System for making renewable fuels

Patent metadata

Field	Value
Publication number	US-9403140-B2
Application number	US-201514618348-A
Country	US
Kind code	B2
Filing date	Feb 10, 2015
Priority date	Mar 24, 2011
Publication date	Aug 2, 2016
Grant date	Aug 2, 2016

Abstract

Multiple catalytic processing stations couple with a system which produces volatile gas streams from biomass decomposition at discrete increasing temperatures. These catalytic processing stations can be programmed to maximize conversion of biomass to useful renewable fuel components based on input feedstock and desired outputs.

First claim

The invention claimed is:

1. A system for the conversion of biomass to renewable fuel, comprising:
a programmable number of processing stations (N) for subjecting biomass to at least one programmable starting temperature (Tstart) and for incrementing the temperature by programmable increments (ΔT) to produce a volatile and a non-volatile component;
a series of catalyst columns for receiving the volatile components generated in each station to produce at least one renewable fuel; and
a hydrotreating catalyst to which the at least one renewable fuel is subjected to produce at least one hydrotreated renewable fuel.

2. The system of claim 1 , wherein the hydrotreating catalyst comprises one or more metals supported on a high surface area inorganic carrier.

3. The system of claim 1 , wherein the at least one renewable fuel is subjected to the hydrotreating catalyst at a temperature of between about 100° C. to about 400° C.

4. The system of claim 1 , wherein the series of catalyst columns comprise catalysts for catalytic aromatization and catalytic gas-upgrading.

5. The system of claim 1 , wherein the series of catalyst columns comprise catalysts for catalytic dehydration and catalytic gas-upgrading.

6. The system of claim 1 , wherein the series of catalyst columns comprise catalysts for catalytic dehydration and catalytic aromatization.

7. The system of claim 1 , wherein the processing station is further used for incrementing the non-volatile component temperature by ΔT to produce additional volatile and non-volatile components.

8. The system of claim 1 , wherein N ranges from 2 to 1000, and wherein Tstart ranges from 100° C. to 1000° C.

9. The system of claim 1 , wherein the temperature increment (ΔT) ranges from 0° C. to 200° C., and wherein biomass moisture content is less than 15%.

10. The system of claim 9 , wherein biomass is ground to a particle size between 1/16 inch and 1 inch.

11. The system of claim 1 , wherein a co-solvent is added to volatile components or added to at least one of the processing stations, wherein the co-solvent is selected from the group consisting of alcohols, aldehydes, ketones, ethers, carboxylic acids, and hydrocarbons, and wherein generation of the co-solvent comprises treatment of the non-volatile component with a syngas conversion catalyst to generate syngas.

12. The system of claim 11 , wherein generation of the co-solvent further comprises treatment of the syngas with a methanol/dimethyl ether synthesis catalyst.

13. The system of claim 11 , further comprising a Fischer-Tropsch catalyst, wherein a portion of the syngas is subjected to the Fischer-Tropsch catalyst to generate synthetic paraffinic kerosene.

14. The system of claim 1 , wherein the biomass is selected from the group consisting of lipids, hemicellulose, cellulose and lignins.

15. The system of claim 14 , wherein Tstart is below 300° C. for biomass composition comprising 20-80% lipids, wherein Tstart is in the range of 300-500° C. for biomass comprising 20-80% hemicellulose, and wherein Tstart is greater than 500° C. for biomass composition comprising 20-80% lignins.

16. The system of claim 14 , wherein Tstart is selected according to the highest biomass compositional component selected from the groups consisting of lipids, hemicellulose and lignins.

17. The system of claim 1 , wherein all processing stations are set at the same Tstart.

18. The system of claim 1 , wherein the non-volatile component is thermally conductive.

19. A system for the conversion of biomass to renewable fuel, comprising:
a programmable number of processing stations (N) for subjecting biomass to at least one programmable starting temperature (Tstart) and for incrementing the temperature by programmable increments (ΔT) to produce a volatile and a non-volatile component;
a series of catalyst columns for receiving the volatile components generated in each station to produce at least one renewable fuel;
a syngas conversion catalyst; and
a methanol/dimethyl ether synthesis catalyst;
wherein a co-solvent is added to volatile components or added to at least one of the processing stations, wherein the co-solvent is selected from the group consisting of alcohols, aldehydes, ketones, ethers, carboxylic acids, and hydrocarbons, and wherein the co-solvent is generated via treatment of the non-volatile component with the syngas conversion catalyst to generate syngas and subsequent treatment of a portion of the syngas with the methanol/dimethyl ether synthesis catalyst.

20. The system of claim 19 , wherein the methanol/dimethyl ether synthesis catalyst comprises a catalyst capable of generating one or more lower alcohols selected from the group consisting of methanol, ethanol, propanol, butanol and isobutanol from a syngas feedstock.

21. The system of claim 19 , wherein the methanol/dimethyl ether synthesis catalyst comprises copper, ruthenium, or both.

22. The system of claim 21 , wherein the methanol/dimethyl ether synthesis catalyst further comprises a solid acid component selected from the group consisting of alumina, silica-alumina, zeolites, sulfated zirconias, and heteropoly acids.

23. The system of claim 19 , further comprising a Fischer-Tropsch catalyst, wherein a portion of the syngas is subjected to the Fischer-Tropsch catalyst to generate synthetic paraffinic kerosene.

24. A system for the conversion of biomass to renewable fuel, comprising:
a programmable number of processing stations (N) for subjecting biomass to at least one programmable starting temperature (Tstart) and for incrementing the temperature by programmable increments (ΔT) to produce a volatile and a non-volatile component;
a series of catalyst columns for receiving the volatile components generated in each station to produce at least one renewable fuel;
a syngas conversion catalyst; and
a Fischer-Tropsch catalyst; wherein the syngas conversion catalyst is used to convert a portion of the non-volatile component to syngas, and wherein a portion of the resulting syngas is subjected to the Fischer-Tropsch catalyst to generate synthetic paraffinic kerosene.

25. The system of claim 24 , wherein the Fischer-Tropsch catalyst comprises one or more selected from the group consisting of iron, cobalt, and ruthenium.

26. The system of claim 24 , wherein a portion of the resulting syngas is subjected to the Fischer-Tropsch catalyst at a temperature of between about 150° C. and about 400° C.

27. The system of claim 24 , wherein a portion of the resulting syngas is subjected to the Fischer-Tropsch catalyst at a pressure of between about 100 psi and about 1000 psi.

28. The system of claim 24 , wherein the portion of the resulting syngas subjected to the Fischer-Tropsch catalyst comprises hydrogen and carbon monoxide at a ratio of between about 1:0.5 to about 1:5.

Assignees

• Cool Planet Energy Systems Inc

Inventors

• Cheiky Michael C
• Malyala Rajashekharam

Classifications

• C10G69/02

  plural serial stages only · CPC title

• C10G3/42

  Catalytic treatment · CPC title

• C10G1/002 Primary

  in combination with oil conversion- or refining processes · CPC title

• B01J2219/00054

  Controlling or regulating the heat exchange system · CPC title

• B01J19/0013 Primary

  Controlling the temperature of the process · CPC title