Fire retardant and/or antistatic, non-mercury catalyzed polyurethane elastomer

Patent metadata

Field	Value
Publication number	US-9416256-B2
Application number	US-201314415246-A
Country	US
Kind code	B2
Filing date	Jul 18, 2013
Priority date	Jul 18, 2012
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

A fire retardant and antistatic polyurethane elastomer free of mercury and having a Shore A hardness of at least 30 is prepared from a polyol component and a prepolymer (e.g., an isocyanate) component. The polyol component comprises (A) a saturated polyester polyol of ethylene/butane/adipate of a nominal molecular weight and with a functionality of 2 or more, (B) a polyester polyol of ethylene/trimethylol propane/neopentyl adipate of nominal molecular weight and with a functionality of 2.5 or more, (C) an optional glycol chain extender, (D) an optional polymethyl alkyl siloxane defoamer, (E) an optional desiccant paste, (F) an optional polybutadiene oligomer, (G) an antistatic agent, (H) an optional surface modified fumed silica, (I) tris(2-chloro-1-methylethyl)phosphate flame retardant, (J) ammonium polyphosphate flame retardant, and (K) an organometallic catalyst other than a mercury-based organometallic catalyst, e.g., a tin-based catalyst.

First claim

I claim:

1. A polyol composition comprising in weight percent based upon the weight of the composition:
A. 10 to 60% of a saturated polyester polyol of ethylene/butane/adipate of a nominal molecular weight and with a functionality of 2 or more;
B. 40 to 90% of a polyester polyol of ethylene/trimethylol propane/neopentyl adipate of nominal molecular weight and with a functionality of 2.5 or more;
C. 0 to 20% 1,4-butane diol chain extender glycol;
D. 0 to 0.4% polymethyl alkyl siloxane defoamer dissolved in an isoparaffin;
E. 0 to 5% desiccant paste comprising 50 weight percent (wt %) of a zeolite powder suspension in castor oil;
F. 0 to 0.8% polybutadiene oligomer;
G. 0 to 10% antistatic agent;
H. 0 to 0.5% surface modified fumed silica;
I. 5 to 15% tris (2-chloro-1-methylethyl) phosphate flame retardant;
J. 5 to 15% ammonium polyphosphate flame retardant; and
K. 0.002 to 0.1% organometallic catalyst other than mercury- or lead-based organometallic catalyst.

2. The polyol composition of claim 1 in which the 1,4-butane diol chain extender is present in an amount of greater than 0 to 20 wt %.

3. The polyol composition of claim 1 in which the polymethyl alkyl siloxane defoamer is present in an amount of 0.1 to 0.4%.

4. The polyol composition of claim 1 in which the desiccant paste is present in an amount of 1 to 5%.

5. The polyol composition of claim 1 in which the polybutadiene oligomer is present in an amount of 0.4 to 0.8%.

6. The polyol composition of claim 1 in which the surface modified fumed silica is present in an amount of 0.1 to 0.5%.

7. The polyol composition of claim 1 in which the antistatic agent is a quaternary ammonium salt of an alkali metal diluted in a trialkyl phosphate or an imidazolium salt.

8. The polyol composition of claim 7 in which the organometallic catalyst is di-n-octyltin bis (isooctyl mercaptoacetate).

9. The polyol composition of claim 8 in which the antistatic agent is 1-ethyl-3-methyl imidazolium dicyanamide.

10. A process for making a fire retardant and static dissipative polyurethane elastomer free of mercury and having a Shore A hardness of at least 30, the process comprising the step of contacting at polyurethane reactive conditions
(1) A polyol composition comprising in weight percent based upon the weight of the composition:
A. 10 to 60% of a saturated polyester polyol of ethylene/butane/adipate of a nominal molecular weight and with a functionality of 2 or more;
B. 40 to 90% of a polyester polyol of ethylene/trimethylol propane/neopentyl adipate of nominal molecular weight and with a functionality of 2.5 or more;
C. 0 to 20% alkyl diol chain extender glycol;
D. 0 to 0.4% polymethyl alkyl siloxane defoamer dissolved in an isoparaffin;
E. 0 to 5% desiccant paste comprising 50 weight percent (wt %) of a zeolite powder suspension in castor oil;
F. 0 to 0.8% polybutadiene oligomer;
G. 0 to 10% antistatic agent;
H. 0 to 0.5% surface modified fumed silica;
I. 5 to 15% tris (2-chloro-1-methylethyl) phosphate flame retardant;
J. 5 to 15% ammonium polyphosphate flame retardant; and
K. 0.002 to 0.1% organometallic catalyst other than mercury- or lead-based organometallic catalyst; with

(2) A prepolymer composition comprising in weight percent based on the weight of the prepolymer composition:
L. 10 to 60% of a saturated polyester polyol of ethylene/butane/adipate of a nominal molecular weight and with a functionality of 2 or more;
M. 30 to 60% diphenylmethane diisocyanate (MDI) containing approximately 97% of 4,4-diphenylmethane diisocyanate isomer and 3% of 2,4-diphenylmethane diisocyanate isomer;
N. 5 to 15% modified MDI; and
O. 0 to 0.1% para-nitrobenzoyl chloride.

11. The process of claim 10 comprising an additional step in which the 1,4-butane diol chain extender glycol is added as a third component separate from the polyol composition and the prepolymer composition.

12. The process of claim 11 comprising a further step in which the organometallic catalyst is absent from the polyol composition and added as a fourth component separate from the polyol composition, prepolymer composition and chain extender component.

13. The process of claim 10 in which the polyol composition comprises a quaternary ammonium salt of alkali metal diluted in a trialkyl phosphate or an imidazolium salt as the antistatic agent.

14. The process of claim 10 in which the polyol composition comprises di-n-octyltin bis (isooctyl mercaptoacetate) as the organometallic catalyst and 1-ethyl-3-methyl imidazolium dicyanamide as the antistatic agent.

15. A fire retardant and static dissipative polyurethane elastomer substantially free of mercury and having a Shore A hardness of at least 30 made by the process of claim 10 .

Assignees

• Dow Global Technologies Llc

Inventors

• Grigoriew Marcin

Classifications

• C08G18/42

  Polycondensates having carboxylic or carbonic ester groups in the main chain · CPC title

• C08G18/4202

  Two or more polyesters of different physical or chemical nature (C08G18/44 takes precedence) · CPC title

• C08K5/521

  Esters of phosphoric acids, e.g. of H3PO4 · CPC title

• C08G18/6607

  with compounds of group C08G18/3203 · CPC title

• C08L75/06

  from polyesters · CPC title