Binder composition for rechargeable lithium battery, preparing method of same, and rechargeable lithium battery including binder composition

Patent metadata

Field	Value
Publication number	US-9406937-B2
Application number	US-201314139344-A
Country	US
Kind code	B2
Filing date	Dec 23, 2013
Priority date	Jul 8, 2013
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

A binder composition for a rechargeable lithium battery includes a semi-interpenetrating polymer network (semi-IPN) including a copolymer including a repeating unit represented by the following Chemical Formula 1 and a repeating unit represented by the following Chemical Formula 2 and polyacrylamide, and polyalkylene glycol.

In Chemical Formula 1, R 1 and R 2 are the same or different and are independently selected from hydrogen, or a substituted or unsubstituted C1 to C10 alkyl group, and R 3 and R 4 are an alkali metal. In Chemical Formula 2, R 5 to R 8 are the same or different, and are independently hydrogen, a substituted or unsubstituted C1 to C30 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C1 to C30 alkoxy group.

First claim

What is claimed is:

1. A binder composition for a rechargeable lithium battery, the binder composition comprising:
a semi-interpenetrating polymer network (semi-IPN) including:
a copolymer having a repeating unit represented by the following Chemical Formula 1 and a repeating unit represented by the following Chemical Formula 2, and
polyacrylamide, and

polyalkylene glycol

wherein,
R 1 and R 2 are the same or different and are independently selected from hydrogen, or a substituted or unsubstituted C1 to C10 alkyl group, and
R 3 and R 4 are an alkali metal, and

wherein,
R 5 to R 8 are the same or different, and are independently hydrogen, a substituted or unsubstituted C1 to C30 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C1 to C30 alkoxy group.

2. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein:
the repeating unit represented by Chemical Formula 1 is included in an amount of about 40 mol % to about 90 mol % based on a total amount of the copolymer, and
the repeating unit represented by Chemical Formula 2 is included in an amount of about 10 mol % to about 60 mol % based on the total amount of the copolymer.

3. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein in the semi-interpenetrating polymer network, a mole ratio of the copolymer to the polyacrylamide ranges from about 1:9 to about 5:5.

4. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein the binder composition includes:
about 5 mol % to about 50 mol % of polyalkylene glycol, based on a sum of the copolymer, the polyacrylamide, and the polyalkylene glycol.

5. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein a weight-average molecular weight of the polyalkylene glycol ranges from about 400 g/mol to about 10,000 g/mol.

6. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein the binder composition further comprises a free lithium ion (Li + ).

7. The binder composition for a rechargeable lithium battery as claimed in claim 6 , wherein the free lithium ion is included in an amount of about 1 mol % to about 10 mol % based on a sum of the copolymer and the polyacrylamide.

8. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein the binder composition has a pH of about 8 to about 11.

9. The binder composition for a rechargeable lithium battery as claimed in claim 1 , wherein a viscosity of the binder composition ranges from about 10,000 cps to about 100,000 cps.

10. A rechargeable lithium battery, comprising:
an electrode including the binder composition as claimed in claim 1 , and an electrode active material; and
an electrolyte.

11. The rechargeable lithium battery as claimed in claim 10 , wherein the electrode active material includes a silicon-based compound, graphite, or a combination thereof.

12. The rechargeable lithium battery as claimed in claim 10 , wherein the electrode active material includes about 10 wt % to about 90 wt % of graphite.

13. The rechargeable lithium battery as claimed in claim 10 , wherein a loading level of the electrode ranges from about 4.5 g/cm 2 to about 10 g/cm 2 .

14. A method of preparing a binder composition for a rechargeable lithium battery, the method comprising:
adding a copolymer of at least one monomer selected from an olefin-based monomer, an aromatic vinyl monomer, and an alkyl vinyl ether monomer and a cyclic unsaturated acid anhydride monomer, and polyalkylene glycol to a solvent;
adding an alkali metal-containing compound to the resultant solution; and
adding an acrylamide monomer to the resultant solution to form polyacrylamide by polymerization and form a semi-interpenetrating network structure of the copolymer and polyacrylamide, wherein:
the at least one monomer selected from an olefin-based monomer, an aromatic vinyl monomer, and an alkyl vinyl ether monomer and the cyclic unsaturated acid anhydride monomer are selected such that the copolymer has a repeating unit represented by the following Chemical Formula 1 and a repeating unit represented by the following Chemical Formula 2,

wherein,
R 1 and R 2 are the same or different and are independently selected from hydrogen, or a substituted or unsubstituted C1 to C10 alkyl group, and
R 3 and R 4 are an alkali metal, and

wherein,
R 5 to R 8 are the same or different, and are independently hydrogen, a substituted or unsubstituted C1 to C30 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C1 to C30 alkoxy group.

15. The method as claimed in claim 14 , wherein:
the cyclic unsaturated acid anhydride monomer is included in an amount of 40 mol % to 90 mol % based on a total amount of the copolymer, and
the at least one monomer selected from the olefin-based monomer, aromatic vinyl monomer, and alkyl vinyl ether monomer is included in an amount of about 10 to about 60 mol % based on the total amount of the copolymer.

16. The method as claimed in claim 14 , wherein the polyalkylene glycol is added in an amount of about 5 mol % to about 50 mol % based on a sum of the copolymer, the polyacrylamide, and polyalkylene glycol.

17. The method as claimed in claim 14 , wherein, during adding the alkali metal-containing compound to the solution, the alkali metal-containing compound is included in an amount of about 28 parts by weight to about 34 parts by weight based on 100 parts by weight of the copolymer.

18. The method as claimed in claim 14 , wherein a mole ratio of the copolymer to the polyacrylamide ranges from about 1:9 to about 5:5.

19. The method as claimed in claim 14 , wherein the method further comprises, during performing polymerization and forming the semi-interpenetrating network structure after adding the acrylamide monomer to the solution, adding a polymerization initiator to the solution.

20. The method as claimed in claim 14 , wherein the method further comprises, after forming the semi-interpenetrating network structure, adding a lithium-containing compound.

21. The method as claimed in claim 20 , wherein, during adding the lithium-containing compound, the lithium-containing compound is added such that a content of a lithium ion is about 1 mol % to about 10 mol % based on a sum of the copolymer and the polyacrylamide.

Assignees

• Samsung Sdi Co Ltd
• Aekyung Chemical Co Ltd
• Aekyung Chemical Co Ltd

Inventors

• Chung Byung-Joo
• Lee Eon-Mi
• Kwon Seung-Uk
• Kim Jae-Hyuk
• Suh Soon-Sung
• Jeong Chang-Ui
• Yoo Ha-Na
• Kim Nam-Seon
• Kim Yang-Soo
• Choi Kwang-Sik

Classifications

• H01M10/052

  Li-accumulators · CPC title

• C08F210/10

  Isobutene · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• C08F8/30

  Introducing nitrogen atoms or nitrogen-containing groups · CPC title

• C08L2205/04

  containing interpenetrating networks · CPC title