Long chain branched EPDM compositions and processes for production thereof
US-8962761-B2 · Feb 24, 2015 · US
US9410008B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9410008-B2 |
| Application number | US-201314437419-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 14, 2013 |
| Priority date | Jul 22, 2013 |
| Publication date | Aug 9, 2016 |
| Grant date | Aug 9, 2016 |
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The present invention relates to an elastic terpolymer which can satisfy excellent processability and elasticity (flexibility) at the same time, and a preparation method thereof. The elastic terpolymer is a copolymer of 40 to 70 weight % of ethylene, 15 to 55 weight % of a C 3 -C 20 alpha-olefin, and 0.5 to 20 weight % of a diene obtained in the presence of a group 4 transition metal catalyst, of which i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) the Mooney viscosity (ML) and the Mooney relaxation area (MLR) measured by a Mooney viscometer (1+4+2 {circle around (a)}125° C.) can satisfy a specific relation.
Opening claim text (preview).
The invention claimed is: 1. An elastic terpolymer of 50.2 to 66.3 weight % of ethylene, 21.9 to 44.7 weight % of propylene, and 4.6 to 12.3 weight % of 5-ethylidene-2-norbornene obtained in the presence of a group 4 transition metal catalyst, of which i) the weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) the Mooney viscosity (ML) and the Mooney relaxation area (MLR) measured by a Mooney viscometer (1+4+2{circle around (a)}125 ° C.) satisfy the following General Equation 1: 11.2 ≦[MLR /( ML ) 2 ]*100≦16.0. [General Equation 1] 2. The elastic terpolymer according to claim 1 , wherein a ratio of MLR/ML is 3 or more. 3. The elastic terpolymer according to claim 1 , wherein the Mooney viscosity is 20 MU or more. 4. The elastic terpolymer according to claim 1 , having density of 0.840 to 0.895 g/cm 3 . 5. The elastic terpolymer according to claim 1 , having a molecular weight distribution of 2 to 4.
unconjugated · CPC title
with non-conjugated dienes, e.g. EPT rubbers · CPC title
Isotactic · CPC title
Low density, i.e. < 0.91 g/cm3 · CPC title
Narrow molecular weight distribution, i.e. Mw/Mn < 3 · CPC title
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