Use of composition to reduce weeping and migration through a water soluble film

Patent metadata

Field	Value
Publication number	US-9404071-B2
Application number	US-201514731455-A
Country	US
Kind code	B2
Filing date	Jun 5, 2015
Priority date	Dec 6, 2012
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

The present invention relates to the use of a composition comprising
a) anionic surfactant; and b) solvent system comprising at least one primary solvent having Hansen solubility (δ) of less than 29 said composition being encapsulated in a water soluble film pouch, for reducing migration and weeping of said composition through said film.

First claim

What is claimed is:

1. A method for reducing migration and weeping of a composition through a water soluble film, comprising the steps of
a) providing an anionic surfactant;
b) mixing said anionic surfactant with a solvent system comprising at least one primary solvent having Hansen solubility (δ) of less than about 29, thereby forming a composition, wherein the composition further comprises a hueing dye, wherein the hueing dye is selected from the group having Formula I below:
[D]—[A] n   Formula I

wherein D represents the residue of a dye comprising a chromophore and A is a moiety selected from the group consisting of OSO 3 M, SO 3 M, CO 2 M, OCO 2 M, OPO 3 M 2 , OPO 3 HM and OPO 2 M, M is selected from the group consisting of Hydrogen, an alkali or alkali earth metal ion and the index n is an integer from 1 to 6; and
c) encapsulating said composition in a water soluble film, wherein the water soluble film comprises a polymer selected from those having Formula V:
[Y]—[G] n   Formula V

wherein Y represents a vinyl alcohol monomer and G represents a monomer comprising an anionic group selected from the group consisting of OSO 3 M, SO 3 M, CO 2 M, OCO 2 M, OPO 3 M 2 , OPO 3 HM and OPO 2 M and the index n is from 1 to 3.

2. A method according to claim 1 wherein the primary solvent has molecular weight of less than about 1500.

3. A method according to claim 1 wherein the primary solvent has a cLog P of greater than about −1.0.

4. A method according to claim 1 wherein the primary solvent has a Hydrogen bonding component of less than about 20.5.

5. A method according to claim 1 wherein G is selected from the group consisting of carboxylic acids.

6. A method according to claim 1 wherein the anionic surfactant is present at a level of from about 2% to about 60.

7. A method according to claim 1 wherein the primary solvent is selected from the group consisting of polyethylene glycol (PEG) polymer having molecular weight between about 400 and about 600, dipropylene glycol (DPG), nbutoxy propoxy propanol (nBPP) and mixtures thereof.

8. A method according to claim 1 wherein the primary solvent is present at a level of from about 1 to about 25%.

9. A method according to claim 1 wherein the solvent system additionally comprises a secondary solvent selected from the group consisting of glycerol, water and mixtures thereof.

10. A method according to claim 9 wherein the secondary solvent is glycerol and is present at a level of less than about 5%.

11. A method according to claim 9 wherein the secondary solvent is water and is present at a level of less than about 20%.

12. A method according to claim 9 wherein the ratio of primary solvent to glycerol is from 7:1 to 1:5.

13. The method according to claim 1 wherein in formula I, A is selected from the group consisting of OSO 3 M, SO 3 M, CO 2 M, and OCO 2 M.

14. The method according to claim 1 wherein M is selected from the group consisting of hydrogen, sodium or potassium ion.

15. The method according to claim 1 wherein in formula I, the index n is from 1 to 4.

16. The method according to claim 1 wherein the chromophore group of dye residue, D, provides the negatively charged hueing dye with a maximum extinction coefficient in methanol solution greater than about 1000 liter/mol/cm in the wavelength range of about 400 nm to about 750 nm.

17. The method according to claim 1 wherein chromophore group of dye residue, D, is selected from the group consisting of benzodifurane, methine, triphenylmethane, azine, tripehnoxazine, naphthalimide, pyrazole, naphthoquinone, anthraquinone, mono-azo and bis-azo and mixtures thereof.

18. The method according to claim 1 , wherein G is selected from the group consisting of maleic acid, itaconic acid, coAMPS, acrylic acid, vinyl acetic acid, vinyl sulfonic acid, allyl sulfonic acid, ethylene sulfonic acid, 2 acrylamido 1 methyl propane sulfonic acid, 2 acrylamido 2 methyl propane sulfonic acid, 2 methyl acrylamido 2 methyl propane sulfonic acid and mixtures thereof.

19. The method according to claim 16 , wherein the chromophore group of dye residue, D, provides the negatively charged hueing dye with a maximum extinction coefficient of from about 10,000 to about 100,000 liter/mol/cm in the wavelength range of about 540 nm to about 630 nm.

20. The method according to claim 17 wherein chromophore group of the dye residue, D, is selected form the group consisting of Azine, anthraquinone, azo chromophores and mixtures thereof.

Assignees

• Procter & Gamble

Inventors

• Labeque Regine
• Van Elsen Katrien Andrea Lieven

Classifications

• C11D1/02

  Anionic compounds {(C11D1/002, C11D1/004, C11D1/008 take precedence)} · CPC title

• C11D3/43

  Solvents · CPC title

• C11D17/042 Primary

  Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions · CPC title