Urethane foam molded product and method for producing the same

Patent metadata

Field	Value
Publication number	US-9399706-B2
Application number	US-201314044157-A
Country	US
Kind code	B2
Filing date	Oct 2, 2013
Priority date	Sep 20, 2011
Publication date	Jul 26, 2016
Grant date	Jul 26, 2016

Abstract

To provide a urethane foam molded product having high thermal conductivity and electric insulation and a method for producing the same. A urethane foam molded product includes a base material made of a polyurethane foam and composite particles that are blended in the base material and oriented in a mutually connected state, in which each of the composite particles includes a thermally conductive particle made of a non-magnetic body, and a magnetic particle and an insulating inorganic particle that are adhered to the surface of the thermally conductive particle through a binder. A powder of the composite particles can be produced by stirring a powder raw material containing a powder of the thermally conductive particle, a powder of the magnetic particle, a powder of the insulating inorganic particle, and the binder using a stirring granulator.

First claim

The invention claimed is:

1. A urethane foam molded product, characterized by comprising:
a base material made of a polyurethane foam; and
composite particles that are blended in the base material and oriented in a mutually connected state, wherein
each of the composite particles includes a thermally conductive particle made of a non-magnetic body, and a magnetic particle and an insulating inorganic particle that are adhered to a surface of the thermally conductive particle through a binder,
the insulating inorganic particle is one or more selected from aluminum hydroxide, aluminum oxide, magnesium hydroxide, magnesium oxide, and talc.

2. The urethane foam molded product according to claim 1 , wherein the insulating inorganic particle is located in outermost layers of the composite particles.

3. The urethane foam molded product according to claim 1 , wherein the insulating inorganic particle has a thermal conductivity of 5 W/m·K or more.

4. The urethane foam molded product according to claim 1 , wherein the insulating inorganic particle has a particle diameter of 1/100 or more and 1/10 or less of a particle diameter of the thermally conductive particle.

5. The urethane foam molded product according to claim 1 , wherein the volume ratio between the thermally conductive particle and the insulating inorganic particle in the composite particle is 4:6 to 3:7.

6. The urethane foam molded product according to claim 1 , wherein the thermally conductive particle is at least one of a natural graphite particle and an expanded graphite particle.

7. The urethane foam molded product according to claim 1 , wherein the binder is one or more selected from methylcellulose, carboxymethylcellulose, hydroxypropylmethylcellulose, and polyvinyl alcohol.

8. The urethane foam molded product according to claim 1 , wherein a thermal conductivity is 1 W/m·K or more and a volume resistivity during application of a voltage of 1 kV is 10 8 Ω·cm or more.

9. The urethane foam molded product according to claim 1 , further comprising the insulating inorganic particle dispersed in the base material.

10. The urethane foam molded product according to claim 1 , wherein the composite particles are produced by a stirring granulation method.

11. A method for producing the urethane foam molded product as claimed in claim 10 , the method characterized by comprising:
a composite particle producing process of stirring a powder raw material containing a powder of the thermally conductive particle, a powder of the magnetic particle, a powder of the insulating inorganic particle, and the binder using a stirring granulator to produce a powder of the composite particles;
a raw material mixing process of mixing the produced powder of the composite particles, a foamable urethane resin raw material, and as necessary, the powder of the insulating inorganic particle to prepare a mixed raw material; and
a foam molding process of injecting the mixed raw material into a cavity of a foaming mold and performing foam molding with applying a magnetic field to the mixed raw material so that the magnetic flux density in the cavity is substantially homogeneous.

12. The method for producing the urethane foam molded product according to claim 11 , wherein the composite particle producing process includes a first stirring process of stirring a first powder raw material containing the powder of the thermally conductive particle, the powder of the magnetic particle, and the binder, and a second stirring process of adding the powder of the insulating inorganic particle and the binder to the resultant stirred material and further stirring the resultant mixture.

13. The method for producing the urethane foam molded product according to claim 11 , wherein in the composite particle producing process, the blending amount of the powder of the insulating inorganic particle is 150 parts by mass or more and 250 parts by mass or less relative to 100 parts by mass of the powder of the thermally conductive particle.

Assignees

• Tokai Rubber Ind Ltd
• Sumitomo Riko Co Ltd

Inventors

• Katayama Naoki
• Tomiyama Koji
• Suzuki Yasuo

Classifications

• C08K9/08

  Ingredients agglomerated by treatment with a binding agent · CPC title

• B29K2995/0008

  Magnetic or paramagnetic · CPC title

• C08J2375/04

  Polyurethanes · CPC title

• C08J2429/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• B29C44/3403

  Foaming under special conditions, e.g. in sub-atmospheric pressure, in or on a liquid · CPC title