Amorphous propylene-ethylene copolymers

Patent metadata

Field	Value
Publication number	US-9399686-B2
Application number	US-201414567074-A
Country	US
Kind code	B2
Filing date	Dec 11, 2014
Priority date	Feb 7, 2014
Publication date	Jul 26, 2016
Grant date	Jul 26, 2016

Abstract

Amorphous propylene-ethylene copolymers are described herein that can include high amounts of ethylene and exhibit desirable softening points and needle penetrations. The desirable combinations of softening points and needle penetrations in these propylene-ethylene copolymers allow them to have a broad operating window. Due their broad operating window, the propylene-ethylene copolymers can be utilized in a wide array of applications and products, including hot melt adhesives.

First claim

What is claimed is:

1. A copolymer comprising propylene and ethylene, wherein said copolymer has a softening point in the range of 90 to less than 115° C., wherein said copolymer has a needle penetration equal to or less than 53 dmm, wherein said copolymer comprises at least 14 weight percent of ethylene.

2. The copolymer of claim 1 , wherein said copolymer comprises in the range of 14 to 35 weight percent of ethylene.

3. The copolymer of claim 1 , wherein said copolymer has a Brookfield viscosity at 190° C. in the range of 500 to 30,000 cps.

4. The copolymer of claim 1 , wherein said copolymer comprises in the range of 40 to 85 weight percent of propylene.

5. The copolymer of claim 1 , wherein the weight ratio of propylene to ethylene in said copolymer is in the range of 1:1 to 15:1.

6. The copolymer of claim 1 , wherein said copolymer comprises at least one C 4 -C 10 alpha-olefin.

7. An article comprising said copolymer of claim 1 .

8. An adhesive comprising said copolymer of claim 1 .

9. The adhesive of claim 8 , wherein said adhesive comprises in the range of 5 to 95 weight percent of said copolymer.

10. The adhesive of claim 8 , wherein said adhesive comprises in the range of 5 to 95 weight percent of at least one polymer.

11. The adhesive of claim 8 , wherein said adhesive comprises in the range of 0 to 70 weight percent of at least one tackifier.

12. The adhesive of claim 8 , wherein said adhesive comprises in the range of 0 to 30 weight percent of at least one processing oil.

13. The adhesive of claim 8 , wherein said adhesive comprises in the range of 0 to 30 weight percent of at least one wax.

14. The adhesive of claim 8 , wherein said needle penetration is in the range of 0.5 to 50 dmm.

15. The adhesive of claim 8 , wherein the weight ratio of propylene to ethylene in said copolymer is in the range of 1:1 to 15:1.

16. The adhesive of claim 8 , wherein said adhesive has a peel strength in the range of 1 to 200 g/mm when applied at temperatures in the range of 100 to 145° C., wherein said adhesive has a peel strength in the range of 1 to 250 g/mm when applied at temperatures in the range of 145 to 180° C.

17. The adhesive of claim 8 , wherein said adhesive has a loop tack in the range of 0.1 to 50 lbf.

18. The adhesive of claim 8 , wherein said adhesive has an initial Gardner color of 0.1 to 18.

19. The copolymer of claim 1 , wherein said copolymer comprises in the range of 17 to 40 weight percent of ethylene.

20. The copolymer of claim 1 , wherein said copolymer comprises a weight ratio of propylene to ethylene of not more than 5:1.

Assignees

• Eastman Chem Co

Inventors

• Somers Marc Stacey
• Novak Bennett H
• Rajesh Raja Puthenkovilakom
• Cottle Raymond Prescott

Classifications

• C09J123/14 Primary

  Copolymers of propene (C09J123/16 takes precedence) · CPC title

• C08F210/06

  Propene · CPC title

• C08F4/6465

  containing silicium · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title

• C08F10/06 Primary

  Propene · CPC title