Lubricating oil compositions and method for making them

Patent metadata

Field	Value
Publication number	US-9416206-B2
Application number	US-201113005388-A
Country	US
Kind code	B2
Filing date	Jan 12, 2011
Priority date	Jan 22, 2010
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

Provided are ethylene propylene copolymers compositions thereof and methods for making the same. The composition may include an ethylene copolymer, comprising 40 wt % to 70 wt % of units derived from ethylene, and at least 30 wt % of units derived from at least one α-olefin having 3 to 20 carbon atoms. The composition can have a melting point (Tm) in ° C., as measured by DSC, that satisfies the relation: Tm>3.4×E−180, where E is the weight % of units derived from ethylene in the copolymer. The composition can also have a Mw/Mn ratio of about 1.5 to about 3.5. The composition can further have a content of Group 4 metals derived from a catalyst of 25 ppm or less.

First claim

What is claimed is:

1. A composition comprising an ethylene-propylene copolymer, which copolymer was prepared in a single reactor using a single catalyst system, comprising 40 wt % to 65 wt % of units derived from ethylene, and at least 35 wt % of units derived from propylene, wherein the composition has:
40-65 wt % units derived from ethylene;
a melting point (Tm) in ° C., as measured by DSC, that satisfies the relation:
Tm>3.4 ×E −180

where E is the weight % of units derived from ethylene in the ethylene-propylene copolymer;

a Mw/Mn ratio of about 1.5 to about 3.5; and
a content of Group 4 metals derived from a catalyst of 25 ppm or less.

2. The composition of claim 1 , wherein the ethylene-propylene copolymer has a weight-average molecular weight (Mw), as measured by GPC, of about 50,000 g/mol to about 200,000 g/mol.

3. The composition of claim 1 , wherein the composition has a shear stability index, SSI, and a thickening efficiency, TE, satisfying the relation: TE>0.034*SSI+0.8.

4. The composition of claim 1 , wherein the composition has a pour point of about −35° C. or less.

5. The composition of claim 1 , wherein the composition has a low temperature viscosity in a Mini Rotary Viscometer (MRV) test at −25° C. of about 20,000 cP or less.

6. The composition of claim 1 , wherein the composition has a shear stability index, SSI, of about 35% to about 50%.

7. The composition of claim 1 , wherein the ethylene-propylene copolymer has a ratio of wt ppm Group 4 metals derived from a catalyst to wt ppm Group 5 metals derived from a catalyst of at least 3.

8. A lubricating oil composition, comprising:
a base oil; and
a high SSI viscosity index improver comprising an ethylene-propylene copolymer, which copolymer was prepared in a single reactor using a single catalyst system, comprising 40 wt % to 65 wt % of units derived from ethylene; and at least 35 wt % of units derived from propylene, wherein the ethylene-propylene copolymer has:
a melting point (Tm) in ° C., as measured by DSC, that satisfies the relation:
Tm>3.4 ×E −180

where E is the weight % of units derived from ethylene in the ethylene-propylene copolymer;

a ratio of Mw/Mn of about 1.5 to about 3.5; and
a content of Group 4 metals derived from a catalyst of 25 ppm or less; and

further wherein the high SSI viscosity index improver has 40 wt % to 65 wt % units derived from ethylene.

9. The lubricating oil composition of claim 8 , wherein the ethylene-propylene copolymer has a weight-average molecular weight (Mw), as measured by GPC, of about 50,000 g/mol to about 200,000 g/mol.

10. The lubricating oil composition of claim 8 , wherein the lubricating oil composition has a shear stability index, SSI, and a thickening efficiency, TE, satisfying the relation: TE>0.034*SSI+0.8.

11. The lubricating oil composition of claim 8 , wherein the lubricating oil composition has a pour point of about −35° C. or less.

12. The lubricating oil composition of claim 8 , wherein the lubricating oil composition has a low temperature viscosity in a Mini Rotary Viscometer (MRV) test at −25° C. of about 20,000 cP or less.

13. The lubricating oil composition of claim 8 , wherein the lubricating oil composition has a shear stability index, SSI, of about 35% to about 50%.

14. The lubricating oil composition of claim 8 , wherein the ethylene-propylene copolymer has a ratio of wt ppm Group 4 metals derived from a catalyst to wt ppm Group 5 metals derived from a catalyst of at least 3.

15. A lubricating oil composition, comprising:
a base oil and a high SSI viscosity index improver comprising an ethylene-propylene copolymer, which copolymer was prepared in a single reactor using a single catalyst system, comprising 40 wt % to 65 wt % of units derived from ethylene and at least 12 wt % of units derived from propylene, wherein the ethylene-propylene copolymer has:
a weight-average molecular weight (Mw), as measured by GPC, in the range of about 50,000 to about 200,000 g/mol;
a melting point (Tm), as measured by DSC, of at least 100° C.;
a ratio of Mw/Mn of about 1.5 to about 3.5; and
a content of Group 4 metals derived from a catalyst of 25 ppm or less; and

further wherein the high SSI viscosity index improver has 40 wt % to 65 wt % units derived from ethylene.

16. The lubricating oil composition of claim 15 , wherein the ethylene-propylene copolymer further comprises a shear stability index, SSI, and a thickening efficiency, TE, satisfying the relation: TE>0.034*SSI+0.08.

17. The lubricating oil composition of claim 15 , wherein the lubricating oil composition has a pour point of about −40° C. or less.

18. The lubricating oil composition of claim 15 , wherein the lubricating oil composition has a shear stability index, SSI, of about 35% to about 50%.

19. The lubricating oil composition of claim 15 , wherein the ethylene-propylene copolymer has a ratio of wt ppm Group 4 metals derived from a catalyst to wt ppm Group 5 metals derived from a catalyst of at least 3.

20. A method for making a lubricating oil composition, comprising:
reacting ethylene and propylene in a single reactor in the presence of a single catalyst system at conditions sufficient to produce a high SSI viscosity index improver comprising an ethylene-propylene copolymer, said high SSI viscosity index improver having 40 wt % to 65 wt % of units derived from ethylene,
wherein the single catalyst system consists of a dimethylsilyl(bisindenyl) hafnium dimethyl metallocene and a trimethylammonium tetrakis-pentafluorophenylborate activator; and
wherein the ethylene-propylene copolymer has:
40 wt % to 65 wt % of units derived from ethylene and at least 35 wt % of units derived from propylene;
a weight-average molecular weight (Mw), as measured by GPC, in the range of about 50,000 to about 200,000 g/mol;
a melting point (Tm), as measured by DSC, that satisfies the relation:
Tm>3.4 ×E −180

where E is the weight % of units derived from ethylene in the ethylene-propylene copolymer;
a ratio of Mw/Mn of about 1.5 to about 3.5; and
a content of Group 4 metals derived from a catalyst of 25 ppm or less; and

blending the high SSI viscosity index improver with a base oil in an amount sufficient to produce a lubricating oil composition.

21. The method of claim 20 , wherein the ethylene-propylene copolymer has a ratio of wt ppm Group 4 metals derived from a catalyst to wt ppm Group 5 metals derived from a catalyst of at least 3.

22. The method of claim 20 , wherein the ethylene-propylene copolymer has a weight-average molecular weight (Mw), as measured by GPC, of about 50,000 g/mol to about 200,000 g/mol.

23. The method of claim 20 , wherein the ethylene-propylene copolymer has a shear stability index, SSI, and a thickening efficiency, TE, satisfying the relation: TE>0.034*SSI+0.8.

24. The method of claim 20 , wherein the ethylene-propylene copolymer has a pour point of about −35° C. or less.

25. A lubricating oil composition comprising the composition of claim 1 .

Assignees

• Kolb Rainer
• Farng Liehpao Oscar
• Datta Sudhin
• Crowther Donna J
• Jiang Peijun
• Exxonmobil Chemical Patents Inc

Inventors

• Kolb Rainer
• Farng Liehpao Oscar
• Datta Sudhin
• Crowther Donna J
• Jiang Peijun

Classifications

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2040/255

  Gasoline engines · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2030/45

  Ash-less or low ash content · CPC title

• C10N2040/08

  Hydraulic fluids, e.g. brake-fluids · CPC title