Solid oxide fuel cell
US-9214693-B2 · Dec 15, 2015 · US
US9406944B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9406944-B2 |
| Application number | US-201213589721-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 20, 2012 |
| Priority date | Aug 18, 2011 |
| Publication date | Aug 2, 2016 |
| Grant date | Aug 2, 2016 |
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In one aspect, the present subject matter is directed to a composite anode for a hydrocarbon solid oxide fuel cell, the anode comprising a layered perovskite ceramic and a bi-metallic alloy.
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What is claimed is: 1. A composite anode for a hydrocarbon solid oxide fuel cell, the anode comprising a layered perovskite ceramic and a bi-metallic alloy, wherein the layered perovskite comprises Pr 0.8 Sr 1.2 (Co,Fe) 0.8 Nb 0.2 O 4 . 2. The anode of claim 1 , wherein the bi-metallic alloy comprises Co—Fe. 3. The anode of claim 1 , wherein the anode is configured to be oxidized and comprise a cubic perovskite. 4. The anode of claim 1 , wherein the layered perovskite ceramic has a lattice spacing of less than 0.5 nanometers. 5. The anode of claim 1 , wherein the layered perovskite ceramic has a lattice spacing of less than 0.3 nanometers. 6. A hydrocarbon solid oxide fuel cell comprising: an anode, the anode comprising layered perovskite ceramic and a bi-metallic alloy, wherein the anode comprises Pr 0.8 Sr 1.2 (Co,Fe) 0.8 Nb 0.2 O 4 ; a cathode; and an electrolyte. 7. The fuel cell of claim 6 , wherein the bi-metallic alloy comprise Co—Fe. 8. The fuel cell of claim 6 , wherein the cathode comprises Ba 0.9 Co 0.7 Fe 0.2 Nb 0.1 O 3 . 9. The fuel cell of claim 6 , wherein the electrolyte comprises La 0.8 Sr 0.2 Ga 0.83 Mg 0.17 O 3 . 10. The fuel cell of claim 6 , wherein the cathode comprises Ba 0.9 Co 0.7 Fe 0.2 Nb 0.1 O 3 and the electrolyte comprises La 0.8 Sr 0.2 Ga 0.83 Mg 0.17 O 3 . 11. A method of forming a composite anode for a hydrocarbon solid oxide fuel cell, the method comprising: printing electrode ink on an electrolyte surface, the electrode ink comprising a layered perovskite ceramic and a bi-metallic alloy, wherein the layered perovskite comprises Pr 0.8 Sr 1.2 (Co,Fe) 0.8 Nb 0.2 O 4 . 12. The method of claim 11 , wherein the bi-metallic alloy comprise Co—Fe. 13. The method of claim 11 , further comprising oxidizing the anode to form a cubic perovskite.
Fuel cells · CPC title
consisting of more than one material, e.g. consisting of composites · CPC title
Coating with slurry or ink · CPC title
Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title
Fuel cells with solid oxide electrolytes · CPC title
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