Attachment of conducting graphene electrode layer to an organic polymer

Patent metadata

Field	Value
Publication number	US-9401489-B2
Application number	US-201314092230-A
Country	US
Kind code	B2
Filing date	Nov 27, 2013
Priority date	Nov 27, 2012
Publication date	Jul 26, 2016
Grant date	Jul 26, 2016

Abstract

A method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer that includes: forming a polymer layer having a hydrophobic, exterior surface; subjecting the hydrophobic, exterior surface of the polymer layer to ultraviolet/ozone (UV/O 3 ) exposure to change the hydrophobic, exterior surface to a hydrophilic, exterior surface; and applying reduced graphene oxide and/or graphene oxide to the hydrophilic surface of the polymer layer. The UV/O 3 exposure reduces the contact angle of droplets on the exterior surface of the polymer layer so that greater amounts of reduced graphene oxide and/or graphene oxide can be applied to the surface.

First claim

We claim:

1. A method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer, the method comprising:
forming a polymer layer having an exterior surface, wherein the exterior surface is hydrophobic;
subjecting the hydrophobic, exterior surface of the polymer layer to ultraviolet/ozone (UV/O 3 ) exposure, wherein the UV/O 3 exposure changes the hydrophobic, exterior surface to a hydrophilic, exterior surface and etches the exterior surface; and
applying a reduced graphene oxide and/or graphene oxide solution or suspension to the hydrophilic surface of the polymer layer.

2. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the polymer layer is a poly-3-hexyl thiophene (P3HT) and phenyl-C 61 -butyric acid methyl ester (PCBM) blend (P3HT:PCBM).

3. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the UV/O 3 exposure has a duration of from 1 to 20 minutes.

4. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the UV/O 3 exposure has a duration of from 5 to 10 minutes.

5. The method of attaching reduced graphene oxide to a polymer layer according to claim 1 , wherein the exterior surface of the polymer layer has a contact angle, and wherein the contact angle is reduced from more than 70 degrees to less than 70 degrees by the UV/O 3 exposure.

6. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the exterior surface of the polymer layer has a contact angle, and wherein the contact angle is reduced from more than 80 degrees to less than 50 degrees by the UV/O 3 exposure.

7. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the reduced graphene oxide and/or graphene oxide comprises gold particles.

8. The method of attaching reduced graphene oxide to a polymer layer according to claim 1 , wherein the reduced graphene oxide and/or graphene oxide solution or suspensions comprises gold particles derived from AuCl 4 .

9. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein UV/O 3 exposure is for a period of from thirty seconds to one hour.

10. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the reduced graphene oxide and/or graphene oxide is in a hydrophilic suspension or in a hydrophilic solution.

11. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 1 , wherein the reduced graphene oxide and/or graphene oxide is applied by spin coating or by applying a thin film from the air-water interface of a Langmuir-Blodgett trough.

12. A method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer, the method comprising:
forming a poly-3-hexyl thiophene (P3HT) and phenyl-C 61 -butyric acid methyl ester (PCBM) blend polymer layer (P3HT:PCBM) having an exterior surface, wherein the exterior surface is hydrophobic;
subjecting the hydrophobic, exterior surface of the P3HT:PCBM blend polymer layer to ultraviolet/ozone (UV/O 3 ) exposure, wherein the UV/O 3 exposure changes the hydrophobic, exterior surface to a hydrophilic, exterior surface and etches the exterior surface; and
applying a hydrophilic suspension or a hydrophilic solvent comprising reduced graphene oxide and/or graphene oxide to the hydrophilic surface of the P3HT:PCBM blend polymerlayer.

13. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 12 , wherein the duration of the UV/O 3 exposure is from 1 to 20 minutes.

14. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 12 , wherein the exterior surface of the polymer layer has a contact angle, and wherein the contact angle of the exterior surface of the polymer layer is reduced from more than 80 degrees to less than 40 degrees by the UV/O 3 exposure.

15. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 12 , wherein the hydrophilic suspension or hydrophilic solvent of reduced graphene oxide and/or graphene oxide comprises gold particles.

16. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 12 , wherein the hydrophilic suspension or hydrophilic solvent of reduced graphene oxide and/or graphene oxide comprises gold particles derived from AuCl 4 .

17. The method of attaching reduced graphene oxide and/or graphene oxide to a polymer layer according to claim 12 , wherein the hydrophilic suspension or hydrophilic solvent of reduced graphene oxide and/or graphene oxide is applied by spin coating or by applying a thin film from the air-water interface of a Langmuir-Blodgett trough.

18. A method of attaching reduced graphene oxide and/or graphene oxide to a poly-3-hexyl thiophene (P3HT) and phenyl-C 61 -butyric acid methyl ester (PCBM) blend polymer layer (P3HT:PCBM), the method comprising:
forming a P3HT:PCBM blend polymer layer having an exterior surface, wherein the exterior surface is hydrophobic and has a contact angle;
subjecting the hydrophobic, exterior surface of the P3HT:PCBM blend polymer layer to ultraviolet/ozone (UV/O 3 ) exposure for a duration of from 30 seconds to one hour, wherein the UV/O 3 exposure changes the hydrophobic, exterior surface to a hydrophilic, exterior surface and etches the exterior surface; and
applying a hydrophilic suspension or a hydrophilic solvent comprising reduced graphene oxide and/or graphene oxide and gold particles to the hydrophobic surface of the P3HT:PCBM blend polymer layer, wherein the UV/O 3 exposure reduces the contact angle of the exterior surface of the P3HT:PCBM blend polymer layer from more than 80 degrees to less than 50 degrees.

19. The method of attaching reduced graphene oxide and/or graphene oxide to a P3HT:PCBM blend polymer layer according to claim 18 , wherein the gold particles are derived from AuCl 4 .

20. The method of attaching reduced graphene oxide and/or graphene oxide to a P3HT:PCBM blend polymer layer according to claim 18 , wherein the hydrophilic suspension of reduced graphene oxide and/or graphene oxide is applied by spin coating or by applying a thin film from the air-water interface of a Langmuir-Blodgett trough.

Assignees

• Univ New York State Res Found

Inventors

• Rafailovich Miriam
• Isseroff Rebecca
• Chen Andrew
• Chittabathini Sneha
• Tse Alexandra

Classifications

• H10K30/50

  Photovoltaic [PV] devices · CPC title

• H01L51/4253

  Electricity · mapped topic

• Y02E10/549

  Organic PV cells · CPC title

• H01L51/441 Primary

  Electricity · mapped topic

• H10K30/30

  comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains · CPC title