Processes for recovering organic solvent extractant from solid-stabilized emulsions formed in hydrometallurgical solvent extraction circuits
US-9474990-B2 · Oct 25, 2016 · US
US9404166B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9404166-B2 |
| Application number | US-201213454932-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 24, 2012 |
| Priority date | Sep 4, 2007 |
| Publication date | Aug 2, 2016 |
| Grant date | Aug 2, 2016 |
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A composition comprising a substrate, an organic ion, and a metal binding agent, wherein the substrate comprises a natural clay, a synthetic clay, a natural zeolite, a synthetic zeolite, a polymer resin, lignite, kaolinite, serpentine, illite, chlorite, smectite, montmorillonite, saponite, sepiolite, nontronite, beidellite, hectorite, fuller's earth, attapulgite, bentonite, analcime, chabazite, heulandite, natrolite, phillipsite, stilbite, diethyl aminoethyl, quaternary aminoethyl, or combinations thereof, wherein the organic ion comprises quaternary amines, imidazolium salts, phosphonium salts, tetra alkyl ammonium, bis-(hydrogenated tallow)-dimethyl-ammonium chloride, bis-(hydrogenated tallow)-benzyl-methyl-ammonium chloride, 4,5-dihydro-1-methyl-2-nortallow-alkyl-1-(2-tallow-amidoethyl)-imidazolium methyl sulfate, 1-ethyl-4,5-dihydro-3-(2-hydroxyethyl)-2-(8-heptadecenyl)-imidazolium ethyl sulfate, or combinations thereof, and wherein the metal-binding agent comprises mercaptan, carboxylic acid, chelating agents, amines, esters, carboxylic acids, alcohols, ethers, aldehydes, ketones, alkenes, alkynes, mercaptans, thiols, tert-dodecanethiol, nonanethiol, octanethiol, n-stearic acid, iso-stearic acid, palmitic acid, or combinations thereof.
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What is claimed is: 1. A composition comprising: a substrate, an organic ion, and a metal binding agent, wherein the substrate comprises bentonite in an amount of from about 30% to about 90% by weight of the composition; wherein the organic ion comprises bis-(hydrogenated tallow)-benzyl-methyl-ammonium chloride in an amount of from about 10% to about 70% by weight of the composition; and wherein the metal-binding agent comprises tert-dodecanethiol and iso-stearic acid in…
Chemistry & Metallurgy · mapped topic
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