Hard coating composition

Patent metadata

Field	Value
Publication number	US-9403991-B2
Application number	US-201314404304-A
Country	US
Kind code	B2
Filing date	May 31, 2013
Priority date	May 31, 2012
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

The present invention relates to a hard coating composition, and, more particularly, to a hard coating composition used in forming a hard coating film exhibiting high hardness and excellent properties. The hard coating composition can be used to form a high-hardness hard coating film that is not easily curled.

First claim

The invention claimed is:

1. A hard coating composition, comprising:
a binder containing a tri- to hexa-functional acrylate-based monomer;
inorganic particles;
a photoinitiator; and
an organic solvent,
wherein a solid content includes the binder, the inorganic particles and the photoinitiator, and a weight ratio of the solid content to the organic solvent is 70:30 to 99:1.

2. The hard coating composition of claim 1 , wherein the tri- to hexa-functional acrylate-based monomer includes at least one selected from the group consisting of trimethylolpropane triacrylate (TMPTA), trimethylolpropaneethoxy triacrylate (TMPEOTA), glycerin-propoxylated triacrylate (GPTA), pentaerythritol tetraacrylate (PETA), and dipentaerythritol hexaacrylate (DPHA).

3. The hard coating composition of claim 1 , wherein the binder further includes a mono- to di-functional acrylate-based monomer.

4. The hard coating composition of claim 3 , wherein the binder includes the mono- to di-functional acrylate-based monomer and the tri- to hexa-functional acrylate-based monomer at a weight ratio of 1:99 to 50:50.

5. The hard coating composition of claim 3 , wherein the mono- to di-functional acrylate-based monomer includes at least one selected from the group consisting of hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate (HEMA), hexanediol diacrylate (HDDA), tripropyleneglycol diacrylate (TPGDA), and ethyleneglycol diacrylate (EGDA).

6. The hard coating composition of claim 1 , wherein the binder further includes a photocurable elastic polymer.

7. The hard coating composition of claim 6 , wherein the photocurable elastic polymer has an elongation of 15 to 200%, as measured according to ASTM D638.

8. The hard coating composition of claim 6 , wherein the photocurable elastic polymer includes at least one selected from the group consisting of polycaprolactone, a urethane acrylate-based polymer, and polyrotaxane.

9. The hard coating composition of claim 8 , wherein the polyrotaxane includes: a macrocycle in which lactone compounds with a (meth)acrylate moiety conjugated to the end thereof are bonded each other; a thread moiety held within the macrocycle; and stoppers provided at both ends of the thread moiety so as to prevent dissociation of the macrocycle.

10. The hard coating composition of claim 1 , wherein the inorganic particles are dispersed in the binder.

11. The hard coating composition of claim 1 , wherein the inorganic particles have a particle size of 100 nm or less.

12. The hard coating composition of claim 1 , wherein the inorganic particles include at least one selected from the group consisting of silica nanoparticles, aluminum oxide nanoparticles, titanium oxide nanoparticles and zinc oxide nanoparticles.

13. The hard coating composition of claim 1 , further comprising an additive.

14. The hard coating composition of claim 13 , wherein the additive includes at least one selected from the group consisting of a mono- to di-functional fluorine-based acrylate, a fluorine-based surfactant, and a silicon-based surfactant.

15. The hard coating composition of claim 13 , wherein the additive includes a yellowing inhibitor including a benzophenone compound or a benzotriazole compound.

16. The hard coating composition of claim 1 , wherein the hard coating composition comprises 35 to 85 parts by weight of the binder, 10 to 60 parts by weight of the inorganic particles and 0.5 to 10 parts by weight of the photoinitiator, based on 100 parts by weight of the solid content.

17. The hard coating composition of claim 1 , wherein the hard coating composition has a viscosity of 100 to 1,200 cps at a temperature of 25° C.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Joon Koo
• Chang Yeong Rae
• Shim Jae Hoon
• Hong Sung Don
• Lee Seung Jung

Classifications

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• Y10T428/31884

  Regenerated or modified cellulose · CPC title

• C08K3/36

  Silica · CPC title