Tire provided with a tread including a thermoplastic elastomer and carbon black

Patent metadata

Field	Value
Publication number	US-9403406-B2
Application number	US-201314428888-A
Country	US
Kind code	B2
Filing date	Sep 16, 2013
Priority date	Sep 17, 2012
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

The present invention relates to a tire comprising a tread, a crown with a crown reinforcement, two sidewalls, two beads and a carcass reinforcement anchored to the two beads and extending from one sidewall to the other. The tread is based on at least one thermoplastic elastomer and on carbon black at a content by volume within a range extending from 5% to 30%, the thermoplastic elastomer being a block copolymer comprising at least one elastomer block and at least one thermoplastic block, and the total content of thermoplastic elastomer being within a range varying from 65 to 100 phr.

First claim

The invention claimed is:

1. A tire comprising:
a tread,
a crown with a crown reinforcement,
two sidewalls,
two beads, and
a carcass reinforcement anchored to the two beads and extending from one sidewall to the other,
wherein the tread comprises at least one thermoplastic elastomer and carbon black at a content by volume within a range extending from 5% to 30%,
wherein the thermoplastic elastomer is a block copolymer comprising at least one elastomer block and at least one thermoplastic block, and
wherein the total content of thermoplastic elastomer is within a range varying from 65 to 100 phr.

2. The tire according to claim 1 , wherein the number-average molecular weight of the thermoplastic elastomer is between 30,000 and 500,000 g/mol.

3. The tire according to claim 1 , wherein the at least one elastomer block is chosen from elastomers having a glass transition temperature of less than 25° C.

4. The tire according to claim 1 , wherein the at least one elastomer block is selected from the group consisting of ethylene elastomers, diene elastomers, and mixtures thereof.

5. The tire according to claim 4 , wherein the at least one elastomer block is chosen from ethylene elastomers.

6. The tire according to claim 4 , wherein the at least one elastomer block is chosen from diene elastomers.

7. The tire according to claim 6 , wherein the at least one elastomer block is selected from diene elastomers resulting from isoprene, butadiene or a mixture thereof.

8. The tire according to claim 1 , wherein the at least one thermoplastic block is chosen from polymers having a glass transition temperature of greater than 80° C.

9. The tire according to claim 1 , wherein the at least one thermoplastic block is a semicrystalline thermoplastic block and is chosen from polymers having a melting point of greater than 80° C.

10. The tire according to claim 1 , wherein the at least one thermoplastic block is selected from the group consisting of polyolefins, polyurethanes, polyamides, polyesters, polyacetals, polyethers, polyphenylene sulphides, polyfluorinated compounds, polystyrenes, polycarbonates, polysulphones, polymethyl methacrylate, polyetherimide, thermoplastic copolymers, and mixtures thereof.

11. The tire according to claim 1 , wherein the at least one thermoplastic block is chosen from polystyrenes.

12. The tire according to claim 1 , wherein the at least one thermoplastic elastomer is selected from the group consisting of styrene/butadiene thermoplastic elastomers, styrene/isoprene thermoplastic elastomers, styrene/butadiene/isoprene thermoplastic elastomers, styrene/butadiene/styrene thermoplastic elastomers, styrene/isoprene/styrene thermoplastic elastomers, styrene/butadiene/isoprene/styrene thermoplastic elastomers and mixtures thereof.

13. The tire according to claim 1 , wherein the at least one thermoplastic elastomer is the only elastomer present in the tread.

14. The tire according to claim 1 , wherein the tread further comprises at least one one non-thermoplastic elastomer at a total content of at most 35 phr.

15. The tire according to claim 1 , wherein the carbon black is present at a content within a range extending from 7% to 30%.

16. The tire according to claim 15 , wherein the carbon black is present at a content within a range extending from 10% to 25%.

17. The tire according to claim 1 , wherein the carbon black is chosen from carbon blacks with a BET specific surface of greater than 80 m 2 /g.

18. The tire according to claim 17 , wherein the carbon black is chosen from carbon backs with a BET specific surface of greater than 90 m 2 /g.

19. The tire according to claim 18 , wherein the carbon black is a carbon black with a BET specific surface of greater than 120 m 2 /g.

20. The tire according to claim 1 , wherein the tread further comprises a plasticizer.

21. The tire according to claim 20 , wherein the plasticizer is present at a content of between 5 and 85 phr.

22. The tire according to claim 20 , wherein the plasticizer is a plasticizing resin, a plasticizing oil, or a combination of a plasticizing resin and a plasticizing oil.

23. The tire according to claim 22 , wherein the plasticizing oil is a paraffinic oil.

24. The tire according to claim 20 , wherein the plasticizer is present at a content within a range extending from 10 to 60 phr.

Assignees

• Michelin & Cie
• Michelin Rech Tech

Inventors

• Custodero Emmanuel
• Abad Vincent
• Lemal Vincent

Classifications

• B60C11/0008

  characterised by the tread rubber · CPC title

• B60C2011/0016

  Physical properties or dimensions · CPC title

• B60C1/0016 Primary

  Compositions of the tread · CPC title

• B60C15/0009

  features of the carcass terminal portion · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title