Method of treating a high-temperature well with a fluid containing a viscosifier and a stabilizer package

Patent metadata

Field	Value
Publication number	US-9410070-B2
Application number	US-201414492001-A
Country	US
Kind code	B2
Filing date	Sep 20, 2014
Priority date	May 15, 2013
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

A treatment fluid for treating a portion of a high-temperature subterranean formation comprises: a base fluid, wherein the base fluid comprises water; a viscosifier, wherein the viscosifier is a polymer, and wherein the viscosifier is thermally stable up to a temperature of 325° F.; and a stabilizer package, wherein the stabilizer package: (A) comprises a first stabilizer and a second stabilizer, wherein the first stabilizer is an oxygen scavenger and the second stabilizer is a pH adjustor; and (B) is capable of increasing the thermal stability of the viscosifier to a temperature greater than 350° F., wherein the portion of the subterranean formation has a bottomhole temperature greater than 350° F. A method of treating a high-temperature subterranean formation comprises introducing the treatment fluid into the portion of the subterranean formation.

First claim

What is claimed is:

1. A treatment fluid for treating a portion of a subterranean formation comprising:
a base fluid, wherein the base fluid comprises water;
a viscosifier, wherein the viscosifier is a polymer, wherein the polymer is a terpolymer comprising the monomer residues of 2-acrylamido-2-methylpropane sulfonic acid, acrylamide, and acrylic acid, and wherein the viscosifier is thermally stable up to a temperature of 325° F.; and
a stabilizer package, wherein the stabilizer package:
(A) comprises a first stabilizer and a second stabilizer, wherein the first stabilizer is an oxygen scavenger and the second stabilizer is a pH adjustor, wherein the first stabilizer is present in a concentration in the range of about 3% to about 5% by weight of the treatment fluid; and
(B) is capable of increasing the thermal stability of the viscosifier to a temperature greater than 350° F.,

wherein the portion of the subterranean formation has a bottomhole temperature greater than 350° F.

2. The fluid according to claim 1 , wherein the water is selected from the group consisting of freshwater, brackish water, saltwater, and any combination thereof.

3. The fluid according to claim 1 , wherein the concentration of the monomer residues is selected such that the polymer is thermally stable up to a temperature of 325° F.

4. The fluid according to claim 1 , wherein the monomer residues are present in the following concentrations: 2-acrylamido-2-methylpropane sulfonic acid from about 15% to about 80%; acrylamide from about 20% to about 85%; and acrylic acid from about 1% to about 10% by weight of the polymer.

5. The fluid according to claim 1 , wherein the first stabilizer is selected from the group consisting of sodium thiosulfate, an alkali metal thiosulfate, sodium dithionite, disodium phosphate, sodium sulfite, zinc sulfite, hydroquinone, hydrazine, diethylhydroxylamine, carbohydrazide, and combinations thereof.

6. The fluid according to claim 1 , wherein the first stabilizer is sodium thiosulfate.

7. The fluid according to claim 1 , wherein the treatment fluid has a pH in the range of about 8.5 to 11.

8. The fluid according to claim 1 , wherein the pH adjustor is a compound that is capable of providing a pH of at least 9 to the treatment fluid.

9. The fluid according to claim 1 , wherein the pH adjustor is a base, a buffer, or an alkaline buffer.

10. The fluid according to claim 1 , wherein the second stabilizer is selected from the group consisting of sodium bicarbonate, N-cyclohexyl-2-aminoethanesulfonic acid, borate, sodium carbonate, potassium carbonate, magnesium oxide, and combinations thereof.

11. The fluid according to claim 1 , wherein the second stabilizer is sodium bicarbonate.

12. The fluid according to claim 1 , wherein the second stabilizer is in a concentration in the range of about 0.1% to about 5% by weight of the treatment fluid.

13. The fluid according to claim 1 , wherein the stabilizer package is capable of increasing the thermal stability of the viscosifier to a temperature greater than 400° F.

14. The fluid according to claim 1 , wherein the stabilizer package increases the thermal stability temperature of the viscosifier by a temperature in the range of 25° F. to about 300° F.

15. The fluid according to claim 1 , wherein the second stabilizer is present in a concentration in the range of about 0.1% to about 5% by weight of the treatment fluid, and wherein the stabilizer package is capable of increasing the thermal stability of the viscosifier to a temperature greater than 450° F.

Assignees

• Halliburton Energy Services Inc

Inventors

• Suryawanshi Prerana U
• Danait Achala V
• Kalgaonkar Rajendra A

Classifications

• C09K8/40

  Spacer compositions, e.g. compositions used to separate well-drilling from cementing masses · CPC title

• C09K8/42

  Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells (compositions for plastering C09K8/50) · CPC title

• C09K8/882

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09K8/12 Primary

  containing synthetic organic macromolecular compounds or their precursors · CPC title

• C09K8/845

  containing inorganic compounds · CPC title