Method for the preparation of a heterophasic copolymer and uses thereof

Patent metadata

Field	Value
Publication number	US-9416238-B2
Application number	US-201514729124-A
Country	US
Kind code	B2
Filing date	Jun 3, 2015
Priority date	Mar 26, 2009
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.

First claim

What is claimed is:

1. An article comprising:
an impact copolymer having a continuous phase polymer and a rubber phase polymeric material incorporated into the continuous phase polymer, wherein the continuous phase polymer is a propylene homopolymer or a propylene random copolymer having a comonomer content ranging from 0.1 to 4 weight percent, wherein the impact copolymer has an Mn ranging from 25,000 to 80,000, an Mw ranging from 150,000 to 450,000, and an Mz ranging from 450,000 to 1,500,000;
wherein the article is an injection molded article wherein a 0.02 inch sample of the injection molded article exhibits a haze of from 20% to 95%, or wherein the article is an injection stretch blow molded article exhibiting a haze of from 10% to 90%, or wherein the article is a film exhibiting an average particle size, measured by Atomic Force Microscopy, of from 0.50 μm to 4.0 μm.

2. The article of claim 1 , wherein the article is the injection molded article, and wherein a 0.02 inch sample of the injection molded article exhibits a haze of from 30% to 80%.

3. The article of claim 1 , wherein the article is the injection molded article, and wherein the injection molded article exhibits a flexural modulus of from 90 kpsi to 250 kpsi.

4. The article of claim 1 , wherein the article is the injection molded article, and wherein the injection molded article exhibits a tensile modulus of from 100 kpsi to 250 kpsi.

5. The article of claim 1 , wherein the article is the injection molded article, and wherein the injection molded article exhibits a tensile strength at yield of from 2500 psi to 4500 psi.

6. The article of claim 1 , wherein the article is the injection molded article, and wherein the injection molded article exhibits a tensile strength at break of from 1500 psi to 3000 psi.

7. The article of claim 1 , wherein the article is the injection molded article, and wherein the injection molded article exhibits an elongation at yield of from 5% to 15%.

8. The article of claim 1 , wherein the article is the injection molded article, and wherein the injection molded article exhibits an annealed heat distortion of from 150° F. to 200° F.

9. The article of claim 1 , wherein the article is the injection stretch blow molded article, and wherein the injection stretch blow molded article exhibits a haze of from 20% to 80%.

10. The article of claim 1 , wherein the article is the injection stretch blow molded article, and wherein the injection stretch blow molded article exhibits a gloss at 45° of from 10% to 65%.

11. The article of claim 1 , wherein the article is the injection stretch blow molded article, and wherein the injection stretch blow molded article exhibits a bumper compression with a load at 0.5 in deflection of from 50 N to 110 N.

12. The article of claim 1 , wherein the article is the injection stretch blow molded article, and wherein the injection stretch blow molded article exhibits a top load of from 70 N to 140 N.

13. The article of claim 1 , wherein the article is the film, and wherein the film exhibits an average particle size, measured by Atomic Force Microscopy, of from 0.7 μm to 3.5 μm.

14. The article of claim 1 , wherein the article is the film, and wherein the film exhibits a 1% secant modulus of from 55 kpsi to 110 kpsi.

15. The article of claim 1 , wherein the article is the film, and wherein the film exhibits a tensile strength at yield of from 2000 kpsi to 4000 kpsi.

16. The article of claim 1 , wherein the article is the film, and wherein the film exhibits an elongation at yield of from 7.5% to 15%.

17. The article of claim 1 , wherein the article is the film, and wherein the film exhibits a dart drop of from 300 g to greater than 1200 g.

18. The article of claim 1 , wherein the article is the film, and wherein the film exhibits an Elmendorf Tear in the machine direction of from 150 g to 250 g.

19. The article of claim 1 , wherein the article is the film, and wherein the film exhibits a film puncture of from 1.5 in-lbs to 2.5 in-lbs.

20. A method comprising:
selecting a continuous phase polymer, wherein the continuous phase polymer is a propylene homopolymer or a propylene random copolymer having a comonomer content ranging from 0.1 to 4 weight percent;
selecting a rubber phase polymeric material;
incorporating the rubber phase polymeric material into the continuous phase polymer to form an impact copolymer, wherein the impact copolymer has an Mn ranging from 25,000 to 80,000, an Mw ranging from 150,000 to 450,000, and an Mz ranging from 450,000 to 1,500,000; and
preparing an article from the impact copolymer, wherein the article is an injection molded article, wherein a 0.02 inch sample of the injection molded article exhibits a haze of from 20% to 95%, or wherein the article is an injection stretch blow molded article exhibiting a haze of from 10% to 90%, or wherein the article is a film exhibiting an average particle size, measured by Atomic Force Microscopy, of from 0.50 μm to 4.0 μm.

21. An article comprising:
an impact copolymer having a continuous phase polymer and a rubber phase polymeric material incorporated into the continuous phase polymer, wherein the impact copolymer has an Mn ranging from 25,000 to 80,000, an Mw ranging from 150,000 to 450,000, and an Mz ranging from 450,000 to 1,500,000;
wherein the article is an injection molded article, an injection stretch blow molded article, or a film; and
wherein:
the continuous phase polymer is the propylene homopolymer; or
the impact copolymer has a melting point, measured by Differential Scanning calorimetry (DSC), of from 135° C. to 170° C.; or
the impact copolymer is a two phase polymer.

22. The article of claim 21 , wherein the impact copolymer has a melting point, measured by Differential Scanning calorimetry (DSC), of from 135° C. to 170° C.

23. The article of claim 21 , wherein the impact copolymer is a two phase polymer.

Assignees

• Fina Technology

Inventors

• Leland Mark

Classifications

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08L2203/16

  used for films · CPC title

• B29K2023/14

  Copolymers of polypropylene (B29K2023/16 takes precedence) · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L23/12

  Polypropene · CPC title