Generation of VUV, EUV, and X-ray Light Using VUV-UV-VIS Lasers
US-2016315442-A1 · Oct 27, 2016 · US
US9405168B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9405168-B2 |
| Application number | US-201414512627-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 13, 2014 |
| Priority date | Oct 18, 2013 |
| Publication date | Aug 2, 2016 |
| Grant date | Aug 2, 2016 |
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Disclosed is a method for fabricating a wavelength conversion device that is capable of suppressing unintended and random polarization reversal due to heating thereby achieving higher wavelength conversion efficiency. The method includes: forming an insulating layer on one place of a crystal substrate naturally and uniformly polarized in a thickness direction; forming an insulating layer pattern with line-and-space by photolithography; then supplying conductive fluid to both planes of the crystal substrate to apply voltage to the crystal substrate, thereby a wavelength conversion device that is periodically polarization-reversed is fabricated. When temperature of the crystal substrate decreases after heating, an ionizer supplies ions to a surface of the crystal substrate, negative ions collect on +z plane, and positive ion collect on −z plane, thereby unintended and random polarization reversal is suppressed.
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What is claimed is: 1. A method of fabricating a wavelength conversion device, the device being fabricated from a crystal substrate and having a structure that is periodically polarization-reversed in the direction perpendicular to a thickness direction of the crystal substrate formed from a ferroelectric crystal demonstrating a non-linear optical effect, the method comprising: heating the crystal substrate; and removing electricity on a surface of the crystal substrate when temperature of the crystal substrate being changing due to the heating, the method further comprising: forming an insulating layer on at least one plane of the crystal substrate; forming a pattern with line-and-space of the insulating layer; and periodically applying voltage to the crystal substrate using the formed pattern with line-and-space of the insulating layer, wherein the heating is carried out after the forming the insulating layer, and before or after the forming the pattern. 2. The method of fabricating a wavelength conversion device according to claim 1 wherein the removing electricity is carried out by collecting, on the surface of the crystal substrate, ions having a polarity different from a polarity on a region of the surface of the crystal substrate in which natural polarization occurs. 3. The method of fabricating a wavelength conversion device according to claim 2 wherein the removing electricity is carried out by use of an ionizer. 4. The method of fabricating a wavelength conversion device according to claim 3 , the applying voltage further comprising: supplying conductive fluid to the crystal substrate in a manner that the conductive fluid contacts a region of the surface of the crystal substrate that is not covered with the insulating layer, the region consisting of each of linear portions constituting the line-and-space; and applying the voltage to the crystal substrate through the conductive fluid. 5. The method of fabricating a wavelength conversion device according to claim 3 , wherein the heating is carried out after forming the insulating layer. 6. The method of fabricating a wavelength conversion device according to claim 3 , wherein the removing electricity is carried out when the temperature of the crystal substrate decreases. 7. A wavelength conversion device fabricated by the method of fabricating a wavelength conversion device according to claim 3 . 8. The method of fabricating a wavelength conversion device according to claim 2 , the applying voltage further comprising: supplying conductive fluid to the crystal substrate in a manner that the conductive fluid contacts a region of the surface of the crystal substrate that is not covered with the insulating layer, the region consisting of each of linear portions constituting the line-and-space; and applying the voltage to the crystal substrate through the conductive fluid. 9. The method of fabricating a wavelength conversion device according to claim 2 , wherein the heating is carried out after forming the insulating layer. 10. The method of fabricating a wavelength conversion device according to claim 2 , wherein the removing electricity is carried out when the temperature of the crystal substrate decreases. 11. A wavelength conversion device fabricated by the method of fabricating a wavelength conversion device according to claim 2 . 12. The method of fabricating a wavelength conversion device according to claim 1 , the applying voltage further comprising: supplying conductive fluid to the crystal substrate in a manner that the conductive fluid contacts a region of the surface of the crystal substrate that is not covered with the insulating layer, the region consisting of each of linear portions constituting the line-and-space; and applying the voltage to the crystal substrate through the conductive fluid. 13. The method of fabricating a wavelength conversion device according to claim 12 , wherein the removing electricity is carried out when the temperature of the crystal substrate decreases. 14. A wavelength conversion device fabricated by the method of fabricating a wavelength conversion device according to claim 12 . 15. The method of fabricating a wavelength conversion device according to claim 1 , wherein the heating is carried out after forming the insulating layer. 16. The method of fabricating a wavelength conversion device according to claim 1 , wherein the removing electricity is carried out when the temperature of the crystal substrate decreases. 17. A wavelength conversion device fabricated by the method of fabricating a wavelength conversion device according to claim 1 .
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