Composition for soft materials, and soft material
US-2015361209-A1 · Dec 17, 2015 · US
US9409999B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9409999-B2 |
| Application number | US-201114004849-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 5, 2011 |
| Priority date | Mar 14, 2011 |
| Publication date | Aug 9, 2016 |
| Grant date | Aug 9, 2016 |
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The present invention aims to provide a method of producing a hydrophilic modified polyrotaxane, which enables production of a hydrophilic modified polyrotaxane excellent in storage stability in an industrially advantageous way. The present invention provides a method of producing a hydrophilic modified polyrotaxane, comprising: a hydrophilic modification step of preparing a solution of a hydrophilic modified polyrotaxane by modifying all or part of hydroxy groups on a cyclodextrin of a polyrotaxane with hydrophilic modifying groups, the polyrotaxane containing the cyclodextrin, a polyethylene glycol included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a drying step in which the prepared solution of the hydrophilic modified polyrotaxane is formed into a thin film state and dried.
Opening claim text (preview).
The invention claimed is: 1. A method of producing a hydrophilic modified polyrotaxane, comprising: a hydrophilic modification step of preparing a solution of a hydrophilic modified polyrotaxane by modifying all or part of hydroxy groups on a cyclodextrin of a polyrotaxane with hydrophilic modifying groups, the polyrotaxane containing the cyclodextrin, a polyethylene glycol included in the cavities of the cyclodextrin molecules in a skewered manner, and a capping group that is placed at each end of the polyethylene glycol and prevents dissociation of the cyclodextrin molecules from the polyethylene glycol; and a drying step in which the prepared solution of the hydrophilic modified polyrotaxane is formed into a thin film state and dried, a thickness of a thin film formed being 0.1 to 2 mm. 2. The method of producing a hydrophilic modified polyrotaxane according to claim 1 , wherein the polyethylene glycol has a weight average molecular weight of 1,000 to 500,000. 3. The method of producing a hydrophilic modified polyrotaxane according to claim 1 , wherein the drying step is carried out at a drying temperature of 70° C. to 200° C. 4. The method of producing a hydrophilic modified polyrotaxane according to the claim 1 , wherein the pressure in the dryer system in the drying step is equal to or lower than an atmospheric pressure. 5. The method of producing a hydrophilic modified polyrotaxane according to the claim 1 , wherein a drying time in the drying step is two minutes or shorter.
Inclusion compounds, i.e. host-guest compounds, e.g. polyrotaxanes · CPC title
cyclic · CPC title
Cyclodextrin; Derivatives thereof · CPC title
End-capping · CPC title
Manufacture of films or sheets · CPC title
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