Blend composition, flexible tubing material and method of making the blend

Patent metadata

Field	Value
Publication number	US-9416267-B2
Application number	US-201213456146-A
Country	US
Kind code	B2
Filing date	Apr 25, 2012
Priority date	Apr 25, 2011
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

A composition includes a blend of (a) a multi-block copolymer including at least one block of an elastomeric polymer and at least one block of a first polymer including a chiral polymer having a stereo isomeric configuration; and (b) a second polymer including an anti-chiral polymer corresponding to the chiral polymer in (a), wherein the second polymer includes an opposite handed stereo isomeric configuration to the chiral polymer in (a); wherein the blend of the chiral polymer and the anti-chiral polymer form stereo complex sites. A flexible tubing material further includes the blend. In an embodiment, a method of making the blend material is also provided.

First claim

What is claimed is:

1. A composition comprising a melt blend of:
(a) a multi-block copolymer including at least one block of an at least semi-miscible elastomeric polymer and at least two end blocks of a first polymer including a chiral polymer having a stereo isomeric configuration; and
(b) a second polymer consisting essentially of an anti-chiral polymer corresponding to the chiral polymer in (a), wherein the second polymer includes an opposite handed stereo isomeric configuration to the chiral polymer in (a);
wherein the melt blend of the multi-block copolymer and the second polymer is in the absence of a solvent and forms a continuous amorphous region with stereo complex crystalline sites dispersed within the continuous amorphous region, wherein the amount of stereo complex crystalline sites in the blend is about 3% to about 35%.

2. The composition of claim 1 , wherein the first polymer and the second polymer include the chiral polymer and the anti-chiral polymer of poly(lactic acid); poly(3-hexylthiophene); syndiotactic polypropylene; ionomers; polymethacrylates; polystyrene; copolymers of polystyrene; poly(β-propiolactones); polyenantiomers; or combinations thereof.

3. The composition of claim 2 , wherein the first polymer and the second polymer include the chiral polymer and the anti-chiral polymer of poly(lactic acid).

4. The composition of claim 1 , wherein the elastomeric polymer is an ether, an olefin, a vinyl, a polyurethane, an acrylate, a vinyl alcohol, an ethylene copolymer, an ester, a silicone, a fluoropolymer, or combination thereof.

5. The composition of claim 4 , wherein the elastomeric polymer is polyethylene oxide (PEO), polyethylene glycol (PEG), polytriethylene glycol, polytetraethylene glycol, polybutadiene, polyisobutylene, polyisoprene, polystyrene-butadiene, acrylonitrile rubber, derivatives of vegetable oils, polypropylene glycol (PPG), polytetra methylene ether glycol (PTMEG), polycaprolactone, poly(para-dioxanone), poly(propylene carbonate), poly(tetramethyleneadipate-co-terephthalate), poly(butylene adipate-co-terephthalate), poly(butylene succinate), polyhydroxyalkanoates, blends, or combinations thereof.

6. The composition of claim 1 , wherein the multi-block copolymer is a diblock copolymer, a triblock copolymer, a star copolymer, a graft copolymer, or a hyper-branched copolymer.

7. The composition of claim 1 , having a shore A durometer of about 40 to shore D of about 50.

8. The composition of claim 1 , having a glass transition temperature (Tg) equal to, or less than an chiral/anti-chiral polymer composition without an elastomeric polymer block.

9. The composition of claim 1 , further comprising a plasticizer.

10. The composition of claim 9 , wherein the plasticizer is a glycol ether ester.

11. A flexible material comprising a melt blend of:
(a) a multi-block copolymer including at least one block of an at least semi-miscible elastomeric polymer and at least two end blocks of a first polymer including a chiral polymer having a stereo isomeric configuration; and
(b) a second polymer consisting essentially of an anti-chiral polymer corresponding to the chiral polymer in (a), wherein the second polymer includes an opposite handed stereo isomeric configuration to the chiral polymer in (a);
wherein the melt blend of the multi-block copolymer and the second polymer is in the absence of a solvent and forms a continuous amorphous region with stereo complex crystalline sites dispersed within the continuous amorphous region, wherein the amount of stereo complex crystalline sites in the blend is about 3% to about 35%.

12. The flexible material of claim 11 , wherein the first polymer and the second polymer include the chiral polymer and the anti-chiral polymer of poly(lactic acid); poly(3-hexylthiophene); syndiotactic polypropylene; ionomers; polymethacrylates; polystyrene; copolymers of polystyrene; poly(β-propiolactones); polyenantiomers; or combinations thereof.

13. The flexible material of claim 12 , wherein the first polymer and the second polymer include the chiral polymer and the anti-chiral polymer of poly(lactic acid).

14. The flexible material of claim 11 , wherein the elastomeric polymer is an ether, an olefin, a vinyl, a polyurethane, an acrylate, a vinyl alcohol, an ethylene copolymer, an ester, a silicone, a fluoropolymer, or combination thereof.

15. The flexible material of claim 11 , having a glass transition temperature (Tg) equal to, or less than an chiral/anti-chiral polymer without an elastomeric polymer block.

16. The flexible material of claim 11 , further comprising a plasticizer.

17. A method of making a melt blend composition comprising:
providing (a) a multi-block copolymer including at least one block of an at least semi-miscible elastomeric polymer and at least two end blocks of a first polymer including a chiral polymer having a stereo isomeric configuration;
melt blending the multi-block copolymer in the absence of a solvent with (b) a second polymer consisting essentially of an anti-chiral polymer corresponding to the chiral polymer in (a), wherein the second polymer includes an opposite handed stereo isomeric configuration to the chiral polymer in (a), wherein the melt blend of the multi-block copolymer and the second polymer is in the absence of a solvent and forms a continuous amorphous region with stereo complex crystalline sites dispersed within the continuous amorphous region, wherein the amount of stereo complex crystalline sites in the blend is about 3% to about 35%; and
extruding or molding the blend.

18. The method of claim 17 , wherein the first polymer and the second polymer include the chiral polymer and the anti-chiral polymer of poly(lactic acid); poly(3-hexylthiophene); syndiotactic polypropylene; ionomers; polymethacrylates such as polymethylmethacrylate, poly(N,N-dimethylamino-2-ethyl methacrylate); polystyrene; copolymers of polystyrene; poly(β-propiolactones); polyenantiomers; or combinations thereof.

19. The method of claim 18 , wherein the first polymer and the second polymer include the chiral polymer and the anti-chiral polymer of poly(lactic acid).

20. The method of claim 17 , wherein the elastomeric polymer is an ether, an olefin, a vinyl, a polyurethane, an acrylate, a vinyl alcohol, an ethylene copolymer, an ester, a silicone, a fluoropolymer, or combination thereof.

21. The method of claim 17 , wherein providing the multi-block copolymer includes polymerizing the first polymer with the elastomeric polymer and a catalyst.

22. The method of claim 17 , wherein the blend has a glass transition temperature (Tg) equal to, or less than an chiral/anti-chiral polymer without an elastomeric polymer block.

23. The method of claim 17 , further comprising blending in the blend composition a plasticizer.

24. The method of claim 17 , wherein extruding or molding the blend includes extruding or injection molding the blend into a flexible component or product.

Assignees

• Hsu Shaw Ling
• Rathi Sahas
• Coughlin Edward
• Chen Xiaolang
• Golub Charles S
• Tzivanis Michael J
• Zimmerman Michael A
• Orf Nicholas
• Lai Choung H
• Saint Gobain Performance Plastics Corp
• Univ Massachusetts

Inventors

• Hsu Shaw Ling
• Rathi Sahas
• Coughlin Edward
• Chen Xiaolang
• Golub Charles S
• Tzivanis Michael J
• Zimmerman Michael A
• Orf Nicholas
• Lai Choung H

Classifications

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L101/16

  the macromolecular compounds being biodegradable · CPC title

• C08L67/04 Primary

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• B29C2045/0091

  Pellets or granules, e.g. their structure, composition, length, height, width · CPC title

• C08K5/103

  with polyalcohols · CPC title