Light-curing ceramic slips for the stereolithographic preparation of high-strength ceramics

Patent metadata

Field	Value
Publication number	US-9403726-B2
Application number	US-201414200323-A
Country	US
Kind code	B2
Filing date	Mar 7, 2014
Priority date	Jul 8, 2010
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

A process for the preparation of a ceramic or glass ceramic shaped article using stereolithography and using a slip based on a radically polymerizable binder, polymerization initiator and filler, which comprises (A) at least one acidic monomer of general formula I

(B) photoinitiator, and (C) ceramic and/or glass ceramic particles.

First claim

The invention claimed is:

1. A process for the preparation of a ceramic or glass ceramic shaped article comprising: preparing a slip comprising:
A) 1 to 30 wt.-% of at least one acidic monomer of general formula I

in which
X is not present or is an (a+b)-valent, unsubstituted, straight-chained or branched aliphatic residue with 3 to 15 carbon atoms, which residues can contain one or two ether groups,
PG is an acrylate or acrylamide group;
HG is —COOH;
Y is a divalent, straight-chained aliphatic group with 2 to 8 carbon atoms, a branched aliphatic group with 3 to 8 carbon atoms or a cycloaliphatic or aromatic group with 6 to 15 carbon atoms, wherein these groups can contain one ester group;
Z is a divalent, straight-chained aliphatic group with 2 to 10 carbon atoms or a branched aliphatic group with 3 to 10 carbon atoms, wherein these groups can contain one or more ether;
a is an integer from 1 to 3; and
b is 1 or 2;

A2) 0 to 50 wt.-% of at least one non-acidic radically polymerizable monomer;
B) 0.001 to 2.0 wt.-% photoinitiator; and
C) 30 to 90 wt.-% ceramic and/or glass ceramic particles; in each case relative to the total mass of the slip; and
forming a green body through layer-by-layer radiation curing of the slip,
heating the green body to remove binder and form a white body, and
sintering the white body to form a dense ceramic article.

2. The process of claim 1 , wherein heating is carried out at a temperature in the range of 90° C. to 600° C.

3. The process of claim 1 , wherein sintering is carried out at a temperature in the range of 650 to 1800° C.

4. The process of claim 1 , wherein the ceramic or glass ceramic shaped article is a dental restoration.

5. The process of claim 4 , wherein the dental restoration comprises an inlay, onlay, veneer, crown, bridge or framework.

6. The process of claim 1 , wherein the variables of formula (I) have the following meaning:
X is not present or is an (a+b)-valent, unsubstituted, branched or straight-chained aliphatic residue with 3 to 15, which residue can contain 1 or 2 ether groups;
PG is an acrylate or acrylamide group;
HG is —COOH;
Y is a divalent, straight-chained aliphatic group with 2 to 8 carbon atoms or a branched aliphatic group with 3 to 8 carbon atoms, wherein these groups can contain 1 ester group;
Z is a divalent, straight-chained aliphatic group with 2 to 10 carbon atoms or a branched aliphatic group with 3 to 10 carbon atoms, wherein these groups can contain 1 to 3, ether groups;
a is 1, 2 or 3; and
b is 1.

7. The process of claim 1 , wherein the slip further comprises
D) 0.001 to 1.0 wt.-% inhibitor, relative to the total mass of the slip.

8. The process of claim 1 , wherein the slip further comprises
0 to 20 wt.-% debinding accelerator (E),
0 to 20 wt.-% plasticizer and
0 to 70 wt.-% solvent,
in each case relative to the total mass of radically polymerizable components.

9. The process of claim 1 , wherein the slip further comprises
F) 0.00001 to 2.0 wt.-% coloring components, relative to the mass of component (C).

10. The process of claim 1 , wherein the slip comprises as component (C) glass ceramic particles or ceramic particles based on pure ZrO 2 , pure Al 2 O 3 , pure ZrO 2 —Al 2 O 3 , ZrO 2 which is stabilized with HfO 2 , CaO, Y 2 O 3 , CeO 2 and/or MgO, ZrO 2 —Al 2 O 3 which is stabilized with HfO 2 , CaO, Y 2 O 3 , CeO 2 and/or MgO or non-oxide ceramics.

11. The process of claim 1 , wherein the particles of component (C) are surface-modified with a linear or branched carboxylic acid, an acidic phosphoric acid ester, a phosphonic acid, or a silane, wherein the surface-modification agent does not contain radically polymerizable groups.

12. The process of claim 1 , wherein the particles of component (C) have a particle size in the range from 20 nm to 50 μm.

13. The process of claim 8 , wherein the slip comprises as debinding accelerator (E)
a chain transfer agent; and/or
a comonomer which has one or more thermally labile groups; and/or
a comonomer with a ceiling temperature of −10 to 150° C.

14. The process of claim 9 , wherein the slip comprises as coloring component (F) a transition metal compound.

15. The process of claim 1 , wherein the slip further comprises at least one further component from the group of dispersants, defoaming agents, and antiskinning agents.

16. The process of claim 1 , wherein the slip comprises at most 40 wt.-% of multifunctional monomers relative to the total mass of radically polymerizable components.

17. The process of claim 6 , wherein:
X is an (a+b)-valent, unsubstituted, branched or straight-chained aliphatic residue with 3 to 8 carbon atoms, which residue can contain 1 or 2 ether groups.

18. The process of claim 13 , wherein
the chain transfer agent comprises a mercaptan, a disulphide or a photoiniferter; and/or
the comonomer comprises one or more peroxide, azo or urethane groups; and/or
the comonomer comprises α-methylstyrene, polytetrahydrofuran (PTHF), or a telechel with radically polymerizable groups.

19. The process of claim 18 , wherein
the chain transfer agent comprises lauryl mercaptan, a dithiourethane disulphide, tetramethyl-thiuram disulphide or isopropylxanthogenic acid disulphide; and/or
the comonomer comprises a PTHF di(meth)acrylate telechel.

20. The process of claim 14 , wherein the slip comprises as coloring component (F) an acetyl acetonate and/or a carboxylic acid salt of the elements iron, cerium, praseodymium, terbium, lanthanum, tungsten, osmium, terbium and manganese.

21. The process of claim 20 , wherein the slip comprises as coloring component (F) iron (III) acetate or iron (III) acetyl acetonate, manganese (III) acetate or manganese (III) acetyl acetonate, praseodymium (III) acetate or praseodymium (III) acetyl acetonate or terbium (III) acetate or terbium (III) acetyl acetonate.

22. The process of claim 11 , wherein
the linear or branched carboxylic acid comprises formic acid, acetic acid, propionic acid, octanoic acid, isobutyric acid, isovaleric acid or pivalic acid;
the acidic phosphoric acid ester comprises dimethyl, diethyl, dipropyl, dibutyl, dipentyl, dihexyl, dioctyl or di(2-10 ethylhexyl)phosphate;
the phosphonic acid comprises methyl, ethyl, propyl, butyl, hexyl, octyl or phenyl phosphonic acid; or
the silane comprises propyltrimethoxysilane, phenyltrimethoxysilane, hexyltrimethoxysilane, octyltrimethoxysilane, trimethylchloro-silane, trimethylbromosilane, trimethylmethoxysilane or hexamethyldisilazane.

Assignees

• Ivoclar Vivadent Ag

Inventors

• Fischer Urs Karl
• Moszner Norbert
• Rheinberger Volker
• Wachter Wolfgang
• Homa Johannes
• Längle Werner

Classifications

• A61K6/833

  Glass-ceramic composites · CPC title

• A61K6/807

  comprising magnesium oxide · CPC title

• A61K6/818

  comprising zirconium oxide · CPC title

• A61K6/887

  Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• A61K6/822

  comprising rare earth metal oxides · CPC title