Method and apparatus for processing fibril cellulose and fibril cellulose product

Patent metadata

Field	Value
Publication number	US-9409998-B2
Application number	US-201314378474-A
Country	US
Kind code	B2
Filing date	Jan 29, 2013
Priority date	Feb 13, 2012
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

A method for processing fibril cellulose which is in the form of aqueous fibril cellulose gel includes lowering the pH of the aqueous fibril cellulose gel to provide aqueous fibril cellulose gel of reduced water retention capacity, and dewatering the aqueous fibril cellulose gel of reduced water retention capacity to provide dewatered fibril cellulose. The dewatering is performed by pressure filtration.

First claim

The invention claimed is:

1. A method for processing anionically charged fibril cellulose which is nanofibrillar cellulose derivative containing additional functional groups making the cellulose anionically charged, manufactured from wood fiber and wherein the fibrils have a maximum diameter of 50 nm and which derivative is in the form of aqueous viscoelastic fibril cellulose hydrogel, the method comprising
lowering the pH of the aqueous fibril cellulose hydrogel below the pKa value of the anionically charged fibril cellulose to pH 2-3 to provide aqueous fibril cellulose hydrogel of reduced water retention capacity, and
dewatering the aqueous fibril cellulose hydrogel of reduced water retention capacity in a pressure filtration step where positive pressure is applied to the aqueous fibril cellulose hydrogel to provide dewatered fibril cellulose.

2. The method according to claim 1 , wherein the anionically charged fibril cellulose is chemically modified cellulose containing dissociated acid moieties, which are carboxyl groups, and wherein pH is lowered such that the dissociated acid moieties are converted to acid form.

3. The method according to claim 1 , wherein the method comprises
contacting the aqueous fibril cellulose hydrogel with an acidic medium so that the aqueous fibril cellulose hydrogel and the acidic medium are mixed homogeneously.

4. The method according to claim 3 , wherein the acidic medium is an aqueous acidic medium.

5. The method according to claim 1 , wherein the method comprises
contacting the aqueous fibril cellulose hydro gel with a volume of acidic medium in a controlled manner so that the aqueous fibril cellulose hydrogel is kept as a separate phase and forms one or more discrete physical entities containing the fibril cellulose within the phase,
separating the one or more physical entities from the volume of acidic medium, and
dewatering the one or more physical entities to provide the dewatered fibril cellulose.

6. The method according to claim 5 , wherein the aqueous fibril cellulose hydrogel is mechanically disintegrated into discrete physical entities before or after contacting it with a volume of acidic medium.

7. The method according to claim 5 , wherein the aqueous fibril cellulose hydrogel is contacted with the volume of acidic medium by introducing aqueous fibril cellulose hydrogel through a port which comprises one or more orifices or nozzles through which the hydrogel issues.

8. The method according to claim 1 , wherein the dewatering is performed at a temperature of 30° C. or higher.

9. The method according to claim 8 , wherein the dewatering is performed at a temperature of 30-70° C.

10. The method according to claim 1 , wherein the aqueous fibril cellulose hydrogel of reduced water retention capacity is dewatered in a pressure filtration step to dry substance content of 10-30 wt-% of fibril cellulose.

11. The method according to claim 1 , wherein dewatering the aqueous fibril cellulose hydrogel of reduced water retention capacity comprises removing water by evaporation from the aqueous fibril cellulose hydrogel after the pressure filtration step.

12. The method according to claim 1 , wherein the dewatered fibril cellulose is neutralized with a base.

13. The method according to claim 1 , wherein the dewatered fibril cellulose is left in acid form.

14. The method according to claim 1 , wherein the concentration of the aqueous fibril cellulose hydrogel is 0.5-5 wt-%.

15. The method according to claim 1 , wherein the method comprises
dispersing the dewatered fibril cellulose in a liquid medium.

16. The method according to claim 15 , wherein the method comprises
transporting the dewatered fibril cellulose to a site of use and dispersing the dewatered fibril cellulose in a liquid medium at the site of use.

17. The method according to claim 1 , wherein the method comprises
adding acid-coagulable additive coagulable by the effect of lowering pH to the aqueous fibril cellulose hydrogel before lowering the pH of the aqueous fibril cellulose hydrogel, and
coagulating the additive in the hydrogel by lowering the pH.

18. The method according to claim 1 , wherein the fibrils have a diameter of 2-20 nm.

19. A fibril cellulose product having a dry substance content of 10-30 wt-% of fibril cellulose, wherein the cellulose is chemically modified nanofibrillar cellulose containing acid moieties in acid form, manufactured from wood fiber and wherein the fibrils have a maximum diameter of 50 nm.

20. The fibril cellulose product according to claim 19 , which is redispersable in water as a gel.

21. The fibril cellulose product according to claim 20 , which is redispersable in water such that at the concentration of 0.5% it shows a maximum viscosity of at least 100 Pa·s in the shear stress range between 0.01 Pa and the yield stress value as measured at 0.5% concentration in water.

22. The fibril cellulose product according to claim 20 , where the fibril cellulose has a zero shear viscosity of 1000 to 50000 Pa·s and a yield stress of 1-30 Pa, as measured at 0.5% concentration in water.

23. The fibril cellulose product according to claim 22 , where the fibril cellulose has a yield stress of 3-15 Pa, as measured at 0.5% concentration in water.

24. The fibril cellulose product according to claim 19 , wherein the product contains acid-coagulated substance coagulated by the effect of lowering pH within the fibril cellulose.

25. The fibril cellulose product according to claim 24 , wherein the product is a fibril cellulose-polymer masterbatch.

26. The fibril cellulose product of claim 19 obtained by a method for processing anionically charged fibril cellulose which is nanofibrillar cellulose derivative containing additional functional groups making the cellulose anionically charged, and is in the form of aqueous fibril cellulose hydrogel, the method comprising
lowering the pH of the aqueous fibril cellulose hydrogel below the pKa value of the anionically charged fibril cellulose to pH 2-3 to provide aqueous fibril cellulose hydrogel of reduced water retention capacity, and
dewatering the aqueous fibril cellulose hydrogel of reduced water retention capacity in a pressure filtration step where positive pressure is applied to the aqueous fibril cellulose hydrogel to provide dewatered fibril cellulose.

27. A fibril cellulose product where the fibril cellulose is anionically charged nanofibrillar cellulose having a dry substance content of 10-30 wt-% of fibril cellulose wherein the cellulose is in neutralized form in the product, manufactured from wood fiber and wherein the fibrils have a maximum diameter of 50 nm.

28. The fibril cellulose product according to claim 27 , which is redispersable in water as a gel.

29. The fibril cellulose product according to claim 28 , which is redispersable in water such that at the concentration of 0.5% it shows a maximum viscosity of at least 100 Pa·s in the shear stress range between 0.01 Pa and the yield stress value as measured at 0.5% concentration in water.

30. The fibril cellulose product according to claim 28 , where the fibril cellulose has a zero shear viscosity of 1000 to 50000 Pa·s and a yield stress of 1-30 Pa, as measured at 0.5% concentration in water.

31. The fibril cellulose product according to claim 30 , where the fibril cellulose h

Assignees

• Upm Kymmene Corp

Inventors

• Laukkanen Antti
• Nuopponen Markus

Classifications

• C08L1/02 Primary

  Cellulose; Modified cellulose · CPC title

• D21H11/18

  Highly hydrated, swollen or fibrillatable fibres · CPC title

• D21H11/20 Primary

  Chemically or biochemically modified fibres · CPC title

• C08B15/04 Primary

  Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide · CPC title

• F26B19/00

  Machines or apparatus for drying solid materials or objects not covered by groups F26B9/00 - F26B17/00 · CPC title