Process for the conversion of a hydrocarbon feedstock into a synthesis gas

Patent metadata

Field	Value
Publication number	US-9409774-B2
Application number	US-201314440755-A
Country	US
Kind code	B2
Filing date	Oct 11, 2013
Priority date	Nov 6, 2012
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

A process for converting a hydrocarbon feedstock into a synthesis gas includes: (i) passing a first stream including a hydrocarbon and steam to externally-heated catalyst-filled tubes in a heat exchange reformer where steam reforming reactions take place to generate a first reformed gas mixture, (ii) passing a second stream including a hydrocarbon and steam, after a heating step, to an autothermal reformer, where it is combined with an oxidant gas containing free oxygen and autothermally reformed to generate a second reformed gas mixture, (iii) mixing the second reformed gas mixture and the first reformed gas mixture to form a combined reformed gas mixture, and (iv) using the combined reformed gas mixture to heat the catalyst filled tubes in the heat exchange reformer to form a partially-cooled combined reformed gas mixture, wherein the partially-cooled combined reformed gas mixture is used to pre-heat the second stream fed to the autothermal reformer.

First claim

The invention claimed is:

1. A process for the conversion of a hydrocarbon feedstock into a synthesis gas, comprising:
(i) forming a mixed feed stream comprising a hydrocarbon feedstock and steam;
(ii) preheating the mixed stream to form a pre-heated mixed stream;
(iii) dividing the preheated mixed stream into a first stream and a second stream;
(iv) passing the first stream comprising a hydrocarbon and steam to externally-heated catalyst-filled tubes in a heat exchange reformer where steam reforming reactions take place to generate a first reformed gas mixture;
(v) passing the second stream comprising a hydrocarbon and steam, after a heating step, to an autothermal reformer, where it is combined with an oxidant gas containing free oxygen and autothermally reformed to generate a second reformed gas mixture;
(vi) mixing the second reformed gas mixture and the first reformed gas mixture to form a combined reformed gas mixture; and
(vii) using the combined reformed gas mixture to heat the catalyst filled tubes in the heat exchange reformer to form a partially-cooled combined reformed gas mixture, wherein the partially-cooled combined reformed gas mixture is used to pre-heat the second stream fed to the autothermal reformer by heat exchange, so that the temperature of the gas fed to the autothermal reformer is increased by between 50 and 200 degrees centigrade.

2. The process according to claim 1 , wherein the partially-cooled combined reformed gas mixture is used to pre-heat the second stream fed to the autothermal reformer and preheat the mixed stream.

3. The process according to claim 1 , wherein the second stream comprises 50-90% by volume of the total hydrocarbon fed to the heat exchange reformer and autothermal reformer.

4. The process according to claim 1 , wherein the steam contents of the first and second streams are 40-60% by volume of the total steam fed to the heat exchange reformer and autothermal reformer.

5. The process according to claim 1 , wherein the amount of steam included is such as to give an overall steam to carbon ratio of 0.5 to 2.

6. The process according to claim 1 , wherein the first and second streams additionally comprise one or more of carbon monoxide, carbon dioxide, hydrogen and a tail gas from a downstream process.

7. The process according to claim 1 , wherein the heat exchange reformer inlet temperature is in the range 350-550° C.

8. The process according to claim 1 , wherein 40 to 60 moles of oxygen are added per 100 gram atoms of hydrocarbon carbon in the hydrocarbon feedstock fed to the heat exchange reformer and autothermal reformer.

9. The process according to claim 1 , wherein the combined reformed gas mixture is at a temperature in the range 950-1150° C.

10. The process according to claim 1 , wherein the temperature of the second stream fed to the autothermal reformer is in the range 450-650° C.

11. The process according to claim 1 , wherein the partially cooled reformed gas mixture, once it has been used to pre-heat the second stream, is further cooled to form a wet synthesis gas stream by heat exchange with one or more streams selected from the hydrocarbon feedstock, steam, oxidant gas, or water under pressure.

12. The process according to claim 11 , wherein the wet synthesis gas stream is cooled further with water to condense unreacted steam, which is separated, to form a dry synthesis gas product.

13. The process according to claim 1 , wherein the second stream comprises 65-85% by volume of the total hydrocarbon fed to the heat exchange reformer and autothermal reformer.

14. The process according to claim 1 , wherein the amount of steam included is such as to give an overall steam to carbon ratio of 1 to 2.

Assignees

• Johnson Matthey Plc

Inventors

• Farnell Peter William

Classifications

• C01B3/382 Primary

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title

• C01B2203/068

  Ammonia synthesis · CPC title

• C01B2203/141

  At least two reforming, decomposition or partial oxidation steps in parallel · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title