Process for the recovery of betaines from electrodialysis waste stream

Patent metadata

Field	Value
Publication number	US-9415346-B2
Application number	US-201013147902-A
Country	US
Kind code	B2
Filing date	Feb 3, 2010
Priority date	Feb 4, 2009
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

The present invention discloses a process for the recovery of betaines from electrodialysis (ED) waste streams, whereby said waste streams are treated with a pressure driven membrane process.

First claim

The invention claimed is:

1. A process for the recovery of betaines from electrodialysis waste streams from betaine production processes comprising:
synthesizing a betaine in a reaction mixture to form a product stream;
purifying the product stream by using an electrodialysis unit to produce a purified product stream and a waste stream;
treating the waste stream by feeding the waste stream through a pressure driven membrane process, wherein the pressure driven membrane process comprises nanofiltration to produce a recovered product stream and a salt stream containing salts; and
purifying the recovered product stream by feeding the recovered product stream directly to an electrodialysis unit to produce a purified recovered product stream that is combined with the purified product stream.

2. A process according to claim 1 , wherein the product stream and the recovered product stream are both fed to the same electrodialysis unit.

3. A process according to claim 1 , wherein the product stream and the recovered product stream are fed to different electrodialysis units.

4. The process according to claim 1 , whereby said betaines are selected from the group consisting of 4-butyrobetaine and L-carnitine.

5. The process according to claim 1 , whereby said waste streams contain salts.

6. The process according to claim 1 , wherein the retention of betaines is in the range of 80-100%.

7. The process according to claim 1 , wherein the retention of betaines is about 100%.

8. The process according to claim 1 , whereby the retention of the salts is below 50%.

9. The process according to claim 1 , whereby the retention of the salts is below 10%.

10. The process according to claim 1 , wherein the pressure driven membrane process includes an applied membrane, the membrane comprising a polymer or a ceramic.

11. The process according to claim 1 , wherein the product stream is channeled into a plurality of electrodialysis units.

12. The process according to claim 1 , wherein the waste stream contains the betaine, inorganic salts, and organic compounds.

13. The process according to claim 12 , wherein the inorganic salts present in the waste stream comprise sodium chloride and sodium hydroxide.

14. The process according to claim 12 , wherein the organic compounds present in the waste stream comprise 4-hydroxybutanoic acid, (E)-4-hydroxycrotonic acid, and mixtures thereof.

15. The process according to claim 1 , wherein the waste stream contains the betaine which is purified by treating the waste stream with the pressure driven membrane process, the recovered product stream containing the betaine which is combined with more betaine contained in the purified product stream.

Assignees

• Bicker Markus
• CARAUCÁN DÁVILA Miguel Angel
• Lonza Ag

Inventors

• Bicker Markus
• CARAUCÁN DÁVILA Miguel Angel

Classifications

• C02F1/444

  by ultrafiltration or microfiltration · CPC title

• B01D61/145

  Ultrafiltration · CPC title

• C13B20/165

  using membranes, e.g. osmosis, ultrafiltration (electrodialysis C13B20/18) · CPC title

• B01D61/02

  Reverse osmosis; Hyperfiltration {; Nanofiltration} · CPC title

• C02F1/4693

  electrodialysis · CPC title