System and method for purifying process water produced from biomass conversion to fuels
US-9216916-B2 · Dec 22, 2015 · US
US9404049B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9404049-B2 |
| Application number | US-201414267211-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 1, 2014 |
| Priority date | Dec 31, 2009 |
| Publication date | Aug 2, 2016 |
| Grant date | Aug 2, 2016 |
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A process and system are described for the processing of gas associated with crude oil production, i.e. associated gas. A separation complex is used to separate produced fluids produced from a hydrocarbon reservoir into crude oil, liquefied petroleum gas, water, and natural gas. At least a portion of the natural gas is converted into synthesis gas in a synthesis gas generator. A combination of a synthesis gas conversion catalysts and hydroconversion catalysts are used in a synthesis gas reactor to convert the synthesis gas into a liquid effluent stream containing liquefied petroleum gas and a synthetic crude oil. The liquefied petroleum gas and synthetic crude oil from the synthesis gas reactor is sent to the separation complex. Liquefied petroleum gas is separated both from the synthetic crude oil and a natural crude oil obtained from the produced fluids. The system and process permits synthetic crude oil to be blended with the natural crude oil producing a blended stabilized crude oil having 2 wt % or more of the synthetic crude oil and with a pour point of 60° C. or less. Use of a common facility for separation operations on the natural crude oil and synthetic crude oil thus reduces capital costs and allows converted associated gases to be shipped with the natural crude oil on a conventional crude oil tanker.
Opening claim text (preview).
What is claimed is: 1. A system for producing a blended stabilized crude oil from a stream of produced fluids produced from a hydrocarbon containing subterranean reservoir, the system comprising: (a) a separation complex used to separate a stream of produced fluids, including hydrocarbons components and water, received from a hydrocarbon containing subterranean reservoir into water, natural gas, liquefied petroleum gas and crude oil; (b) a synthesis gas generator which converts the natural gas into synthesis gas; and (c) a conversion reactor which utilizes both a synthesis gas conversion catalyst and a hydroconversion catalyst to convert the synthesis gas into a tail gas and a liquid effluent stream which includes liquefied petroleum gas and synthetic crude oil containing less than 5 wt % C 21+ normal paraffins and a tail gas and a liquid effluent stream which includes liquefied petroleum gas and synthetic crude oil; wherein at least a portion of the liquid effluent stream can be fed to the separation complex and the liquefied petroleum gas is separated from the synthetic crude oil and liquefied petroleum gas is separated from natural crude oil with a blended stabilized crude oil being produced which includes natural crude oil and synthetic crude oil; and wherein the blended stabilized crude oil has a pour point at or below 60° C. and comprises at least 2 wt % of the synthetic crude oil. 2. The system of claim 1 wherein: the liquid effluent stream includes water and the water is separated from the liquid effluent stream to produce water and a water depleted effluent stream, the water depleted effluent steam being in fluid communication with the separation complex so that the liquefied petroleum gas can be separated from the synthetic crude oil. 3. The system of claim 1 wherein: the separation complex includes a water/oil separator; and the liquid effluent stream including water and the synthetic crude oil is in fluid communication with the water/oil separator so that water and synthetic crude oil can be separated by the water/oil separator. 4. The system of claim 1 wherein: the synthetic crude oil has less than 1 wt % oxygen as oxygenates, less than 10 wt % olefins, and with an acid number of 1.5 mg KOH or less as measured by ASTM D664. 5. The system of claim 1 wherein: the synthetic crude oil has less than 0.25 wt % oxygen as oxygenates, less than 2 wt % olefins, and with an acid number of 0.5 mg KOH or less as measured by ASTM D664. 6. The system of claim 1 wherein: the conversion reactor includes a bed of integral catalyst which includes particles containing both synthesis gas conversion catalyst and a hydroconversion catalysts. 7. The system of claim 1 wherein: the conversion reactor includes a stacked bed of a first upstream bed of synthesis gas conversion catalysts and a second downstream bed of hydroconversion catalysts. 8. The system of claim 1 wherein: the conversion reactor includes synthesis gas conversion catalysts carried on first particles and hydroconversion catalysts carried on second particles with the first and second particles being intermixed with one another to form a mixed bed. 9. The system of claim 1 wherein: the system is located offshore.
with the use of catalysts · CPC title
Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title
Fischer-Tropsch products · CPC title
with stationary catalyst bed · CPC title
Geographical aspects, e.g. different process units form a combination process at different geographical locations · CPC title
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