Lubricant compositions comprising epoxide compounds

Patent metadata

Field	Value
Publication number	US-9410105-B2
Application number	US-201314081360-A
Country	US
Kind code	B2
Filing date	Nov 15, 2013
Priority date	Nov 16, 2012
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

A lubricant composition including an epoxide compound is disclosed. An additive package including the epoxide compound is also disclosed. The epoxide compound of the lubricant composition acts to improve compatibility of the lubricant composition with a fluoropolymer seal and improve the total base number of the lubricant composition.

First claim

The invention claimed is:

1. A lubricant composition comprising:
a base oil included in said lubricant composition in an amount of greater than 70 wt. % based on a total weight of said lubricant composition, wherein said base oil has a viscosity of from 1 to 20 cSt when tested at 100° C. according to ASTM D445, and wherein said base oil is selected from the group of API Group I base oils, API Group II base oils, API Group III base oils, and combinations thereof;
an epoxide compound included in said lubricant composition in an amount of from 0.3 to 1.2 wt. % based on the total weight of said lubricant composition, said epoxide compound having the formula:

 and
an amine compound included in said lubricant composition in an amount of from 1 to 3 wt. % based on the total weight of said lubricant composition, said amine compound having the general formula:

wherein each R 16 is independently a hydrogen atom or an alkyl group having from 1 to 17 carbon atoms, wherein at least three groups designated by R 16 are each an alkyl group; and
wherein each R 17 is independently a hydrogen atom or an alkyl group having from 1 to 17 carbon atoms.

2. The lubricant composition of claim 1 wherein at least 50 wt. % of said epoxide compound remains unreacted in said lubricant composition based on a total weight of said epoxide compound utilized to form said lubricant composition prior to any reaction in said lubricant composition.

3. The lubricant composition of claim 1 wherein said amine compound is (2,2,6,6-tetramethyl-4-piperidyl) dodecanoate.

4. The lubricant composition of claim 1 further comprising an antiwear additive comprising phosphorous included in said lubricant composition in an amount of from 0.1 to 5 wt. % based on a total weight of said lubricant composition.

5. The lubricant composition of claim 1 further comprising a dispersant included in said lubricant composition in an amount of from 0.01 to 15 wt. % based on a total weight of said lubricant composition.

6. The lubricant composition of claim 1 wherein said lubricant composition has a fluoropolymer seal compatibility such that a fluoropolymer seal submerged in said lubricant composition exhibits a change in tensile strength of from −50 to 10% when tested according to CEC L-39-T96.

7. The lubricant composition of claim 1 wherein said lubricant composition has a fluoropolymer seal compatibility such that a fluoropolymer seal submerged in said lubricant composition exhibits a change in elongation at rupture of from −60 to 10% when tested according to CEC L-39-T96.

8. The lubricant composition of claim 1 wherein said lubricant composition has a total base number of at least 3 mg KOH/g when tested according to ASTM D2896.

9. A method of lubricating a system comprising a fluoropolymer seal, said method comprising:
providing a lubricant composition comprising:
a base oil included in the lubricant composition in an amount of greater than 70 wt. % based on a total weight of the lubricant composition, wherein the base oil has a viscosity of from 1 to 20 cSt when tested at 100° C. according to ASTM D445, and wherein the base oil is selected from the group of API Group I base oils, API Group II base oils, API Group III base oils, and combinations thereof;
an epoxide compound included in the lubricant composition in an amount of from 0.3 to 1.2 wt. % based on the total weight of the lubricant composition, the epoxide compound having the formula:

 and
an amine compound included in the lubricant composition in an amount of from 1 to 3 wt. % based on the total weight of the lubricant composition, the amine compound having the general formula:

wherein each R 16 is independently a hydrogen atom or an alkyl group having from 1 to 17 carbon atoms, wherein at least three groups designated by R 16 are each an alkyl group, and
wherein each R′ 7 is independently a hydrogen atom or an alkyl group having from 1 to 17 carbon atoms; and

contacting the fluoropolymer seal with the lubricant composition.

10. The lubricant composition of claim 4 wherein said antiwear additive comprising phosphorous is a dihydrocarbyldithiophosphate salt having the general formula (XIX):
[R 21 O(R 22 O)PS(S)] 2 M  (XIX):

wherein R 21 and R 22 are each independently a hydrocarbyl groups having from 1 to 20 carbon atoms, and wherein M is a metal atom or an ammonium group.

Assignees

• Basf Se

Inventors

• Desantis Kevin J
• Hoey Michael D
• Jung Alfred Karl
• Rabbat Phil
• Jones Stephen

Classifications

• C10M2215/28

  Amides; Imides · CPC title

• C10M141/10

  at least one of them being an organic phosphorus-containing compound · CPC title

• C10N2030/42

  Phosphor free or low phosphor content compositions · CPC title

• C10M129/66 Primary

  Epoxidised acids or esters · CPC title

• C10M2223/045

  Metal containing thio derivatives · CPC title