Ni, Pt, Si, Sn, Ta, Ti, V, W, Nb, Zn, Zr, an oxide of any of the foregoing metals, a sulfide of any of the foregoing metals, a nitride of any of the foregoing metals, alkyl silyl groups, graphite, graphene, fullerenes, carbon nanotubes, a mesoporous material, and combinations thereof.

12. The photovoltaic device of claim 1 , wherein the first and second interfacial layers comprise one or more compounds each selected from the group consisting of NiO, TiO 2 , SrTiO 3 , Al2O 3 , ZrO 2 , WO 3 , V 2 O 5 , MO 3 , ZnO, graphene, carbon black, and combinations thereof.

13. The photovoltaic device of claim 1 , wherein the first interfacial layer comprises ZnO doped with one or more compounds selected from the group consisting of Al, In, B, Be, Mg, Ca, Sr, Ba, Sc, Y, Nb, and combinations thereof.

14. A photovoltaic device comprising:
a first electrode;
a second electrode; and
an active layer disposed at least partially between the first and second electrodes, the active layer comprising:
a perovskite material; and
three or more adjacent interfacial layers; wherein each interfacial layer is in contact with at least one adjacent interfacial layer and comprises a different material than the adjacent interfacial layers that it is in contact with;
wherein the perovskite material has the formula CMX 3 ;

wherein C comprises one or more cations each selected from the group consisting of Group 1 metals, Group 2 metals, organic cations, and combinations thereof;
wherein M comprises one or more metals each selected from the group consisting of Fe, Co, Ni, Cu, Sn, Pb, Bi, Ge, Ti, Zn, and combinations thereof; and
wherein X comprises one or more anions each selected from the group consisting of halides, pseudohalides, sulfide, selenide, and combinations thereof.

15. The photovoltaic device of claim 11 , wherein C is methylammonium, M is Pb, and wherein X comprises one or more halides.

16. The photovoltaic device of claim 11 , wherein C is methylammonium, M is Sn, and wherein X comprises one or more halides.

17. The photovoltaic device of claim 11 , wherein C is a formamidinium, M is Pb, and wherein X comprises one or more halides.

18. The photovoltaic device of claim 11 , wherein C is a formamidinium, M is Sn, and wherein X comprises one or more halides.

19. The photovoltaic device of claim 14 , wherein at least one of the plurality of interfacial layers comprises ZnO and at least one of the plurality of interfacial layers comprises Al 2 O 3 .

20. The photovoltaic device of claim 19 , wherein the ZnO comprises doped ZnO comprising one or more compounds selected from the group consisting of Al doped ZnO, In doped ZnO, B doped ZnO, Be doped ZnO, Mg doped ZnO, Ca doped ZnO, Sr doped ZnO, Ba doped ZnO, Sc doped ZnO, Y doped ZnO, Nb doped ZnO, and combinations thereof.

21. The photovoltaic device of claim 14 , wherein the plurality of interfacial layers comprises:
a first interfacial layer comprising Al 2 O 3 ;
a second interfacial layer comprising ZnO;
a third interfacial layer comprising Al 2 O 3 ;
a fourth interfacial layer comprising ZnO; and
a fifth interfacial layer comprising Al 2 O 3 .

22. The photovoltaic device of claim 14 , wherein:
the first electrode further comprises an anode;
the second electrode further comprises a cathode; and
the plurality of interfacial layers are disposed between the perovskite material and the first electrode.

23. The photovoltaic device of claim 14 , wherein each of the plurality of interfacial layers comprise one or more compounds each selected from the group consisting of Al, Bi, Co, Cu, Fe, In, Mn, Mo, Ni, Pt, Si, Sn, Ta, Ti, V, W, Nb, Zn, Zr, an oxide of any of the foregoing metals, a sulfide of any of the foregoing metals, a nitride of any of the foregoing metals, alkyl silyl groups, graphite, graphene, fullerenes, carbon nanotubes, a mesoporous material, and combinations thereof.

24. The photovoltaic device of claim 14 , wherein each of the plurality of interfacial layers comprise one or more compounds each selected from the group consisting of NiO, TiO 2 , SrTiO 3 , Al 2 O 3 , ZrO 2 , WO 3 , V 2 O 5 , MO 3 , ZnO, graphene, carbon black, and combinations thereof.

Assignees

• Hunt Energy Entpr Llc

Inventors

• Irwin Michael D
• Chute Jerred A
• Dhas Vivek V

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H10F77/12

  Active materials · CPC title

• H01L51/006

  Electricity · mapped topic

• H01G9/2059

  comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution · CPC title

• C09D1/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title