Polyphenylene sulfide resin composition, molded product of polyphenylene sulfide resin composition and production method of polyphenylene sulfide resin composition

Patent metadata

Field	Value
Publication number	US-9416272-B2
Application number	US-201514882325-A
Country	US
Kind code	B2
Filing date	Oct 13, 2015
Priority date	Dec 28, 2011
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

There is provided a polyphenylene sulfide resin composition, comprising 5 to 95% by weight of a component (B) which is a polyphenylene sulfide resin having a weight-average molecular weight of not less than 10,000 and a weight loss percentage ΔWr of not greater than 0.18% under heating, relative to 95 to 5% by weight of a component (A) which is a polyphenylene sulfide resin having the weight loss percentage ΔWr of greater than 0.18%, wherein a total of the component (A) and the component (B) is equal to 100% by weight.

First claim

The invention claimed is:

1. A production method of a polyphenylene sulfide resin composition, comprising the steps of:
providing a component (A) which is a polyphenylene sulfide resin having a weight loss percentage ΔWr expressed by Equation (1) of greater than 0.18% under heating:
Δ Wr =( W 1− W 2)/ W 1×100%  (1)

wherein ΔWr denotes weight loss percentage (%) and is a value determined from a sample in thermogravimetric analysis at a temperature rise rate of 20° C. per minute under ordinary-pressure and non-oxidizing atmosphere ΔWr is determined from a sample weight (W1) at 100° C. and a sample weight (W2) at 330° C.;
providing a component (B) which is a polyphenylene sulfide resin having a weight-average molecular weight of not less than 10,000 and having the weight loss percentage ΔWr expressed by the Equation (1) of not greater than 0.18% under heating;
providing a component (C) that is a fibrous and/or non-fibrous filler and/or a component (E) that is a functional group-containing olefin copolymer; and
melt kneading 95 to 5% by weight of the component (A) with 5 to 95% by weight of the component (B) and additionally with 1 to 500 parts by weight of the component (C) and/or 1 to 70 parts by weight of the component (E),
wherein a total of the component (A) and the component (B) is equal to 100% by weight; the total of the component (A) and the component (B) is equal to 100 parts by weight; and the functional group of the component (E) is one or more groups selected from the group consisting of epoxy group, carboxyl group, acid anhydride group, amino group and mercapto group.

2. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein
the melt kneading comprises melt kneading at least the component (C) out of the component (C) and the component (E),
the component (C) includes at least a fibrous filler, and
the fibrous filler of the component (C) has a fiber length of 1 to 5 mm, prior to the melt kneading.

3. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the melt kneading comprises melt kneading the component (C) out of the component (C) and the component (E), simultaneously with the component (A) and the component (B).

4. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the melt kneading comprises melt kneading the component (C) out of the component (C) and the component (E), after melt kneading the component (A) and the component (B).

5. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the melt kneading comprises melt kneading at least the component (C) out of the component (C) and the component (E) and further comprises melt kneading 0.05 to 10 parts by weight of an alkoxysilane compound (D) having one or more groups selected from the group consisting of epoxy group, amino group, isocyanate group, hydroxyl group, mercapto group and ureido group, in addition to 100 parts by weight of a total of the component (A), the component (B) and the component (C).

6. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the melt kneading comprises melt kneading the component (E) out of the component (C) and the component (E), simultaneously with the component (A) and the component (B).

7. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the polyphenylene sulfide resin that is the component (B) has a degree of dispersion of not greater than 2.5, wherein the degree of dispersion is provided by dividing the weight-average molecular weight by the number-average molecular weight.

8. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the component (B) has an alkali metal content of less than 700 ppm based on the total weight of the component (B).

9. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein a content of a total amount of a lactone-based compound in a gas component produced by heating the component (B) which is provided in the step of providing the component (B) at 320° C. under nitrogen stream for 60 minutes is not greater than 500 ppm on a weight basis of polyphenylene sulfide.

10. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein a content of a total amount of an aniline-based compound in a gas component produced by heating the component (B) which is provided in the step of providing the component (B) at 320° C. under nitrogen stream for 60 minutes is not greater than 300 ppm on a weight basis of polyphenylene sulfide resin.

11. The production method of a polyphenylene sulfide resin composition according to claim 1 , wherein the component (B) is a polyphenylene sulfide resin obtained by heating a polyphenylene sulfide prepolymer to be converted to a high degree of polymer, wherein the polyphenylene sulfide prepolymer includes at least 50% by weight of a cyclic polyphenylene sulfide shown by a formula (1):

wherein m is an integral number of 4 to 20, and the cyclic polyphenylene sulfide is either a single component having a single repeating number or a mixture having different repeating numbers.

Assignees

• Toray Industries

Inventors

• Ouchiyama Naoya
• Horiuchi Shunsuke
• Matsumoto Hideki
• Saitoh Kei

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L81/02 Primary

  Polythioethers; Polythioether-ethers · CPC title

• C08L81/04 Primary

  Polysulfides · CPC title

• C08G75/02

  Polythioethers · CPC title

• B29C45/0001

  characterised by the choice of material · CPC title