Photoelectric conversion device, electromagnetic wave detection device, photoelectric conversion method and electromagnetic wave detection method
US-12567553-B2 · Mar 3, 2026 · US
US9406488B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9406488-B2 |
| Application number | US-201414190835-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 26, 2014 |
| Priority date | Mar 15, 2013 |
| Publication date | Aug 2, 2016 |
| Grant date | Aug 2, 2016 |
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A method of achieving heightened quantum efficiencies and extended photocathode lifetimes is provided that includes using an electron beam bombardment to activate color centers in a CsBr film of a photocathode, and using a laser source for pumping electrons in the color centers of the photocathode.
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What is claimed: 1. A method of achieving heightened quantum efficiencies and extended photocathode lifetimes, comprising: a. using an electron beam bombardment to activate color centers in a photocathode, wherein said photocathode comprises a substrate layer, a conductive layer, an alkali halide film disposed on said conductive layer or a semiconductor film disposed on said conductive layer, wherein said electron beam bombardment bombards said alkali halide film or said semiconductor film as a pre-treatment, wherein said electron bombardment generates in-gap color center states or intra-band states in said alkali halide film or said semiconductor film to enable photon excitation in a bandgap of said alkali halide film or said semiconductor film, wherein said color centers comprise energy levels within a band gap of said alkali halide film or said semiconductor film of said photocathode, wherein said electron beam is disposed to directly bombard said photocathode with electrons; and b. using photons from a separate light source for pumping electrons in said color centers of said photocathode, wherein said photon excitation in said bandgap of said alkali halide film or said semiconductor film is provided at a different time from said electron bombardment, wherein said pumped electrons improve a quantum efficiency of said photocathode, wherein said pumped electrons improve the lifetime of said photocathode. 2. The method according to claim 1 , wherein said light source is selected from the group consisting of laser, LED, and incandescent light bulb. 3. The method according to claim 2 , wherein said laser comprises a 405 nm laser source. 4. The method according to claim 1 , wherein said photocathode is selected from the group consisting of a doped alkali halide-on-metal, a doped alkali halide-on-semiconductor, a doped alkali halide film, a doped alkali halide-on-ITO film, a semiconductor-on-metal, a semiconductor-on-ITO film, a doped semiconductor-on-metal, and a doped semiconductor-on-ITO film. 5. The method according to claim 4 , wherein said alkali halide film is selected from the group consisting of a CsBr film, a CsI film, a GaN substrate coated with CsBr, a doped CsBr film and a doped CsI film, wherein said doped CsBr film is capable of having a color center that is different than said CsBr color center, wherein said doped CsI film is capable of having a color center that is different than said CsI color center. 6. The method according to claim 4 , wherein said color centers are created with energy levels up to the material band gap energy above the valence band maximum, wherein said CsBr has an energy bandgap of ˜7.3 eV. 7. The method according to claim 1 , wherein said color centers are created with energy levels up to the material band gap energy above the valence band maximum. 8. The method according to claim 1 , wherein said electron beam bombardment is repeated during operation of said photocathode, wherein said repeated electron beam bombardment is directed to a previously exposed or unexposed region of said photocathode. 9. The method according to claim 1 , wherein said electron beam source comprises a pulsed or a CW electron beam source. 10. The method according to claim 1 , wherein said electron bombardment generates desorption in said alkali halide film to expose a monolayer at the alkali halide surface to reduce a work function of said alkali halide film.
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