Pigmented polymerizable compositions and optical articles prepared therefrom

Patent metadata

Field	Value
Publication number	US-9411076-B2
Application number	US-201314025300-A
Country	US
Kind code	B2
Filing date	Sep 12, 2013
Priority date	Sep 14, 2012
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

Provided is a polymerizable composition including: (a) a polymerizable component; and (b) a pigment component the pigment component includes: (i) an ionic or amphoteric dispersant material; and (ii) pigment nanoparticles uniformly dispersed in the dispersant material (i). The nanoparticles have a particle size of up to 500 nanometers. Also provided is a polymerizable composition of: (a) a polymerizable component including: (i) diethylene glycol bis(allyl carbonate); and (ii) a radical initiator; and (b) a pigment component which includes: (i) an ionic or amphoteric dispersant material derived from polycaprolactone; and (ii) pigment nanoparticles of ultramarine blue having an average particle size of up to 500 nanometers, uniformly dispersed in the dispersant material.

First claim

What is claimed is:

1. A polymerizable composition comprising:
(a) a polymerizable component comprising allyl diglycol carbonate; and
(b) a pigment component comprising:
(i) an ionic or amphoteric dispersant material; and
(ii) pigment nanoparticles uniformly dispersed in the dispersant material (i), wherein the nanoparticles have an average particle size of up to 500 nanometers.

2. The polymerizable composition of claim 1 , wherein the polymerizable component (a) comprises a resinous component comprising at least one of monomers, oligomers, and/or prepolymers of any materials selected from the group consisting of allyl diglycol carbonate, poly(meth)acrylate, polycarbonate precursors, polyurethane precursors, polyureaurethane precursors, polythiourethane precursors, polyamide precursors, styrene, and mixtures thereof.

3. The polymerizable composition of claim 2 , wherein the polymerizable component (a) further comprises poly(meth)acrylate.

4. The polymerizable composition of claim 3 , wherein the polymerizable component (a) further comprises a radical initiator.

5. The polymerizable composition of claim 4 , wherein the radical initiator comprises a peroxy initiator.

6. The polymerizable composition of claim 1 , further comprising an ultraviolet light absorber and/or a hindered amine light stabilizer.

7. The polymerizable composition of claim 1 , wherein the ionic or amphoteric dispersant material is derived from an acrylic polymer and/or polycaprolactone.

8. The polymerizable composition of claim 1 , wherein the pigment nanoparticles (ii) have an average particle size of up to 200 nanometers.

9. The polymerizable composition of claim 1 , wherein at least 90 percent of the pigment nanoparticles (ii) have an average particle size of up to 300 nanometers.

10. The polymerizable composition of claim 1 , wherein the pigment nanoparticles (ii) are present in the polymerizable composition in an amount ranging from 0.01 to 1000 parts per million.

11. The polymerizable composition of claim 1 , wherein the pigment nanoparticles (ii) are present in the polymerizable composition in an amount ranging from 0.05 to 50 parts per million.

12. The polymerizable composition of claim 1 , wherein the pigment component (b) comprises organic pigment nanoparticles.

13. The polymerizable composition of claim 1 , wherein the pigment component (b) comprises inorganic pigment nanoparticles.

14. The polymerizable composition of claim 13 , wherein the inorganic pigment nanoparticles comprise (i) metal-containing inorganic pigments selected from the group consisting of ultramarine blue, ultramarine violet, reduced tungsten oxide, cobalt aluminate, cobalt phosphate, and manganese ammonium pyrophosphate; and/or (ii) metal-free inorganic pigments.

15. The polymerizable composition of claim 13 , wherein the inorganic pigment nanoparticles comprise ultramarine blue, ultramarine violet, Prussian blue, cobalt blue and/or reduced tungsten oxide.

16. The polymerizable composition of claim 12 , wherein the organic pigment nanoparticles comprise indanthrone, quinacridone, phthalocyanine blue, copper phthalocyanine blue, and/or perylene anthraquinone.

17. An optical article comprising a polymer prepared from the polymerizable composition of claim 1 .

18. The optical article of claim 17 , wherein the optical article is a lens, sheet product, scratch resistant lens, or scratch resistant sheet.

19. A polymerizable composition comprising:
(a) a polymerizable component comprising:
(i) diethylene glycol bis(allyl carbonate); and
(ii) a radical initiator; and

(b) a pigment component comprising:
(i) an ionic or amphoteric dispersant material derived from polycaprolactone; and
(ii) pigment nanoparticles comprising ultramarine blue uniformly dispersed in the dispersant material (i), wherein the nanoparticles have an average particle size of up to 500 nanometers.

Assignees

• Ppg Ind Ohio Inc

Inventors

• Slezak Brandy D
• Stewart-Davis Royann L
• Herold Robert D
• Bowman Mark P
• Szul Joseph S

Classifications

• G02B1/04 Primary

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• G02B1/041

  Lenses · CPC title

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title