Salt byproduct separation during formation of polyarylene sulfide

Patent metadata

Field	Value
Publication number	US-9403948-B2
Application number	US-201414481199-A
Country	US
Kind code	B2
Filing date	Sep 9, 2014
Priority date	Sep 25, 2013
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

Methods of forming a polyarylene sulfide and systems as may be utilized in carrying out the methods are described. Included in the formation method is a filtration process for treatment of a mixture, the mixture including a polyarylene sulfide, a salt byproduct of the polyarylene sulfide formation reaction, and a solvent. The filtration process includes maintaining the downstream side of the filter medium at an increased pressure. The downstream pressure can such that the boiling temperature of the mixture at the downstream pressure can be higher than the temperature at which the polyarylene sulfide is insoluble in the solvent.

First claim

What is claimed is:

1. A method for forming a polyarylene sulfide comprising:
performing a first polymerization in which a dihaloaromatic compound is reacted with an alkali metal sulfide or hydrosulfide in an organic amide solvent to form a mixture that includes a polyarylene sulfide and a salt;
contacting the mixture with a filter that separates the mixture into a filter cake and a filtrate, wherein the filtrate contains at least a portion of the polyarylene sulfide and the filter cake contains at least a portion of the salt, wherein the filter is maintained at a pressure that is elevated above atmospheric pressure and at a temperature of from about 220° C. to about 300° C.; and
performing a second polymerization in which the polyarylene sulfide from the filtrate is reacted with an alkali metal sulfide or hydrosulfide.

2. The method of claim 1 , wherein the dihaloaromatic compound is a dichlorobenzene.

3. The method of claim 1 , wherein the organic amide solvent is N-methylpyrrolidone.

4. The method of claim 1 , wherein the polyarylene sulfide is a linear polyphenylene sulfide.

5. The method of claim 1 , further comprising carrying out a second filtration process following the second polymerization.

6. The method of claim 1 , further comprising washing the filter cake with a wash solution.

7. The method of claim 6 , wherein the wash solution from the washing step is combined with the filtrate.

8. The method of claim 6 , wherein the washing step includes agitation of the filter cake.

9. The method of claim 1 , further comprising drying the filter cake.

10. The method of claim 1 , further comprising combining the filter cake with a liquid to form a slurry.

11. The method of claim 10 , wherein the liquid contains N-methyl pyrrolidone.

12. The method of claim 1 , wherein the dihaloaromatic compound is reacted with a complex of sodium methylaminobutyrate and sodium hydrogen sulfide during the first polymerization.

13. The method of claim 1 , wherein the polyarylene sulfide from the filtrate is reacted with a complex of sodium methylaminobutyrate and sodium hydrogen sulfide during the second polymerization.

14. The method of claim 1 , wherein water is combined with the filtrate during the second polymerization.

15. The method of claim 1 , wherein the elevated pressure is about 300 kilopascals or more.

16. The method of claim 1 , wherein the elevated pressure is constant.

17. The method of claim 1 , wherein the pressure upstream of the filter is greater than the pressure downstream of the filter.

18. The method of claim 17 , wherein the downstream pressure is about 300 kilopascals or more.

19. The method of claim 17 , wherein the difference between the upstream pressure and the downstream pressure is constant.

20. The method of claim 17 , wherein the upstream pressure and downstream pressure are constant.

21. The method of claim 1 , wherein the salt includes sodium chloride.

Assignees

• Ticona Llc

Inventors

• Chiong Hendrich
• Haubs Michael
• Feord Damian
• Shatzer Mark
• Grayson Jacob

Classifications

• C08G75/16 Primary

  by polycondensation of organic compounds with inorganic polysulfides · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• C08G75/14 Primary

  Polysulfides · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• B01J19/245

  placed in series · CPC title