Thermoplastic resin composition and molded article using the same

Patent metadata

Field	Value
Publication number	US-9403978-B2
Application number	US-201314097538-A
Country	US
Kind code	B2
Filing date	Dec 5, 2013
Priority date	Dec 28, 2012
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

A thermoplastic resin composition comprises (A) about 30 to about 98 wt % of a polycarbonate resin, (B) about 1 to about 50 wt % of a rubber modified acrylic-based graft copolymer, and (C) about 1 to about 69 wt % of a branched copolymer including silicon-based compound. A molded article can be made using the same.

First claim

What is claimed is:

1. A thermoplastic resin composition, comprising:
(A) about 30 to about 98 wt % of a polycarbonate resin,
(B) about 1 to about 50 wt % of a rubber modified acrylic-based graft copolymer, and
(C) about 1 to about 69 wt % of a branched copolymer including silicon-based compound, wherein the branched copolymer including a silicon-based compound (C) is a copolymer prepared by copolymerizing a mixture consisting of:
(c1) about 10 to about 85 wt % of an aromatic vinyl-based monomer;
(c2) about 10 to about 85 wt % of an unsaturated nitrile-based monomer; and
(c3) about 0.1 to about 20 wt % of a silicon-based compound including at least two unsaturated reactive groups wherein the branched copolymer including the silicon-based compound (C) has a weight average molecular weight of about 50,000 to about 5,000,000 g/mol as measured by using gel permeation chromatography.

2. The thermoplastic resin composition of claim 1 , wherein the aromatic vinyl-based monomer (c1) is styrene, p-methylstyrene, α-methylstyrene, halogen- and/or C1-C10 alkyl-substituted styrene, or a combination thereof.

3. The thermoplastic resin composition of claim 1 , wherein the unsaturated nitrile-based monomer (c2) is acrylonitrile, methacrylonitrile, ethacrylonitrile, phenylacrylonitrile, α-chloroacrylonitrile, or a combination thereof.

4. The thermoplastic resin composition of claim 1 , wherein the silicon-based compound including at least two unsaturated reactive groups comprises a silicon-based compound represented by the following Chemical Formula 2, singly or as a mixture thereof:

wherein, in the above Chemical Formula 2,
l, m, and n are the same or different and are each independently an integer ranging from 0 to 100, with the proviso that l, m, and n are not 0 simultaneously,
R 1 to R 8 are the same or different and are each independently hydrogen, substituted or unsubstituted C1 to C30 alkyl, substituted or unsubstituted C2 to C30 alkenyl, substituted or unsubstituted C2 to C30 alkynyl, substituted or unsubstituted C3 to C30 cycloalkyl, substituted or unsubstituted C6 to C30 aryl, substituted or unsubstituted C1 to C30 heteroaryl, a hydroxy group, alkoxy, an amino group, an amide group, an epoxy group, a carboxyl group, a halogen, an ester group, an isocyanate group, or a mercapto group, wherein at least two of the R 1 to R 8 include a polymerizable unsaturated reactive group.

5. The thermoplastic resin composition of claim 1 , wherein the silicon-based compound including at least two unsaturated reactive groups comprises dimethoxymethylvinylsilane, diethoxymethylvinylsilane, diacetoxy methylvinylsilane, 1,1,1,3,5,5,5-heptamethyl-3-vinyltrisiloxane, 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane, polydimethylsiloxane, vinyl-modified dimethylsiloxane, or a combination thereof.

6. The thermoplastic resin composition of claim 1 , wherein the thermoplastic resin composition further comprises a styrene-based copolymer (D).

7. The thermoplastic resin composition of claim 1 , wherein the thermoplastic resin composition further comprises a matting agent (E).

8. The thermoplastic resin composition of claim 1 , wherein the thermoplastic resin composition has gloss of about 10 to about 60% at about 60°.

9. The thermoplastic resin composition of claim 1 , wherein the thermoplastic resin composition has ΔE of about 0 to about 2.0 measured by using SAE J1885 standards under an exposure condition of 42 MJ/m 2 in order to evaluate light resistance.

10. A molded article using the thermoplastic resin composition of claim 1 .

Assignees

• Cheil Ind Inc

Inventors

• Kwon Kee-Hae
• Kim In-Chol
• Kim Bo-Eun
• Jang Joo-Hyun
• Hong Chang-Min

Classifications

• C08L25/12

  with unsaturated nitriles · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L51/04

  grafted on to rubbers · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• C08L25/08

  Copolymers of styrene (C08L29/08, C08L35/06, C08L55/02 take precedence) · CPC title