Plasticizer for low temperature unwind with weight retention during heat aging

Patent metadata

Field	Value
Publication number	US-9403965-B2
Application number	US-201214344421-A
Country	US
Kind code	B2
Filing date	Sep 13, 2012
Priority date	Sep 30, 2011
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

The present disclosure is directed to a plasticizer, polymeric compositions containing the plasticizer, and conductors coated with the polymeric composition. The plasticizer includes (i) an epoxidized fatty acid methyl ester, (ii) an epoxidized natural oil, and (iii) an epoxidized tallate ester. Polymeric compositions containing a polymeric resin and the plasticizer exhibit a weight loss less than 50 mg/cm 2 after exposure to 100° C. for seven days. Conductors coated with the polymeric composition (containing the plasticizer) pass the low temperature unwind test of UL719 and exhibit a weight loss less than 50 mg/cm 2 after exposure to 100° C. for seven days.

First claim

The invention claimed is:

1. A polymeric composition comprising:
from 40 wt % to 50 wt % of a vinyl chloride resin;
from 5 wt % to 15 wt % of epoxidized fatty acid methyl ester;
from 5 wt % to 15 wt % of epoxidized natural oil;
from 2 wt % to 10 wt % of epoxidized tallate ester;
from greater than 0 wt % to 35 wt % of a filler; and
the polymeric composition is phthalate-free and passes the low-temperature unwind test as measured in accordance with UL 719 or when formed into a plaque has a weight loss less than 50 mg/cm 2 after exposure to 100° C. for seven days.

2. The polymeric composition of claim 1 wherein
the epoxidized natural oil is an epoxidized soy oil; and
the epoxidized tallate ester is selected from the group consisting of 2-ethylhexyl epoxytallate, octyl epoxytallate, and combinations thereof.

3. The polymeric composition of claim 1 comprising
from 25 wt % to 35 wt % of the filler.

4. The polymeric composition of claim 1 formed into a plaque and having a weight loss less than 50 mg/cm 2 after exposure to 100° C. for seven days.

5. The polymeric composition of claim 1 wherein the polymeric composition passes the low-temperature unwind test as measured in accordance with UL 719.

6. The polymeric composition of claim 1 wherein the polymeric composition passes the low-temperature unwind test as measured in accordance with UL 719 and when the polymeric composition is formed into a plaque has a weight loss less than 50 mg/cm 2 after exposure to 100° C. for seven days.

7. The polymeric composition of claim 6 wherein the epoxidized natural oil is an epoxidized soy oil; and
the epoxidized tallate ester is selected from the group consisting of 2-ethylhexyl epoxytallate, octyl epoxytallate, and combinations thereof.

8. The polymeric composition of claim 7 comprising
from 5 wt % to 15 wt % of epoxidized fatty acid methyl ester;
from 5 wt % to 15 wt % of epoxidized soybean oil;
from 2 wt % to 10 wt % of epoxidized tallate ester; and
from 25 wt % to 35 wt % of a filler.

9. A coated conductor comprising:
a conductor; and
a coating on the conductor, the coating formed from the polymeric composition of claim 1 .

10. The coated conductor of claim 9 wherein the coating has a weight loss less than 50 mg/cm 2 after exposure to 100° C. for seven days.

11. The coated conductor of claim 9 wherein the coated conductor passes the low temperature unwind test as determined in accordance with UL 719.

Assignees

• Laufer Caroline H
• Eaton Robert F
• Ghosh-Dastidar Abhijit
• Mundra Manish
• Chaudhary Bharat I
• Cogen Jeffrey M
• Fu Lin
• Dow Global Technologies Llc

Inventors

• Laufer Caroline H
• Eaton Robert F
• Ghosh-Dastidar Abhijit
• Mundra Manish
• Chaudhary Bharat I
• Cogen Jeffrey M
• Fu Lin

Classifications

• C08K5/0016 Primary

  Plasticisers · CPC title

• C09D127/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08K5/1515 Primary

  Three-membered rings · CPC title

• H01B3/443

  from vinylhalogenides or other halogenoethylenic compounds · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title