Heterophasic propylene copolymer with excellent impact/stiffness balance

Patent metadata

Field	Value
Publication number	US-9416262-B2
Application number	US-201113813796-A
Country	US
Kind code	B2
Filing date	Aug 1, 2011
Priority date	Aug 6, 2010
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

Heterophasic propylene copolymer comprising —a matrix (M) being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate MFR 2 (230° C.) and at least one of the three polypropylene fractions has a melt flow rate MFR 2 (230° C.) in the range of 1.0 to 15.0 g/10 min, and —an elastomeric propylene copolymer dispersed in said matrix, wherein —the heterophasic propylene copolymer has a melt flow rate MFR 2 (230° C.) of equal or more than 20.0 g/10 min, and —the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.

First claim

The invention claimed is:

1. Heterophasic propylene copolymer (HECO) comprising:
(a) a matrix (M) being a polypropylene (PP), said polypropylene (PP) comprises at least three polypropylene fractions (PP1), (PP2) and (PP3), the three polypropylene fractions (PP1), (PP2) and (PP3) differ from each other by the melt flow rate MFR 2 (230° C.) measured according to ISO 1133 and at least one of the three polypropylene fractions (PP1), (PP2) and (PP3) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 1.0 to 15.0 g/10 min, and
(b) an elastomeric propylene copolymer (EC) dispersed in said matrix (M), wherein;
(i) said heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of equal or more than 20.0 g/10 min, and
(ii) the amorphous phase (AM) of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer (HECO) has an intrinsic viscosity (IV) measured according to ISO 1628-1 (at 135° C. in decaline) of equal or higher than 2.0 dl/g.

2. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the polypropylene (PP) has:
(a) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 30.0 to 500.0 g/10 min, and/or
(b) a molecular weight distribution (MWD) of equal or less than 8.0.

3. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the polypropylene (PP) has:
(a) a comonomer content equal or below 1.0 wt. %, and/or
(b) a xylene cold soluble (XCS) fraction measured according to ISO 6427 (23° C.) of equal or below 3.5 wt. %.

4. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the polypropylene fraction with the melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 1.0 to 15.0 g/10 min is the polypropylene fraction with the lowest melt flow rate MFR 2 (230° C.) of the three polypropylene fractions (PP1), (PP2) and (PP3).

5. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein:
(a1) one of the three polypropylene fractions (PP1), (PP2) and (PP3) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 1.0 to 15.0 g/10 min, and
(b1) another of the three polypropylene fractions (PP1), (PP2) and (PP3) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 150.0 to 500.0 g/10 min.

6. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the second polypropylene fraction (PP2) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 20.0 to 300.0 g/10 min.

7. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein all three polypropylene fractions (PP1), (PP2) and (PP3) are propylene homopolymers.

8. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein each of the three polypropylene fractions (PP1), (PP2) and (PP3) has a xylene cold soluble (XCS) content of equal or below 4.0 wt. %.

9. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein:
(a) the amount of the third polypropylene fraction (PP3) is in the range of 15.0 to 60.0 wt. % based on the total amount of the polypropylene (PP), and/or
(b) the amount of the first polypropylene fraction (PP1) is in the range of 20.0 to 65.0 wt. % based on the total amount of the polypropylene (PP).

10. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein weight ratio [PP3/PP1] of the third polypropylene fraction (PP3) and the first polypropylene fraction is in the range of 15/85 to 75/25.

11. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein
(a) the comonomers of the elastomeric copolymer (EC) are ethylene and/or at least one C 4 to C 10 α-olefin, and/or
(b) the amorphous phase (AM) of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer (HECO) has a comonomer content of below 45.0 wt. %.

12. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:
(a) a comonomer content equal or below 10.0 wt. %, and/or
(b) a xylene cold soluble (XCS) fraction measured according to ISO6427 (23° C.) of equal or below 20.0 wt. %, and/or
(c) hexane solubles measured according to FDA of below 3.6 wt. %, and/or
(d) a heat resistance measured according to Vicat B of more than 78° C.

13. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises:
(a) 80.0 to 94.0 wt. % of the polypropylene (PP), and
(b) 6.0 to 20.0 wt. % of the elastomeric copolymer (EC), based on the total amount of the polypropylene (PP) and the elastomeric copolymer (EC), wherein the amount of the elastomeric copolymer (EC) corresponds to the amount of the amorphous fraction (AM) of the xylene cold soluble (XCS) fraction.

14. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the polypropylene (PP) comprises:
(a) 20.0 to 65.0 wt. % of the first polypropylene fraction (PP1),
(b) 20.0 to 50.0 wt. % of the second polypropylene fraction (PP2), and
(c) 15.0 to 60.0 wt. % of the third polypropylene fraction (PP3), based on the total amount of the first polypropylene (PP1), the second polypropylene (PP2), and the third polypropylene (PP3).

15. Process for the preparation of a heterophasic propylene copolymer (HECO) according to claim 1 , in a sequential polymerization process, said heterophasic propylene copolymer (HECO) comprises a first polypropylene fraction (PP1), a second polypropylene fraction (PP2) and a third polypropylene fraction (PP3), wherein said process comprises the steps of:
(a1) polymerizing propylene and optionally at least one ethylene and/or C 4 to C 12 α-olefin in a first reactor (R1) obtaining the first polypropylene fraction (PP1),
(b1) transferring the first polypropylene fraction (PP1) into a second reactor (R2),
(c1) polymerizing in the second reactor (R2) and in the presence of said first polypropylene fraction (PP1) propylene and optionally at least one ethylene and/or C4 to C 12 α-olefin obtaining thereby the second polypropylene fraction (PP2), the first polypropylene fraction (PP1) being mixed with the second polypropylene fraction (PP2),
(d1) transferring the mixture of step (c1) into a third reactor (R3),
(e1) polymerizing in the third reactor (R3) and in the presence of the mixture obtained in step (c1) propylene and optionally at least one ethylene and/or C 4 to C 12 α-olefin obtaining thereby a third polypropylene (PP3), the first polypropylene fraction (PP1), the second polypropylene fraction (PP2) and the third polypropylene fraction (PP3) form the polypropylene (PP),
(f1) transferring the polypropylene (PP) into a fourth reactor (R4), and
(g1) polymerizing in the fourth reactor (R4) and in the presence of the polypropylene (PP) propylene and at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby an elastomeric propylene copolymer (EC), the polypropylene (PP) and the elastomeric propylene copolymer (EC) form the heterophasic propylene copolymer (HECO), or
(a2) polymerizing propylene and optionally at least one ethylene and/or a C 4 to C 12 α-olefin in a first reactor (R1) obtaining the first polypropylene fraction (PP1),
(b2) transferring the first polypropylene fraction (PP1) into a second reactor (R2),
(c2) polymerizing in the second reactor (R2) and in the presence of said first polypropylene fraction (PP1) propylene and optionally at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby the third polypropylene fraction (PP3), the first polyprop

Assignees

• Kock Cornelia
• Doshev Petar
• Potter Elisabeth
• Gsellmann Guenter
• Leskinen Pauli
• Borealis Ag

Inventors

• Kock Cornelia
• Doshev Petar
• Potter Elisabeth
• Gsellmann Guenter
• Leskinen Pauli

Classifications

• C08F297/086 Primary

  the block polymer contains at least three blocks · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L2308/00

  Chemical blending or stepwise polymerisation process with the same catalyst · CPC title

• C08L23/14 Primary

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title