Activated carbon with a metal based component

Patent metadata

Field	Value
Publication number	US-9409162-B2
Application number	US-201214238347-A
Country	US
Kind code	B2
Filing date	May 25, 2012
Priority date	Aug 14, 2011
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

The invention relates to an activated carbon, in particular an activated carbon with reactive and/or catalytic activity, said activated carbon being in the form of discrete activated carbon particles, preferably in a spherical and/or grain form. The activated carbon is provided with and/or comprises at least one metal component which has at least one metal-containing ionic liquid (IL) containing, in particular metal ions, preferably based on a metal compound. The invention also related to methods for producing said activated carbon, to the uses thereof and to materials provided herewith.

First claim

The invention claimed is:

1. Activated carbon particles comprising an activated carbon provided with catalytic or reactive constituents,
wherein the activated carbon is in the form of discrete activated carbon particles having a spherical or grain shape, where the activated carbon has particle sizes in the range from 0.01 to 2 mm, as determined according to the method of ASTM D2862-97/04;
wherein the activated carbon has a total pore volume in the range from 0.7 to 2.5 cm 3 /g, wherein from 30% to 85% of the total pore volume of the activated carbon is formed by pores having pore diameters in the range from 2 nm to 50 nm;
wherein the activated carbon has a specific BET surface area in the range from 500 m 2 /g to 3,500 m 2 /g;
wherein the activated carbon is provided with at least one metal component, wherein the metal component comprises at least one metal-containing ionic liquid (IL) comprising at least one metal compound dissolved or dissociated in the ionic liquid (IL), wherein the metal compound comprises at least one metal selected from the group consisting of Cu, Ag, Au, Zn, Hg, Sn, Ce, Ti, Zr, V, Nb, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and Pt;
wherein the ionic liquid (IL) is selected from the group consisting of:
(i) compounds of the general formula [Cat] n+ [An] n− where “Cat” is a cation and “An” is an anion and “n” is an integer equal to 1 or 2; and
(ii) compounds of the general formula [Cat 1 ] x y+ [An 1 ] y x− where “Cat 1 ” is a cation and “An 1 ” is an anion and “x” and “y” are each, independently of one another, an integer in the range from 1 to 4,

where the cation of the ionic liquid (IL) is selected among nitrogen-containing cations selected from the group consisting of quaternary ammonium cations, imidazolium cations, pyridinium cations, pyrazolium cations and triazinium cations and phosphorus-containing cation in the form of a phosphonium cation and where the anion of the ionic liquid (IL) is an organic or inorganic anion; and
wherein the activated carbon comprises the metal-containing ionic liquid (IL) in amounts of from 1% by volume to 70% by volume, based on the volume of the activated carbon; or wherein the amount of metal-containing ionic liquid (IL), determined as the pore-filling degree α, is such that 20% to 95% of the pore volume of the activated carbon is not filled with the metal-containing ionic liquid (IL),
wherein the pore-filling degree α is determined according to the formula [α=V IL /(V pore · m support )], wherein “V IL ” designates the volume of the ionic liquid to be used, “m support ” designates the mass of the activated carbon to be used and “V pore ” designates the specific pore volume of the activated carbon.

2. The activated carbon particles as claimed in claim 1 ,
wherein the metal component includes the metal in a positive oxidation state, wherein the oxidation state of the metal lies in the range from +I to +VII.

3. The activated carbon particles as claimed in claim 1 ,
wherein the metal component includes at least one metal selected from the group of Zn, Ag, Sn, Ni and Cu.

4. The activated carbon particles as claimed in claim 1 ,
wherein the metal component includes an organic or inorganic metal salt, based on the metal, wherein the salt is selected from the group of halide salts, sulfates, sulfides, sulfites, nitrates, nitrites, phosphates, phosphides, phosphites, carbamates, alkoxides and carboxylic acid salts.

5. The activated carbon particles as claimed in claim 1 ,
wherein the metal component includes the metal compound selected from the group of nickel chloride, copper chloride, zinc acetate and tin acetate.

6. The activated carbon particles as claimed in claim 1 ,
wherein the ionic liquid (IL) contains the metal in amounts of 0.001 wt % to 80 wt %, based on the ionic liquid (IL) and calculated as metal.

7. The activated carbon particles as claimed in claim 1 ,
wherein the ionic liquid (IL) contains the metal in a molar mass fraction ranging from 1% to 90%, based on the ionic liquid (IL) and calculated as metal.

8. The activated carbon particles as claimed in claim 1 ,
wherein the molar ratio of ionic liquid (IL) to metal “[ionic liquid (IL) : metal]” lies in the range from [10:0.1] to [0.1:10].

9. The activated carbon particles as claimed in claim 1 ,
wherein the activated carbon includes the metal-containing ionic liquid (IL) in amounts of 2 vol % to 60 vol %, based on the volume of the activated carbon.

10. The activated carbon particles as claimed in claim 1 ,
wherein the activated carbon, with respect to the metal-containing ionic liquid (IL), has a pore-filling degree α of 0.05 to 0.8, wherein the pore-filling degree α is determined according to the formula [α=V IL /(V pore ·m support )].

11. The activated carbon particles as claimed in claim 1 ,
wherein the pore-filling degree and the amount of metal-containing ionic liquid (IL) are determined such that 30% to 90% of the pore volume of the activated carbon is not filled with the metal-containing ionic liquid (IL).

12. A process for producing activated carbon particles as claimed in claim 1 ,
wherein the process comprises the step of providing activated carbon particles with at least one metal component wherein the metal component comprises at least one metal-containing ionic liquid (IL) comprising at least one metal compound dissolved or dissociated in the ionic liquid (IL), wherein the metal compound comprises at least one metal selected from the group consisting of Cu, Ag, Au, Zn, Hg, Sn, Ce, Ti, Zr, V, Nb, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and Pt, wherein a plurality of discrete activated carbon particles having a spherical or grain shape are brought into contact with the ionic liquid (IL);
wherein the activated carbon particles used as a starting material have particle sizes in the range from 0.01 to 2 mm, as determined according to the method of ASTM D2862-97/04, and wherein the activated carbon has a total pore volume in the range from 0.7 to 2.5 cm 3 /g, wherein from 30% to 85% of the total pore volume of the activated carbon is formed by pores having pore diameters in the range from 2 nm to 50 nm;
wherein the activated carbon has a specific BET surface area in the range from 500 m 2 /g to 3,500 m 2 /g;
wherein the ionic liquid (IL) is selected from the group consisting of:
(i) compounds of the general formula [Cat] n+ [An] n− where “Cat” is a cation and “An” is an anion and “n” is an integer equal to 1 or 2; and
(ii) compounds of the general formula [Cat 1 ] x y+ [An 1 ] y x− where “Cat 1 ” is a cation and “An 1 ” is an anion and “x” and “y” are each, independently of one another, an integer in the range from 1 to 4,

where the cation of the ionic liquid (IL) is selected among nitrogen-containing cations selected from the group consisting of quaternary ammonium cations, imidazolium cations, pyridinium cations, pyrazolium cations and triazinium cations and phosphorus-containing cation in the form of a phosphonium cation and where the anion of the ionic liquid (IL) is an organic or inorganic anion; and
wherein the resulting activated carbon particles provided with at least one metal component comprise the metal-containing ionic liquid (IL) in amounts of from 1% by volume to 70% by volume, based on the volume of the activated carbon; or wherein the amount of metal-containing ionic liquid (IL), determined as the pore-filling degree of the resulting activated carbon particles provided with at least one metal component, is such that 20% to 95% of the pore volume of the activated carbon particles is not filled with the metal-containing ionic liquid (IL),
wherein the pore-filling degree α is d

Assignees

• Bohringer Bertram
• Eckle Ilsebill
• Wasserscheid Peter
• Roth Daniel
• Bluecher Gmbh

Inventors

• Bohringer Bertram
• Eckle Ilsebill
• Wasserscheid Peter
• Roth Daniel

Classifications

• C01B32/372

  Coating; Grafting; Microencapsulation · CPC title

• B01D2239/1291

  Other parameters · CPC title

• B01J20/28073

  being in the range 0.5-1.0 ml/g · CPC title

• C01P2004/60

  Particles characterised by their size · CPC title

• B01J20/3236

  containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts · CPC title